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As such, this ratio is a measure of the [[charge density]] at the surface of the ion; usually the denser the charge, the stronger the [[ionic bond|bond]] formed by the ion with ions of opposite charge.<ref>{{Cite web| first=Bruce |last=Railsback| title = Ionic potential| url=http://railsback.org/Fundamentals/IonicPotential04P.pdf|access-date = 16 July 2020|url-status=}}</ref>
As such, this ratio is a measure of the [[charge density]] at the surface of the ion; usually the denser the charge, the stronger the [[ionic bond|bond]] formed by the ion with ions of opposite charge.<ref>{{Cite web| first=Bruce |last=Railsback| title = Ionic potential| url=http://railsback.org/Fundamentals/IonicPotential04P.pdf|access-date = 16 July 2020|url-status=}}</ref>


The ionic potential gives an indication of how strongly, or weakly, the ion will be electrostatically attracted by ions of opposite charge; and to what extent the ion will be repelled by ions of the same charge.
The ionic potential gives an indication of how strongly, or weakly, the ion will be electrostatically attracted by ions of opposite charge; and to what extent the ion will be repelled by ions of the same charge.

Millot (1970) stresses the importance of the ionic potential of cations to explain the high, or the low, [[solubility]] of minerals and the expansive behaviour (swelling/shrinking) of [[clay minerals|clay materials]].<ref name="Millot1970">{{cite book|last1=Millot|first1=Georges|year=1970|title=Geology of clays: weathering – sedimentology – geochemistry|publisher=Springer Science & Business Media|doi=10.1007/978-3-662-41609-9}}</ref>


It is also a measure of the [[Polarizability|polarising power]] of a [[cation]].
It is also a measure of the [[Polarizability|polarising power]] of a [[cation]].

Revision as of 17:59, 16 July 2020

Ionic potential is the ratio of the electrical charge (z) to the radius (r) of an ion.[1]

As such, this ratio is a measure of the charge density at the surface of the ion; usually the denser the charge, the stronger the bond formed by the ion with ions of opposite charge.[2]

The ionic potential gives an indication of how strongly, or weakly, the ion will be electrostatically attracted by ions of opposite charge; and to what extent the ion will be repelled by ions of the same charge.

Millot (1970) stresses the importance of the ionic potential of cations to explain the high, or the low, solubility of minerals and the expansive behaviour (swelling/shrinking) of clay materials.[3]

It is also a measure of the polarising power of a cation.

Ionic potential could be used as a general criterion for the selection of efficient adsorbents for toxic elements.[4]

See also

References

  1. ^ "Ionic potential". A Dictionary of Earth Sciences 1999, originally published by Oxford University Press 1999. Retrieved 17 April 2017.{{cite web}}: CS1 maint: location (link)
  2. ^ Railsback, Bruce. "Ionic potential" (PDF). Retrieved 16 July 2020.
  3. ^ Millot, Georges (1970). Geology of clays: weathering – sedimentology – geochemistry. Springer Science & Business Media. doi:10.1007/978-3-662-41609-9.
  4. ^ Li, Ronghui; Yang, Weiyi; Su, Yu; Li, Qi; Gao, Shian; Shang, Jian Ku (2014). "Ionic potential: A general material criterion for the selection of highly efficient arsenic adsorbents". Journal of Materials Science & Technology. 30 (10): 949–953. doi:10.1016/j.jmst.2014.08.010. ISSN 1005-0302.