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Calcite

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This is an old revision of this page, as edited by Coylabe (talk | contribs) at 16:06, 17 June 2006 (Changed "only calcite effervescences with acids" to "all carbonate or bicarbonate salts do so"). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

Doubly refracting Calcite from Iceberg claim, Dixon, New Mexico. This 35 pound crystal, on display at the National Museum of Natural History, is one of the largest single crystals in the United States.

The carbonate mineral calcite is a calcium carbonate corresponding to the formula CaCO3 and is one of the most widely distributed minerals on the Earth's surface. It is a common constituent of sedimentary rocks, limestone in particular. It is also the primary mineral in metamorphic marble. It also occurs as a vein mineral in deposits from hot springs, and also occurs in caverns as stalactites and stalagmites. Calcite is often the primary constituent of the shells of marine organisms, e.g., plankton (such as coccoliths and planktic foraminifera), the hard parts of red algae, some sponges, Brachiopoda, echinoderms, most Bryozoa, and parts of the shells of some bivalves, such as oysters and rudists). Calcite represents the stable form of calcium carbonate; aragonite will change to calcite at 470°C.

Properties

Calcite crystals are hexagonal-rhombohedral, though actual calcite rhombohedrons are rare as natural crystals. However, they show a remarkable variety of habit including acute to obtuse rhombohedrons, tabular forms, prisms, or various scalenohedrons. Calcite exhibits several twinning types adding to the variety of observed forms. It may occur as fibrous, granular, lamellar, or compact. Cleavage is usually in three directions parallel to the rhombohedron form. Its fracture is conchoidal, but difficult to obtain.

It has a Mohs hardness of 3, a specific gravity of 2.71, and its luster is vitreous in crystallized varieties. Colour is white or colourless, though shades of gray, red, yellow, green, blue, violet, brown, or even black can occur when the mineral is charged with impurities. Calcite is transparent to opaque and may occasionally show phosphorescence or fluorescence. It is perhaps best known because of its power to produce strong double refraction of light, such that objects viewed through a clear piece of calcite appear doubled in all of their parts - a phenomenon first described by Rasmus Bartholin. A beautifully transparent variety used for optical purposes comes from Iceland, called Iceland spar. Acute scalenohedral crystals are sometimes referred to as "dogtooth spar".

Reactions

Calcite, when heated, will decompose to calcium oxide and carbon dioxide, according to the reaction:

CaCO3→CaO + CO2

Calcite also reacts when in contact with dilute acid of a pH lower than 5.4, causing effervescence and the release of carbon dioxide gas. All carbonate or bicarbonate salts do so, making them easily identified by this acid test.


See also

Wikimedia Commons has media related to Calcite.
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