Thermal grease

From Wikipedia, the free encyclopedia
Jump to navigation Jump to search
Several containers of thermal grease of different brands. From left to right: Arctic Cooling MX-2 and MX-3, Tuniq TX-3, Cool Laboratory Liquid Metal Pro, Shin-Etsu MicroSi G751, Arctic Silver 5, Powdered Diamond. In background Arctic Silver grease remover
Silicone thermal compound
Metal (silver) thermal compound
Metal thermal grease applied to a chip
Thermal grease is designed to fill surface imperfections on CPU, as pictured.

Thermal grease (also called CPU grease, heat paste, heat sink compound, heat sink paste, thermal compound, thermal gel, thermal interface material, or thermal paste) is a thermally conductive (but usually electrically insulating) compound, which is commonly used as an interface between heat sinks and heat sources such as high-power semiconductor devices. The main role of thermal grease is to eliminate air gaps or spaces (which act as thermal insulation) from the interface area in order to maximize heat transfer and dissipation. Thermal grease is an example of a thermal interface material.

As opposed to thermal adhesive, thermal grease does not add mechanical strength to the bond between heat source and heat sink. It will have to be coupled with a mechanical fixation mechanism such as screws, applying pressure between the two, spreading the thermal grease onto the heat source.

Composition[edit]

Thermal grease consists of a polymerizable liquid matrix and large volume fractions of electrically insulating, but thermally conductive filler. Typical matrix materials are epoxies, silicones, urethanes, and acrylates; solvent-based systems, hot-melt adhesives, and pressure-sensitive adhesive tapes are also available. Aluminum oxide, boron nitride, zinc oxide, and increasingly aluminum nitride are used as fillers for these types of adhesives. The filler loading can be as high as 70–80% by mass, and raises the thermal conductivity of the base matrix from 0.17–0.3 W/(m·K) (watts per meter-kelvin) up to about 2 W/(m·K).[1]

Silver thermal compounds may have a conductivity of 3 to 8 W/(m·K) or more, and consist of micronized silver particles suspended in a silicone/ceramic medium. However, metal-based thermal grease can be electrically conductive and capacitive; if some flows onto the circuits, it can cause malfunctioning and damage.

The most effective (and most expensive) pastes consist almost entirely of liquid metal, usually a variation of the alloy galinstan, and have thermal conductivities in excess of 13 W/(m·K). These are difficult to apply evenly and have the greatest risk of causing malfunction due to spillage. These pastes contain gallium, which is highly corrosive to aluminium and cannot be used on aluminium heat sinks.

Uses[edit]

Thermal grease is used to drain away waste heat generated by electrical resistance in semiconductor devices including power transistors, CPUs, GPUs, and LED COBs. Cooling these devices is essential because excess heat rapidly degrades their performance and can cause a runaway to catastrophic failure of the device due to the negative temperature coefficient property of semiconductors.

Factory PCs and laptops (though seldom tablets or smartphones) typically incorporate thermal paste between the top of the CPU case and a heat sink for cooling. Thermal paste is sometimes also used between the CPU die and its integrated heat spreader, though solder is sometimes used instead.

When a CPU heat spreader is coupled to the die via thermal paste, performance enthusiasts such as overclockers are able to, in a process known as "delidding"[2], pry the heat spreader (the CPU "lid") from the die, and replace the thermal paste, which is usually of low-quality, with a thermal paste having greater thermal conductivity. Generally, liquid metal thermal pastes are used in such instances.

Filler properties (at 300 K)[edit]

Compound Thermal conductivity
in W/(m·K)
Electrical resistivity
in Ω·cm
Thermal expansion coefficient
in 10−6 K−1
Refe-
rence
Diamond 020‒2000 1016‒1020 01.18 [3]
Silver 418 18.9 [4]
Aluminum nitride 140‒180 > 1011 04.15 (par), 5.27 (ortho) [5]
β-Boron nitride 100 > 1010 11.9 [5]
Zinc oxide 025.2 [6]
Silicon Carbide 120 04

See also[edit]

References[edit]

  1. ^ Werner Haller; et al. (2007), "Adhesives", Ullmann's Encyclopedia of Industrial Chemistry (7th ed.), Wiley, pp. 58–59.
  2. ^ "What is delidding? - ekwb.com". ekwb.com. 2016-08-25. Retrieved 2018-10-18.
  3. ^ Otto Vohler; et al. (2007), "Carbon", Ullmann's Encyclopedia of Industrial Chemistry (7th ed.), Wiley
  4. ^ Hermann Renner; et al. (2007), "Silver", Ullmann's Encyclopedia of Industrial Chemistry (7th ed.), Wiley, p. 7
  5. ^ a b Peter Ettmayer; Walter Lengauer (2007), "Nitrides", Ullmann's Encyclopedia of Industrial Chemistry (7th ed.), Wiley, p. 5
  6. ^ Hans G. Völz; et al. (2007), "Pigments, Inorganic", Ullmann's Encyclopedia of Industrial Chemistry (7th ed.), Wiley