Sticky-shed syndrome is a condition created by the deterioration of the binders in a magnetic tape, which hold the iron oxide magnetizable coating to its plastic carrier, or which hold the thinner back-coating on the outside of the tape. This deterioration renders the tape unusable. Some kinds of binder are known to break down over time, due to the absorption of moisture (hydrolysis).
The symptoms of this breakdown can be immediately obvious even when rewinding the tape: tearing sounds and sluggish behavior. If a tape with sticky-shed syndrome is played, the reels will make screeching or squeaking sounds, and the tape will leave dusty, rusty particles on the guides and heads. In some cases, particularly with digital tapes, the symptoms are more subtle, causing intermittent dropouts.
Some tapes may deteriorate because of a breakdown in the binder (the glue) that holds the oxide particles on the tape, or the back coating on the reverse side, if the tape was from any of the tape manufacturers who had inadvertently used an unstable binder formulation. That binder contained polyurethane that soaks up water and causes the urethane to rise to the tape's surface. This problem became known as the 'sticky-shed syndrome'. One explanation was offered that short strands of urethane were most commonly used in tapes - until it was discovered that middle-sized strands are better and were good at absorbing moisture. Baking the tape temporarily restores the tape by driving the water molecules from the binder so that it can be safely copied to another tape or a different format. After baking, the tape usually remains in good condition for approximately a month. If the tape re-deteriorates, it may be possible to bake the tape again.
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Tapes made by Scotch/3M are also affected and the most common offenders here are the "pro" tapes such as 206/207, 226/227, 808, and 986 as well as audiophile tapes such as "Classic" and "Master-XS".
Though less common, many Sony branded tapes such as PR-150, SLH, ULH, and FeCr have also been reported to suffer from sticky-shed.
Blank cassettes from the 70's-90's are unaffected because the hygroscopic binder was not used in cassette formulations. However, some cassette tape formulations do suffer from a similar problem caused by fatty acids working to the surface of the tape that can cause sticking to heads and guides and severe modulation of signals through the playback head until it is cleaned.
As of 2012, no documented or proven examples of sticky-shed from Maxell. TDK has been showing signs as of late of shedding its lubricant in the form of a white powder or white/yellowish goo. This has shown up on the TDK SA and some LX and BX tapes.. There have been a few reports of some tape from the current manufacturers ATR and RMGI exhibiting symptoms of sticky-shed. But these may be isolated incidents relating to prototype or single bad batches and not necessarily indicative of the overall product line integrity.
BASF tape production did not use the unstable formulation, and their tape production rarely shows this type of coating instability, although BASF LH Super SM cassettes manufactured in the mid-70s are prone to the problem.
As of 2015 some 35mm magnetic fullcoat tapes produced by Kodak, such as those used for the audio portion of older IMAX films, are also reported to be exhibiting sticky-shed. As tapes remain in storage for a longer time, it is possible that other binder formulations may develop problems.
Current solutions to sticky-shed syndrome seek to safely remove the unwanted moisture from the tape binder. Two different strategies are commonly employed: applying heat to the tape (commonly called 'baking'), and changing the environment to lower the humidity. Baking is widely practiced, but can destroy tapes. While modification of humidity by safely controlling the environment may take significantly longer, its major benefit is that it does not irreparably damage the tape. Alternate practices have also been developed by engineers to fix affected tapes.
Baking is a common practice for temporarily repairing sticky-shed syndrome. There is no standard equipment or practice for baking, so each engineer is left to create their own methods and materials. Generally, tapes are baked at low temperatures for relatively long periods of time, such as 130 °F to 140 °F (54 to 60 °C) for 1 to 8 hours. Wider tape formats may take longer. It is commonly thought that baking a tape will temporarily remove the moisture that has accumulated in the binder. A treated tape will reportedly function like new for a few weeks to a few months before it will reabsorb moisture and be unplayable again.
Baking cannot be used with acetate tapes, nor is it needed.
Tape baking is a somewhat risky procedure, since there is a risk of damaging the tape from the heat. However, there are some important signs that show when a tape needs baking. The typical symptom is squealing when the tape passes the playback head or other fixed parts of a tape player. The squealing is audible directly from the tape and also transmitted electronically through the output of the tape recorder. Continuous use of a squealing tape risks permanently damaging the tape, as oxide is sometimes torn off the tape. This flaking residue can be seen and can feel gummy while still on the tape's surface. There is also a risk of damage to the player. Another symptom is the tape sounding dull and distorted. In a video recording, degradation can be represented by audio-visual dropouts.
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- Lots of info on recovering vintage video(tapes)
- Explanation on "sticky-shed" syndrome
- 'Dealing with "sticky-shed syndrome
- List of some specific analog reel tape types and manufacturers known to require baking
- Association of Moving Image Archives on sticky-shed syndrome for Videotape
- Step-by-step guide on tape baking by Dave Luepke
- Cups ‘N Strings saves 50 Record Plant live recordings.
- Master preservation
- Tape Resources Online
- Super Oldies Reel Tape Baking Guide