Zirsilite-(Ce)
| Zirsilite-(Ce) | |
|---|---|
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| General | |
| Category | Cyclosilicate |
| Formula (repeating unit) | (Na,□)12(Ce,Na)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)·H2O (original form) |
| IMA symbol | Zir-Ce[1] |
| Strunz classification | 9.CO.10 |
| Dana classification | 64.1.5 |
| Crystal system | Trigonal |
| Crystal class | Ditrigonal pyramidal (3m) H-M symbol: (3m) |
| Space group | R3m |
| Unit cell | a = 14.25, c = 30.08 [Å] (approximated); Z = 3 |
| Identification | |
| Color | Creamy white |
| Crystal habit | rhombohedra (rims of zoned crystals) |
| Cleavage | None |
| Fracture | Conchoidal |
| Tenacity | Brittle |
| Mohs scale hardness | 5 |
| Luster | Vitreous |
| Streak | White |
| Diaphaneity | Transparent |
| Density | 3.15 (measured) |
| Optical properties | Uniaxial (-) |
| Refractive index | nω=1.65, nε=1.64 (approximated) |
| Pleochroism | None |
| Ultraviolet fluorescence | No |
| References | [2][3] |
Zirsilite-(Ce) is a very rare mineral of the eudialyte group, with formula (Na,□)12(Ce,Na)3Ca6Mn3Zr3NbSi(Si9O27)2(Si3O9)2O(OH)3(CO3)·H2O.[2][3] The original formula was extended to show the presence of cyclic silicate groups and the presence of silicon at the M4 site, according to the nomenclature of the eudialyte group.according to the nomenclature of eudialyte group.[4] Zirsilite-(Ce) differs from carbokentbrooksite in cerium-dominance over sodium only. Both minerals are intimately associated.[2][3] The only other currently known representative of the eudialyte group having rare earth elements (in particular cerium, as suggested by the "-Ce)" Levinson suffix in the name[5]) in dominance is johnsenite-(Ce).[2]
Occurrence and association
Zirsilite-(Ce) and carbokentbrooksite occur in pegmatites of Darai-Pioz alkaline massif, Tajikistan - a locality known for many rare minerals.[6] They are found as replacements of grains and crystals of eudialyte.[2] The minerals are associated with aegirine, ekanite, microcline, polylithionite, quartz, stillwellite-(Ce) (silicates), pyrochlore-group mineral, fluorite, calcite, and galena.[3]
Notes on chemistry
Beside the elements given in the formula, zirsilite-(Ce) contains admixtures of lanthanum, strontium, neodymium, iron, yttrium, titanium, potassium, chlorine, and praseodymium.[3]
Notes on structure
Zirsilite-(Ce) is isostructural with kentbrooksite.[3]
References
- ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
- ^ a b c d e Mindat, Zirsilite-(Ce), http://www.mindat.org/min-25674.html
- ^ a b c d e f Khomyakov, A.P., Dusmatov, V.D., Ferraris, G., Gula, A., Ivaldi, G., and Nechelyustov, G.N., 2003: Zirsilite-(Ce), (Na,□)12(Ce,Na)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)·H2O, and carbokentbrooksite (Na,□)12(Na,Ce)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)·H2O - two new eudialyte-group minerals from the Dara-i-Pioz alkaline massif, Tajikistan. Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva 132(5), 40–51 (in Russian, with English abstract); in: Jambor, J.I, and Roberts, A.C., 2004: New mineral names. American Mineralogist 89(11-12), 1826-1834
- ^ Johnsen, O., Ferraris, G., Gault, R.A., Grice, D.G., Kampf, A.R., and Pekov, I.V., 2003. The nomenclature of eudialyte-group minerals. The Canadian Mineralogist 41, 785-794
- ^ Hatert, F., Mills, S.J., Pasero, M., and Williams, P.A., 2013. CNMNC guidelines for the use of suffixes and prefixes in mineral nomenclature, and for the preservation of historical names. European Journal of Mineralogy 25, 113-115
- ^ "Darai-Pioz Glacier (Dara-i-Pioz; Dara-Pioz), Alai Range (Alayskiy), Tien Shan Mtn, Region of Republican Subordination, Tajikistan - Mindat.org". Mindat.org. Retrieved 2016-03-11.