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Inglis-Teller limit
<div style="position: absolute; top: 4em; right: 5cm;"><font size="20" face="impact"><i>[[User_talk:DJIndica|My talk]]</i></font></div>


The linear [[Stark shift]] is given by
User:Iridescent


:<math>\Delta E_\text{S} = \frac{3}{2}er_nF,</math>
<area shape=circle coords="0,0,50">


where e is the [[elementary charge]], radius of the ''n''<sup>th</sup> electron orbit in the [[Bohr model]] of the [[hydrogen atom]] and ''F'' is the component of the local [[electric field]] parallel with the electric dipole. The energy of the ''n''<sup>th</sup> electron orbit is simply the [[Coulomb potential energy]] with ''r'' = ''r<sub>n</sub>''
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:<math>U_n = -\dfrac{1}{4\pi\varepsilon_0}\dfrac{e^2}{r_n} = -\left(\dfrac{e^2}{4\pi\varepsilon_0\hbar}\right)^2\dfrac{m_e}{n^2},</math>
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giving an energy level spacing


:<math>\Delta U_n = \left(\dfrac{e^2}{4\pi\varepsilon_0\hbar}\right)^2\dfrac{2m_e}{n^2}.</math>


The Inglis-Teller limit is defined as the field strength at which the Stark states with |(''n''<sub>1</sub> - ''n''<sub>2</sub>)| = n are shifted by half of this spacing, Δ''E''<sub>S</sub> = Δ''U''<sub>''n''</sub>/2,


:<math>\rightarrow F = </math>







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RABI FREQUENCY

The '''Rabi frequency''' is an important quantity in [[First quantization|semi-classical]] [[atomic physics]]. For a given atomic transition in a given light field, the Rabi frequency represents the coupling strength between the (classical) light and the (quantum) transition. [[Rabi flopping]] between the levels of a 2-level system illuminated with resonant light, will occur at the Rabi frequency.

[[Image:Sine cosine plot.svg|thumb|right|290px|Rabi flopping in a 2-level system [[Media:Sine cosine plot.svg|Actual size]]]]

== Definition ==

:<math> \chi_{ij} = {\vec{d}_{ij}.\vec{E}_0 \over \hbar}</math>

where

:<math>\vec{d}_{i,j}</math> is the [[transition dipole moment]] for the <math>i \rightarrow j</math> transition.

:<math>\vec{E}_0 = \hat{\epsilon}E_0</math> is the [[vector]] [[electric field]] [[amplitude]] which includes the [[polarization]].

The numerator has dimensions of energy, dividing by <math>\hbar</math> gives an [[angular frequency]]. As <math>\vec{d}_{ij} = \vec{d}_{ji}^*</math>, we have <math>\chi_{ij} = \chi_{ji}^*</math>.

By analogy with a [[Classical physics|classical]] [[dipole]], it is clear that an atom with a large dipole moment will be more susceptible to perturbation by [[Electric field|electric]] and [[Magnetic field|magnetic]] fields. The [[dot product]] includes a factor of <math>\cos\theta</math>, where <math>\theta</math> is the angle between the polarization of the light and the transition dipole moment. When they are parallel or antiparallel the interaction is strongest, when they are perpendicular there is no interaction at all. The vector electric field amplitude defines both the intensity and the polarization of the light.

== Generalized Rabi frequency ==

For light that is off resonance with a transition, it is common to define the ''generalized Rabi frequency'' <math>\Omega_{i,j}</math>. [[Rabi flopping]] actually occurs at the generalized Rabi frequency.

:<math>\Omega_{i,j} = \sqrt{|\chi_{i,j}|^2 + \Delta^2}</math>

where <math>\Delta = \omega_{light} - \omega_{transition}</math> is the ''detuning'', a measure of how far the light is off resonance with the transition.

== Derivation ==

We start with the [[Hamiltonian]] for a 2-level system with frequency splitting <math>\omega_0</math>, illuminated by a light field with frequency <math>\omega</math>

:<math>\hat{H} = \begin{pmatrix}
{\hbar \omega_0 \over 2} & \chi_{21}e^{i\omega t/2}\\
\chi_{12}e^{-i\omega t/2} & -{\hbar \omega_0 \over 2}
\end{pmatrix}
</math>

with a wavefunction for the system (in the [[interaction picture]]) given by

:<math>|\Psi\rangle = c_1(t)|1\rangle + c_2(t)|2\rangle</math>

We can write the [[Schrödinger equation|time-dependent Schrödinger equation]] in the form

:<math>\dot{c}(t) = {1 \over i\hbar}\hat{H}c(t)</math>

And solve using the [[rotating wave approximation]], giving a probability of being in states <math>|1\rangle</math> and <math>|2\rangle</math>

:<math>P_1 = \left({\chi_{21} \over \Omega_{21}}\right)^2 \sin^2\left({\Omega_{21} \over 2}t\right)</math>

:<math>P_2 = 1 - \left({\chi_{21} \over \Omega_{21}}\right)^2 \sin^2\left({\Omega_{21} \over 2}t\right)</math>

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Revision as of 06:32, 30 November 2009

Inglis-Teller limit

The linear Stark shift is given by

where e is the elementary charge, radius of the nth electron orbit in the Bohr model of the hydrogen atom and F is the component of the local electric field parallel with the electric dipole. The energy of the nth electron orbit is simply the Coulomb potential energy with r = rn

giving an energy level spacing

The Inglis-Teller limit is defined as the field strength at which the Stark states with |(n1 - n2)| = n are shifted by half of this spacing, ΔES = ΔUn/2,