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The first three papers in 1965<ref>{{Cite journal |last=Gryziński |first=Michał |date=1965-04-19 |title=Two-Particle Collisions. I. General Relations for Collisions in the Laboratory System |url=https://link.aps.org/doi/10.1103/PhysRev.138.A305 |journal=Physical Review |language=en |volume=138 |issue=2A |pages=A305–A321 |doi=10.1103/PhysRev.138.A305 |issn=0031-899X}}</ref><ref>{{Cite journal |last=Gryziński |first=Michał |date=1965-04-19 |title=Two-Particle Collisions. II. Coulomb Collisions in the Laboratory System of Coordinates |url=https://link.aps.org/doi/10.1103/PhysRev.138.A322 |journal=Physical Review |language=en |volume=138 |issue=2A |pages=A322–A335 |doi=10.1103/PhysRev.138.A322 |issn=0031-899X}}</ref> developed a model electron scattering from atoms based on an empirical form for the velocity of electrons in the atom.<ref>{{Cite journal |last=Rudge |first=M. R. H. |date=1968-07-01 |title=Theory of the Ionization of Atoms by Electron Impact |url=https://link.aps.org/doi/10.1103/RevModPhys.40.564 |journal=Reviews of Modern Physics |language=en |volume=40 |issue=3 |pages=564–590 |doi=10.1103/RevModPhys.40.564 |issn=0034-6861}}</ref> These results where widely used for computing cross sections.<ref>{{Cite journal |last=Powell |first=C. J. |date=1976-01-01 |title=Cross sections for ionization of inner-shell electrons by electrons |url=https://link.aps.org/doi/10.1103/RevModPhys.48.33 |journal=Reviews of Modern Physics |language=en |volume=48 |issue=1 |pages=33–47 |doi=10.1103/RevModPhys.48.33 |issn=0034-6861}}</ref>
The first three papers in 1965<ref>{{Cite journal |last=Gryziński |first=Michał |date=1965-04-19 |title=Two-Particle Collisions. I. General Relations for Collisions in the Laboratory System |url=https://link.aps.org/doi/10.1103/PhysRev.138.A305 |journal=Physical Review |language=en |volume=138 |issue=2A |pages=A305–A321 |doi=10.1103/PhysRev.138.A305 |issn=0031-899X}}</ref><ref>{{Cite journal |last=Gryziński |first=Michał |date=1965-04-19 |title=Two-Particle Collisions. II. Coulomb Collisions in the Laboratory System of Coordinates |url=https://link.aps.org/doi/10.1103/PhysRev.138.A322 |journal=Physical Review |language=en |volume=138 |issue=2A |pages=A322–A335 |doi=10.1103/PhysRev.138.A322 |issn=0031-899X}}</ref> developed a model electron scattering from atoms based on an empirical form for the velocity of electrons in the atom.<ref>{{Cite journal |last=Rudge |first=M. R. H. |date=1968-07-01 |title=Theory of the Ionization of Atoms by Electron Impact |url=https://link.aps.org/doi/10.1103/RevModPhys.40.564 |journal=Reviews of Modern Physics |language=en |volume=40 |issue=3 |pages=564–590 |doi=10.1103/RevModPhys.40.564 |issn=0034-6861}}</ref> These results where widely used for computing cross sections.<ref>{{Cite journal |last=Powell |first=C. J. |date=1976-01-01 |title=Cross sections for ionization of inner-shell electrons by electrons |url=https://link.aps.org/doi/10.1103/RevModPhys.48.33 |journal=Reviews of Modern Physics |language=en |volume=48 |issue=1 |pages=33–47 |doi=10.1103/RevModPhys.48.33 |issn=0034-6861}}</ref>
For [[plasma (physics) |plasma]] research the inelastic scattering cross-section for electrons from atoms is needed to understand plasma energy loss mechanisms. The [[Born approximation]] cross sections work for energies above 200 eV; the Gryziński model has been shown match experiment better below 40eV.<ref>Monnin, Carl F., and George M. Prok. Comparison of gryzinski's and born's approximations for inelastic scattering in atomic hydrogen. No. NASA-TN-D-2903. 1965.</ref> Similarly, using exact analytic calculations for hydrogen atoms, the classical Gryzinski model works well at low energy but fails for higher energies.<ref>{{Cite journal |last=Kingston |first=A. E. |date=1964-09-14 |title=Calculation of Cross Sections for Electron Ionization of Atoms Using Classical Mechanics |url=https://link.aps.org/doi/10.1103/PhysRev.135.A1537 |journal=Physical Review |language=en |volume=135 |issue=6A |pages=A1537–A1539 |doi=10.1103/PhysRev.135.A1537 |issn=0031-899X}}</ref>
For [[plasma (physics) |plasma]] research the inelastic scattering cross-section for electrons from atoms is needed to understand plasma energy loss mechanisms. The [[Born approximation]] cross sections work for energies above 200 eV; the Gryziński model has been shown match experiment better below 40eV.<ref>Monnin, Carl F., and George M. Prok. Comparison of gryzinski's and born's approximations for inelastic scattering in atomic hydrogen. No. NASA-TN-D-2903. 1965.</ref> Similarly, using exact analytic calculations for hydrogen atoms, the classical Gryzinski model works well at low energy but fails for higher energies.<ref>{{Cite journal |last=Kingston |first=A. E. |date=1964-09-14 |title=Calculation of Cross Sections for Electron Ionization of Atoms Using Classical Mechanics |url=https://link.aps.org/doi/10.1103/PhysRev.135.A1537 |journal=Physical Review |language=en |volume=135 |issue=6A |pages=A1537–A1539 |doi=10.1103/PhysRev.135.A1537 |issn=0031-899X}}</ref> Numerous extensions of Gryziński's model have been applied to atom-electron impact
ionization.<ref>{{Cite journal |last=Younger |first=S. M. |last2=Märk |first2=T. D. |date=1985 |editor-last=Märk |editor-first=Tilmann D. |editor2-last=Dunn |editor2-first=Gordon H. |title=Semi-Empirical and Semi-Classical Approximations for Electron Ionization |url=http://link.springer.com/10.1007/978-3-7091-4028-4_2 |language=en |location=Vienna |publisher=Springer Vienna |pages=24–41 |doi=10.1007/978-3-7091-4028-4_2 |isbn=978-3-7091-4030-7}}</ref>


The fourth paper in 1965 replaced the empirical velocity distribution with a model based on radial motion of a classical electron.<ref>{{Cite journal |last=Gryziński |first=Michał |date=1965-06-28 |title=Radially Oscillating Electron-the Basis of the Classical Model of the Atom |url=https://link.aps.org/doi/10.1103/PhysRevLett.14.1059 |journal=Physical Review Letters |language=en |volume=14 |issue=26 |pages=1059–1059 |doi=10.1103/PhysRevLett.14.1059 |issn=0031-9007}}</ref> Gryziński's later work all focused on this model.
The fourth paper in 1965 replaced the empirical velocity distribution with a model based on radial motion of a classical electron.<ref>{{Cite journal |last=Gryziński |first=Michał |date=1965-06-28 |title=Radially Oscillating Electron-the Basis of the Classical Model of the Atom |url=https://link.aps.org/doi/10.1103/PhysRevLett.14.1059 |journal=Physical Review Letters |language=en |volume=14 |issue=26 |pages=1059–1059 |doi=10.1103/PhysRevLett.14.1059 |issn=0031-9007}}</ref> Gryziński's later work all focused on this model.

Revision as of 22:39, 19 September 2023

Michał Gryziński
Born(1930-09-29)September 29, 1930
DiedJune 1, 2004(2004-06-01) (aged 73)
Known forFree fall atomic model
Scientific career
FieldsPlasma physics
InstitutionsWarsaw Institute of Experimental Physics
Institute for Nuclear Research, Swierk (Otwock)

Michał Gryziński (29 September 1930 - 1 June 2004) was a Polish nuclear physicist specialized in plasma physics. He is developed the free-fall atomic model, a semiclassical approximation of the electron motion in the atom, averaging over trajectories to reproduce the results of quantum mechanics. His model provided a partial explanation for the Ramsauer effect.

Work

Electron scattering

Michał Gryziński worked in a hot plasma group on an approach to nuclear fusion which has later evolved to what is currently known as dense plasma focus. His experimental and theoretical consideration have led him 1957[1] to emphasize the importance of the orbital motion of electrons of a medium for stopping of slow charged particles. This work led him to a series of articles in 1965 about the problem of scattering with classical approximation of dynamics of the electrons.

The first three papers in 1965[2][3] developed a model electron scattering from atoms based on an empirical form for the velocity of electrons in the atom.[4] These results where widely used for computing cross sections.[5] For plasma research the inelastic scattering cross-section for electrons from atoms is needed to understand plasma energy loss mechanisms. The Born approximation cross sections work for energies above 200 eV; the Gryziński model has been shown match experiment better below 40eV.[6] Similarly, using exact analytic calculations for hydrogen atoms, the classical Gryzinski model works well at low energy but fails for higher energies.[7] Numerous extensions of Gryziński's model have been applied to atom-electron impact ionization.[8]

The fourth paper in 1965 replaced the empirical velocity distribution with a model based on radial motion of a classical electron.[9] Gryziński's later work all focused on this model.

Free-fall atomic model

This classical approximation of the dynamics of electrons in atoms has led him to the free-fall atomic model to improve agreement with scattering experiments comparing to the popular Bohr approximation[citation needed] as circular orbits for electrons. This dominant radial dynamics of electrons makes the atom effectively a pulsating electric multipole (dipole, quadrupole), what allowed him to propose an explanation for the Ramsauer effect (1970) and improve agreement for modeling of low energy scattering (1975). His later articles try to expand these classical approximations to multielectron atoms and molecules.

In 2002 Gryzinski published a book length description of his atomic theory along with related topics.[10] Gryzinski found the Bohr model unsatisfactory, presenting arguments against it,[which?][citation needed], especially for agreement with various scattering scenarios, to focus on nearly zero angular momentum trajectories: with electrons traveling through nearly radial trajectories. Attracted by the Coulomb field they free-fall to the nucleus, then increase the distance up to some turning point and so on.

The free-fall atomic model focuses on Kepler-like orbits for very low angular momentum. They are not exactly ellipses due to adding the magnetic dipole moment of the electron (electron magnetic moment) into considerations, which results in a Lorentz force proportional to and perpendicular to the velocity and spin of the electron. This spin–orbit interaction is nearly negligible unless the electron passes very close to the nucleus (small distance , large speed ). This force bends the trajectory of the electron, preventing any collision with the nucleus.

For simplicity, most of these considerations neglect small changes of orientation of the spin axis of electron, assuming that it is firmly oriented in space - this is called rigid top approximation. The magnetic moment of the nucleus is thousands of times smaller than the electron's, so such hyperfine corrections can be neglected in basic models.

Finally the basic considered Lagrangian for dynamics of a single electron in these models is:

.

The last term describes the interaction between the magnetic field of the traveling electron's magnetic moment and the electric field of the nucleus (spin–orbit interaction).

David Bates and R. Snyder examined the free-fall model and found it unsatisfactory (disagreeing with other models, not experimental data).[11]

Bibliography

References

  1. ^ Gryziński, Michał (1957-09-15). "Stopping Power of a Medium for Heavy, Charged Particles". Physical Review. 107 (6): 1471–1475. doi:10.1103/PhysRev.107.1471. ISSN 0031-899X.
  2. ^ Gryziński, Michał (1965-04-19). "Two-Particle Collisions. I. General Relations for Collisions in the Laboratory System". Physical Review. 138 (2A): A305–A321. doi:10.1103/PhysRev.138.A305. ISSN 0031-899X.
  3. ^ Gryziński, Michał (1965-04-19). "Two-Particle Collisions. II. Coulomb Collisions in the Laboratory System of Coordinates". Physical Review. 138 (2A): A322–A335. doi:10.1103/PhysRev.138.A322. ISSN 0031-899X.
  4. ^ Rudge, M. R. H. (1968-07-01). "Theory of the Ionization of Atoms by Electron Impact". Reviews of Modern Physics. 40 (3): 564–590. doi:10.1103/RevModPhys.40.564. ISSN 0034-6861.
  5. ^ Powell, C. J. (1976-01-01). "Cross sections for ionization of inner-shell electrons by electrons". Reviews of Modern Physics. 48 (1): 33–47. doi:10.1103/RevModPhys.48.33. ISSN 0034-6861.
  6. ^ Monnin, Carl F., and George M. Prok. Comparison of gryzinski's and born's approximations for inelastic scattering in atomic hydrogen. No. NASA-TN-D-2903. 1965.
  7. ^ Kingston, A. E. (1964-09-14). "Calculation of Cross Sections for Electron Ionization of Atoms Using Classical Mechanics". Physical Review. 135 (6A): A1537–A1539. doi:10.1103/PhysRev.135.A1537. ISSN 0031-899X.
  8. ^ Younger, S. M.; Märk, T. D. (1985). Märk, Tilmann D.; Dunn, Gordon H. (eds.). "Semi-Empirical and Semi-Classical Approximations for Electron Ionization". Vienna: Springer Vienna: 24–41. doi:10.1007/978-3-7091-4028-4_2. ISBN 978-3-7091-4030-7. {{cite journal}}: Cite journal requires |journal= (help)
  9. ^ Gryziński, Michał (1965-06-28). "Radially Oscillating Electron-the Basis of the Classical Model of the Atom". Physical Review Letters. 14 (26): 1059–1059. doi:10.1103/PhysRevLett.14.1059. ISSN 0031-9007.
  10. ^ Gryziński, Michał (2002). Sprawa atomu [The case of the atom] (in Polish). Homo-sapiens.
  11. ^ Bates, D. R.; Snyder, R. (1973). "Classical free-fall atomic model". Journal of Physics B: Atomic and Molecular Physics. 6 (7): L159–L160. Bibcode:1973JPhB....6L.159B. doi:10.1088/0022-3700/6/7/001.