Thallium(III) nitrate

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Thallium(III) nitrate
Formula of Thallium(III) nitrate.png
Names
IUPAC name
thallium(3+) trinitrate
Identifiers
3D model (JSmol)
ChemSpider
Properties
Tl(NO3)3
Molar mass 390.398
Appearance colorless solid
Melting point 103 °C (217 °F; 376 K)
Boiling point decomposes
decomposes
Hazards
Safety data sheet Mallinckrodt Baker
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Thallium(III) nitrate, also known as thallic nitrate, is a thallium compound with chemical formula Tl(NO3)3.[1] It is normally found as the trihydrate. It is a colorless and highly toxic solid. It is a strong oxidizing agent useful in organic synthesis. Among its many transformations, it oxidizes methoxyl phenols to quinone acetals, alkenes to acetals, and cyclic alkenes to ring-contracted aldehydes.[2]

References[edit]

  1. ^ MSDS for thallium(III) nitrate
  2. ^ Mukund P. Sibi, Luiz F. Silva Jr., Vânia M. T. Carneiro "Thallium(III) Nitrate Trihydrate" Encyclopedia of Reagents for Organic Synthesis 2008 John Wiley & Sons. doi:10.1002/047084289X.rt085.pub2
Salts and covalent derivatives of the Nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)4 C N O FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3 Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)3,
Fe(NO3)2
Co(NO3)2,
Co(NO3)3
Ni(NO3)2 Cu(NO3)2 Zn(NO3)2 Ga(NO3)3 Ge As Se Br Kr
RbNO3 Sr(NO3)2 Y Zr(NO3)4 Nb Mo Tc Ru Rh Pd(NO3)2 AgNO3 Cd(NO3)2 In Sn Sb(NO3)3 Te I Xe(NO3)2
CsNO3 Ba(NO3)2   Hf Ta W Re Os Ir Pt Au Hg2(NO3)2,
Hg(NO3)2
Tl(NO3)3,
TlNO3
Pb(NO3)2 Bi(NO3)3
BiO(NO3)
Po At Rn
FrNO3 Ra(NO3)2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
La(NO3)3 Ce(NO3)3,
Ce(NO3)4
Pr Nd Pm Sm Eu Gd(NO3)3 Tb Dy Ho Er Tm Yb Lu
Ac(NO3)3 Th(NO3)4 Pa UO2(NO3)2 Np Pu Am Cm Bk Cf Es Fm Md No Lr