Vinyl sulfone: Difference between revisions

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{{Primary sources|date=December 2020}}
{{Primary sources|date=December 2020}}
'''Vinyl sulfone''' is created when a [[vinyl group|vinyl]] group is mated with a [[sulfone]] group. They come in various flavours: [[divinyl]] sulfone,<ref name="divinyl70">{{cite book |last1=Leonard |first1=Edward C. |title=Vinyl and Diene Monomers, Part 3 |date=1970 |publisher=Wiley-Interscience |page=1466}}</ref> [[phenyl]] vinyl sulfone,<ref name="cg52">{{cite book |last1=Gustavson |first1=Clarence |title=Reactions of Phenyl Vinyl Sulfone with Organometallic Reagents |date=1952 |publisher=Syracuse University}}</ref> [[methyl]] vinyl sulfone,<ref name="ntp585">{{cite book |last1=Keith |first1=Lawrence H. |last2=Walters |first2=Douglas B. |title=The National Toxicology Program's Chemical Data Compendium |date=1991 |publisher=CRC Press |edition=Volume 8 |url=https://books.google.ca/books?id=3rmiNPNOe0AC&pg=PA585}}</ref> [[ethyl]] vinyl sulfone,<ref name="ethyl70">{{cite book |last1=Leonard |first1=Edward C. |title=Vinyl and Diene Monomers, Part 3 |date=1970 |publisher=Wiley-Interscience |page=1475}}</ref> and [[peptide]] vinyl sulfone<ref name="cyr05">{{cite book |editor1-last=Patterson |editor1-first=Cam |editor2-last=Cyr |editor2-first=Douglas M. |title=Ubiquitin-Proteasome Protocols |date=2005 |publisher=Springer Science & Business Media |page=PA7 |url=https://books.google.ca/books?id=qv3ok4y7-j0C&pg=PA7}}</ref> amongst others.
'''Vinyl sulfone''' is created when a [[vinyl group|vinyl]] group is mated with a [[sulfone]] group. They come in various flavours: [[divinyl]] sulfone,<ref name="divinyl70">{{cite book |last1=Leonard |first1=Edward C. |title=Vinyl and Diene Monomers, Part 3 |date=1970 |publisher=Wiley-Interscience |page=1466}}</ref> [[phenyl]] vinyl sulfone,<ref name="cg52">{{cite book |last1=Gustavson |first1=Clarence |title=Reactions of Phenyl Vinyl Sulfone with Organometallic Reagents |date=1952 |publisher=Syracuse University}}</ref> [[methyl]] vinyl sulfone,<ref name="ntp585">{{cite book |last1=Keith |first1=Lawrence H. |last2=Walters |first2=Douglas B. |title=The National Toxicology Program's Chemical Data Compendium |date=1991 |publisher=CRC Press |isbn=9780873717229 |edition=Volume 8 |url=https://books.google.com/books?id=3rmiNPNOe0AC&pg=PA585}}</ref> [[ethyl]] vinyl sulfone,<ref name="ethyl70">{{cite book |last1=Leonard |first1=Edward C. |title=Vinyl and Diene Monomers, Part 3 |date=1970 |publisher=Wiley-Interscience |page=1475}}</ref> and [[peptide]] vinyl sulfone<ref name="cyr05">{{cite book |editor1-last=Patterson |editor1-first=Cam |editor2-last=Cyr |editor2-first=Douglas M. |title=Ubiquitin-Proteasome Protocols |date=2005 |publisher=Springer Science & Business Media |page=PA7 |isbn=9781592598953 |url=https://books.google.com/books?id=qv3ok4y7-j0C&pg=PA7}}</ref> amongst others.


==Uses==
==Uses==
Vinyl sulfone has uses as a [[molluscicide]] [[pesticide]].<ref name="epapest">{{cite book |title=Pesticides Abstracts |date=1975 |publisher=U.S. Environmental Protection Agency, Office of Pesticide Programs, Program Support Division}}</ref>
Vinyl sulfone has uses as a [[molluscicide]] [[pesticide]].<ref name="epapest">{{cite book |title=Pesticides Abstracts |date=1975 |publisher=U.S. Environmental Protection Agency, Office of Pesticide Programs, Program Support Division}}</ref>


Phenyl vinyl sulfone has been applied to [[ruthenium]] chemistry as part of [[alkene]] [[metathesis reaction|metathesis]].<ref name="bruneau05">{{cite book |last1=Bruneau |first1=Christian |last2=Dixneuf |first2=Pierre H. |title=Ruthenium Catalysts and Fine Chemistry |date=2004 |publisher=Springer Science & Business Media |url=https://books.google.ca/books?id=6UP05zXC5ioC&pg=PA101}}</ref>
Phenyl vinyl sulfone has been applied to [[ruthenium]] chemistry as part of [[alkene]] [[metathesis reaction|metathesis]].<ref name="bruneau05">{{cite book |last1=Bruneau |first1=Christian |last2=Dixneuf |first2=Pierre H. |title=Ruthenium Catalysts and Fine Chemistry |date=2004 |publisher=Springer Science & Business Media |isbn=9783540205432 |url=https://books.google.com/books?id=6UP05zXC5ioC&pg=PA101}}</ref>


Vinyl sulfone has applications to [[protein purification]], especially when linked with [[mercaptoethanol]].<ref name="scopes93">{{cite book |last1=Scopes |first1=Robert K. |title=Protein Purification: Principles and Practice |date=1993 |publisher=Springer Science & Business Media |page=184 |url=https://books.google.ca/books?id=byi_lK0gk6cC&pg=PA184}}</ref>
Vinyl sulfone has applications to [[protein purification]], especially when linked with [[mercaptoethanol]].<ref name="scopes93">{{cite book |last1=Scopes |first1=Robert K. |title=Protein Purification: Principles and Practice |date=1993 |publisher=Springer Science & Business Media |page=184 |isbn=9780387940724 |url=https://books.google.com/books?id=byi_lK0gk6cC&pg=PA184}}</ref>


[[Vinyl sulfone dyes]] are used in [[reactive dye]] chemistry.<ref name="eiri05">{{cite book |title=Research In Technology Of Synthetic Dyes, Pigments And Intermediates |date=2005 |publisher=Engineers India |url=https://books.google.ca/books?id=c98gNFmnnYAC&pg=PA274}}</ref>
[[Vinyl sulfone dyes]] are used in [[reactive dye]] chemistry.<ref name="eiri05">{{cite book |title=Research In Technology Of Synthetic Dyes, Pigments And Intermediates |date=2005 |publisher=Engineers India |isbn=9788186732519 |url=https://books.google.com/books?id=c98gNFmnnYAC&pg=PA274}}</ref>


==References==
==References==

Revision as of 03:56, 25 December 2020

Vinyl sulfone is created when a vinyl group is mated with a sulfone group. They come in various flavours: divinyl sulfone,[1] phenyl vinyl sulfone,[2] methyl vinyl sulfone,[3] ethyl vinyl sulfone,[4] and peptide vinyl sulfone[5] amongst others.

Uses

Vinyl sulfone has uses as a molluscicide pesticide.[6]

Phenyl vinyl sulfone has been applied to ruthenium chemistry as part of alkene metathesis.[7]

Vinyl sulfone has applications to protein purification, especially when linked with mercaptoethanol.[8]

Vinyl sulfone dyes are used in reactive dye chemistry.[9]

References

  1. ^ Leonard, Edward C. (1970). Vinyl and Diene Monomers, Part 3. Wiley-Interscience. p. 1466.
  2. ^ Gustavson, Clarence (1952). Reactions of Phenyl Vinyl Sulfone with Organometallic Reagents. Syracuse University.
  3. ^ Keith, Lawrence H.; Walters, Douglas B. (1991). The National Toxicology Program's Chemical Data Compendium (Volume 8 ed.). CRC Press. ISBN 9780873717229.
  4. ^ Leonard, Edward C. (1970). Vinyl and Diene Monomers, Part 3. Wiley-Interscience. p. 1475.
  5. ^ Patterson, Cam; Cyr, Douglas M., eds. (2005). Ubiquitin-Proteasome Protocols. Springer Science & Business Media. p. PA7. ISBN 9781592598953.
  6. ^ Pesticides Abstracts. U.S. Environmental Protection Agency, Office of Pesticide Programs, Program Support Division. 1975.
  7. ^ Bruneau, Christian; Dixneuf, Pierre H. (2004). Ruthenium Catalysts and Fine Chemistry. Springer Science & Business Media. ISBN 9783540205432.
  8. ^ Scopes, Robert K. (1993). Protein Purification: Principles and Practice. Springer Science & Business Media. p. 184. ISBN 9780387940724.
  9. ^ Research In Technology Of Synthetic Dyes, Pigments And Intermediates. Engineers India. 2005. ISBN 9788186732519.
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