|Molar mass||266.31 g·mol−1|
|Appearance||Colorless to pale-yellow liquid|
|Melting point||−80 °C (−112 °F; 193 K)|
|Boiling point||289 °C (552 °F; 562 K)|
|1 mL/165 mL water|
|Flash point||146.1 °C (295.0 °F; 419.2 K)|
|US health exposure limits (NIOSH):|
|TWA 5 mg/m3|
Except where noted otherwise, data is given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
|what is: / ?)(|
Tributyl phosphate, known commonly as TBP, is an organophosphorus compound with the chemical formula (CH3CH2CH2CH2O)3PO. This colourless, odorless liquid finds some applications as an extractant and a plasticizer. It is an ester of phosphoric acid with n-butanol.
- POCl3 + 3 C4H9OH → PO(OC4H9)3 + 3 HCl
Production is estimated at 3,000–5,000 tonnes worldwide.
TBP is a solvent and plasticizer for cellulose esters such as nitrocellulose and cellulose acetate. It forms stable hydrophobic complexes with some metals; these complexes are soluble in organic solvents as well as supercritical CO2. The major uses of TBP in industry are as a component of aircraft hydraulic fluid and as a solvent for extraction and purification of rare earth metals from their ores.
As it has no odour, it finds use as anti-foaming agent in detergent solutions, and in various emulsions, paints, and adhesives. It is also found as a defoamer in ethylene glycol-borax antifreeze solutions. In oil-based lubricants addition of TBP increases the oil film strength. It is used also in mercerizing liquids, where it improves their wetting properties. It is also used as a heat exchange medium. TBP is used in some consumer products such as herbicides and water thinned paints and tinting bases.
A 15–40% (usually about 30%) solution of tributyl phosphate in kerosene or dodecane is used in the liquid–liquid extraction (solvent extraction) of uranium, plutonium, and thorium from spent uranium nuclear fuel rods dissolved in nitric acid, as part of a nuclear reprocessing process known as PUREX.
The shipment of 20 tons of tributyl phosphate to North Korea from China in 2002, coinciding with the resumption of activity at Yongbyon Nuclear Scientific Research Center, was seen by the United States and the International Atomic Energy Agency as cause for concern; that amount was considered sufficient to extract enough material for perhaps three to five potential nuclear weapons.
- CDC - NIOSH Pocket Guide to Chemical Hazards
- "NIOSH Pocket Guide to Chemical Hazards #0625". National Institute for Occupational Safety and Health (NIOSH).
- G. R. Dutton and C. R. Noller (1943). "n-Butyl phosphate". Org. Synth.; Coll. Vol. 2, p. 109
- "Tributyl Phosphate | SIDS Initial Assessment Profile". Japan Chemical Industry Ecology-Toxicology & Information Center.
- "Tributyl Phosphate Product Information". Great Vista Chemicals.
- "Tributyl Phosphate". Scorecard.
- "Yongbyon - North Korean Special Weapons Facilities". GlobalSecurity.org.