Weaire–Phelan structure

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Weaire–Phelan structure
Space group
Fibrifold notation
Coxeter notation
Pm3n (223)
2o
[[4,3,4]+]

In geometry, the Weaire–Phelan structure is a complex 3-dimensional structure representing an idealised foam of equal-sized bubbles. In 1993, Trinity College Dublin physicist Denis Weaire and his student Robert Phelan found in computer simulations of foam that this structure was a better solution of the "Kelvin problem" than the previous best-known solution, the Kelvin structure.[1]

The Kelvin problem

In 1887, Lord Kelvin asked how space could be partitioned into cells of equal volume with the least area of surface between them, i.e., what was the most efficient bubble foam?[2] This problem has since been referred to as the Kelvin problem.

He proposed a foam, based on the bitruncated cubic honeycomb, which is called the Kelvin structure. This is the convex uniform honeycomb formed by the truncated octahedron, which is a 14-faced space-filling polyhedron (a tetradecahedron), with 6 square faces and 8 hexagonal faces. To conform to Plateau's laws governing the structures of foams, the hexagonal faces of Kelvin's variant are slightly curved.

The Kelvin conjecture is that this structure solves the Kelvin problem: that the foam of the bitruncated cubic honeycomb is the most efficient foam. The Kelvin conjecture was widely believed, and no counter-example was known for more than 100 years, until it was disproved by the discovery of the Weaire–Phelan structure.

In 2009, Ruggero Gabbrielli[3] published a way to use the Swift–Hohenberg equation to find candidate solutions to the Kelvin Problem on minimal surfaces.[4][5]

Description of Weaire–Phelan structure

Irregular dodecahedron

The Weaire–Phelan structure differs from Kelvin's in that it uses two kinds of cells, although they have equal volume.

From a topological and symmetrical point of view, one is a pyritohedron, an irregular dodecahedron with pentagonal faces, possessing tetrahedral symmetry (Th).

Tetrakaidecahedron

The second is a form of truncated hexagonal trapezohedron, a species of tetrakaidecahedron with two hexagonal and twelve pentagonal faces, in this case only possessing two mirror planes and a rotoreflection symmetry.

Like the hexagons in the Kelvin structure, the pentagons in both types of cells are slightly curved. The surface area of the Weaire–Phelan structure is 0.3% less than that of the Kelvin structure. It has not been proved that the Weaire–Phelan structure is optimal. Experiments have also shown that, with favorable boundary conditions, equal-volume bubbles spontaneously self-assemble into the A15 phase, whose atoms coincide with the centroids of the polyhedra in the Weaire–Phelan structure.[6][7]

A close-up of the mold used for the growth of ordered liquid foams.

Polyhedral approximation

The polyhedral honeycomb associated with the Weaire–Phelan structure (obtained by flattening the faces and straightening the edges) is also referred to loosely as the Weaire–Phelan structure. It was known well before the Weaire–Phelan structure was discovered, but the application to the Kelvin problem was overlooked.[8]

It is found in two related geometries of crystal structure in chemistry.

Where the components of the crystal lie at the centres of the polyhedra it forms one of the Frank–Kasper phases.[9]

Where the components of the crystal lie at the corners of the polyhedra, it is known as the "Type I clathrate structure".[citation needed] Gas hydrates formed by methane, propane and carbon dioxide at low temperatures have a structure in which water molecules lie at the nodes of the Weaire–Phelan structure and are hydrogen bonded together, and the larger gas molecules are trapped in the polyhedral cages.[citation needed] Some alkali metal silicides and germanides also form this structure (Si/Ge at nodes, alkali metals in cages), as does the silica mineral melanophlogite (silicon at nodes, linked by oxygen along edges).[citation needed] Melanophlogite is a metastable form of SiO2 that is stabilized in this structure because of gas molecules trapped in the cages. The International Zeolite Association uses the symbol MEP to indicate the framework topology of melanophlogite.[citation needed]

Applications

The Weaire–Phelan structure is the inspiration for the design by Tristram Carfrae of the Beijing National Aquatics Centre, the 'Water Cube', for the 2008 Summer Olympics.[10] The resulting structural support system is inherently strong and lightweight. As all joints in the structure are close to tetrahedral angles, the framework fills a large volume of space with a reduced amount of material, similar to a hexagonal honeycomb in two dimensions.