Speculum metal is a mixture of around two-thirds copper and one-third tin making a white brittle alloy that can be polished to make a highly reflective surface. It is used primarily to make different kinds of mirrors including early reflecting telescope optical mirrors. Speculum metal can also be used as the metallic coating on glass mirrors (as opposed to silver or aluminium) giving a reflectivity of 68% at 6000 angstroms when evaporated onto the surface.
Speculum metal mixtures usually contain two parts copper to one part tin along with a small amount of arsenic, although there are other mixtures containing silver, brass, lead, or zinc. The knowledge of making very hard white high luster metal out of bronze-type high-tin alloys may date back more than 2000 years in China although it could also be an invention of western civilizations as well. Such metals were used in sculpture and to make more effective mirrors than the more common yellow easily tarnishing bronze mirrors. In that era mirrors of speculum metal, or any precious metal, were rare and only owned by the wealthy 
Speculum and telescopes
Speculum metal found an application in early modern Europe as the only known good reflecting surface for mirrors in reflecting telescopes. Such telescopes needed first surface mirrors that could be ground and polished into complex shapes such as parabolic reflectors. For nearly 200 years speculum metal was the only mirror substance that could perform this task. One of the earliest designs, James Gregory’s Gregorian telescope could not be built because Gregory could not find a craftsman capable of fabricating the complex speculum mirrors needed for the design. Isaac Newton was the first to successfully build a reflecting telescope in 1668. His first reflecting telescope (a design which came to be known as a Newtonian reflector) had a 33-mm (1.3-inch) diameter speculum metal primary mirror of his own formulation. Newton again faced the problem of fabricating the complex parabolic shape needed to create the image and settled on a simple spherical shape. The composition of speculum metal was further refined and went on to be used in the 1700s and 1800s in many designs of reflecting telescopes. The ideal composition was around 68.21% copper to 31.7 % tin, more copper made the metal more yellow, more tin made the metal more blue in color. Ratios with up to 45% tin were used for resistance to tarnishing.
Although speculum metal mirror reflecting telescopes could be built very large, such as William Herschel's 126-cm (49.5-inch) "40-foot telescope" of 1789 and Lord Rosse 1845 183-cm (72-inch) mirror of his "Leviathan of Parsonstown", impracticalities in using the metal made most astronomers prefer their smaller refracting telescope counterparts. Speculum metal was very hard to cast and shape. It only reflected 66 percent of the light that hit it. Speculum also had the unfortunate property of tarnishing in open air with a sensitivity to humidity, requiring constant re-polishing to maintain its usefulness. This meant the telescopes mirrors had to be constantly removed, polished, and re-figured to the correct shape. This sometimes proved difficult, with some mirrors having to be abandoned. It also required that two or more mirrors had to be fabricated for each telescope so that one could be used while the other was being polished. Rapidly cooling night time air would cause stresses in large speculum metal mirrors, distorting their shape and causing them to produce poor images. Lord Rosse had a system of adjustable levers on his 72-inch metal mirror so he could adjust the shape but it was hit or miss at producing an acceptable image.
In 1856-57 an improvement over speculum mirrors was invented when Karl August von Steinheil and Léon Foucault introduced the process of depositing an ultra thin layer of silver (silvering) on the front surface (first surface) of glass telescope mirrors. Silvered glass mirrors were a vast improvement since silver reflects 90 percent of the light that hits it and is much slower to tarnish than speculum. Silver coatings can also be removed from glass without changing the delicate shape of the glass substrate. Glass was also more thermally stable than speculum metal, allowing it to hold its shape better through temperature changes. This marked the end of the speculum-mirror reflecting telescope, with the last large one, the Great Melbourne Telescope with its 122-cm (48-inch) mirror, being completed in 1867. The era of the large glass-mirror reflector had begun, with telescopes such as Andrew Ainslie Common's 1879 36 inch (91 cm) and 1887 60 inch (152 cm) reflectors built at Ealing, and the first of the "modern" large glass mirror research reflectors, 60 inch (150 cm) Mount Wilson Observatory Hale telescope of 1908, and the 100 inch (2.5 m) Mount Wilson Hooker telescope in 1917.
- "Original mirror for William Herschel's forty-foot telescope, 1785". Science Museum. Retrieved 2008-11-23.
- by Joseph Needham, Gwei-djen Lu, Science and civilisation in China, Volume 5, page 238
- The Journal of the Anthropological Institute of Great Britain and Ireland - Volume 64 - Page 71
- Albert Allis, The Scientific American cyclopedia of formulas, page 89
- A Biographical Dictionary of Eminent Scotsmen By Robert Chambers, Thomas - Page 175
- The History of the Telescope By Henry C. King, Page 74
- Speculum Metal.
- Pettit, E., Astronomical Society of the Pacific Leaflets, Vol. 7, p.249 (SAO/NASA Astrophysics Data System (ADS))
- Voyage through the universe: The Visible Universe. Copyright Time-Life Books, 1990 web clip
- Pettit, E., Astronomical Society of the Pacific Leaflets, Vol. 7, p.249
|Wikimedia Commons has media related to Speculum metal.|