Technetium(IV) chloride

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Technetium(IV) chloride
TcCl4 structure.png
Names
IUPAC name
Technetium(IV) chloride
Other names
Technetium tetrachloride, Technetium chloride
Identifiers
14215-13-5 YesY
Properties
TcCl4
Molar mass 239.718 g/mol
Boiling point 300 °C (572 °F; 573 K)[1]
Structure
Orthorhombic, oP40
Pbca, No. 61
a = 0.603 nm, b = 1.165 nm, c = 1.406 nm
α = 90°, β = 90°, γ = 90°
Related compounds
Other anions
Technetium(VI) fluoride
Other cations
Manganese(II) chloride
Rhenium(V) chloride
Ruthenium(III) chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
 YesY verify (what isYesY/N?)
Infobox references

Technetium(IV) chloride is the chemical compound composed of technetium and chlorine with the formula TcCl4 which has been investigated as a method of separating technetium from other volatile chlorides.[2] Colloidal solutions of technetium(IV) chloride are oxidized to form Tc(VII) ions when exposed to gamma rays. [3]

Technetium trichloride[edit]

Technetium trichloride TcCl3 was reported in 2010. It was prepared from ditechnetium(III) tetraacetate dichloride and HCl(g) at 300 °C as a black solid and consists of triangular Tc3Cl9 units with C3V symmetry, with each Tc atom coordinated to two Tc neighbors and five chloride ligands (Tc-Tc bond length 2.44 angstrom).[4]

References[edit]

  1. ^ Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5. 
  2. ^ Schwochau, Klaus (2000). Technetium. Wiley-VCH. p. 67. ISBN 3-527-29496-1. 
  3. ^ Fattahi, M.; Vichot, L.; Poineau, F.; Houée-Levin, C.; Grambow, B. (2005). "Speciation of technetium(IV) chloride under gamma irradiation". Radiochimica Acta 93 (7): 409–413. doi:10.1524/ract.2005.93.7.409. 
  4. ^ Poineau, Frederic; Johnstone, Erik V.; Weck, Philippe F.; Kim, Eunja; Forster, Paul M.; Scott, Brian L.; Sattelberger, Alfred P.; Czerwinski, Kenneth R. (2010). "Synthesis and Structure of Technetium Trichloride". Journal of the American Chemical Society 132 (45): 15864–5. doi:10.1021/ja105730e. PMID 20977207.