Volume viscosity (also called bulk viscosity, second coefficient of viscosity, or dilatational viscosity) is a material property relevant for characterizing fluid flow. Common symbols are or . It has dimensions (mass / (length × time)), and the corresponding SI unit is the pascal-second (Pa·s).
Like other material properties (e.g. density, shear viscosity, and thermal conductivity) the value of volume viscosity is specific to each fluid and depends additionally on the fluid state, particularly its temperature and pressure. Physically, volume viscosity represents the irreversible resistance, over and above the reversible resistance caused by isentropic bulk modulus, to a compression or expansion of a fluid. At the molecular level, it stems from the finite time required for energy injected in the system to be distributed among the rotational and vibrational degrees of freedom of molecular motion.
Knowledge of the volume viscosity is important for understanding a variety of fluid phenomena, including sound attenuation in polyatomic gases (e.g. Stokes's law), propagation of shock waves, and dynamics of liquids containing gas bubbles. In many fluid dynamics problems, however, its effect can be neglected. For instance, it is 0 in a monatomic gas at low density, whereas in an incompressible flow the volume viscosity is superfluous since it does not appear in the equation of motion.
Volume viscosity was introduced in 1879 by Sir Horace Lamb in his famous work Hydrodynamics. Although relatively obscure in the scientific literature at large, volume viscosity is discussed in depth in many important works on fluid mechanics, fluid acoustics, theory of liquids, and rheology.
Derivation and use
which depends only on equilibrium state variables like temperature and density (equation of state). In general, the trace of the stress tensor is the sum of thermodynamic pressure contribution and another contribution which is proportional to the divergence of the velocity field. This coefficient of proportionality is called volume viscosity. Common symbols for volume viscosity are and .
where is the shear viscosity coefficient and is the volume viscosity coefficient. The parameters and was originally called the first and second viscosity coefficients, respectively. The operator is the material derivative. By introducing the tensors (matrices) , and , which describes crude shear flow, pure shear flow and compression flow, respectively,
the classic Navier-Stokes equation gets a lucid form.
Note that the term in the momentum equation that contains the volume viscosity disappears for an incompressible fluid because the divergence of the flow equals 0.
There are cases where , which are explained below. In general, moreover, is not just a property of the fluid in the classic thermodynamic sense, but also depends on the process, for example the compression/expansion rate. The same goes for shear viscosity. For a Newtonian fluid the shear viscosity is a pure fluid property, but for a non-Newtonian fluid it is not a pure fluid property due to its dependence on the velocity gradient. Neither shear nor volume viscosity are equilibrium parameters or properties, but transport properties. The velocity gradient and/or compression rate are therefore independent variables together with pressure, temperature, and other state variables.
In compression or expansion, as in any rapid change of state, the fluid ceases to be in thermodynamic equilibrium, and internal processes are set up in it which tend to restore this equilibrium. These processes are usually so rapid(i.e. their relaxation time is so short) that the restoration of equilibrium follows the change in volume almost immediately unless, of course, the rate of change of volume is very large.
He later adds:
It may happen, nevertheless, that the relaxation times of the processes of restoration of equilibrium are long, i.e. they take place comparatively slowly.
After an example, he concludes (with used to represent volume viscosity):
Hence, if the relaxation time of these processes is long, a considerable dissipation of energy occurs when the fluid is compressed or expanded, and, since this dissipation must be determined by the second viscosity, we reach the conclusion that is large.
methanol - 0.8 ethanol - 1.4 propanol - 2.7 pentanol - 2.8 acetone - 1.4 toluene - 7.6 cyclohexanone - 7.0 hexane - 2.4
Recent studies have determined the volume viscosity for a variety of gases, including carbon dioxide, methane, and nitrous oxide. These were found to have volume viscosities which were hundreds to thousands of times larger than their shear viscosities. Fluids having large volume viscosities include those used as working fluids in power systems having non-fossil fuel heat sources, wind tunnel testing, and pharmaceutical processing.
There are many publication dedicated to numerical modeling of the volume viscosity. A detailed review of these studies can be found in Sharma (2019), and Cramer. In the latter study, a number of common fluids were found to have bulk viscosities which were hundreds to thousands of times larger than their shear viscosities.
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- Sharma, B and Kumar, R "Estimation of bulk viscosity of dilute gases using a nonequilibrium molecular dynamics approach.", Physical Review E,100, 013309 (2019)
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