Scheil equation

In metallurgy, the Scheil-Gulliver equation (or Scheil equation) describes solute redistribution during solidification of an alloy.

Solidification of a binary Cu Zn alloy, lever rule, with composition of 30% of Zinc in weight, using open version of Computherm Pandat.

Solidification -using the Scheil lever -  of a binary Cu Zn alloy, at composition Zn in weight 30% using free version of Computherm Pandat software

Solidification of a binary Cu Zn alloy, with composition of 30% of Zinc in weight, using open version of Computherm Pandat. Red line is folowing lever rule, while Scheil model applies to the blue one

Assumptions

Four key assumptions in Scheil analysis enable determination of phases present in a cast part. These assumptions are:

1. No diffusion occurs in solid phases once they are formed ($\ D_{S}=0$)
2. Infinitely fast diffusion occurs in the liquid at all temperatures by virtue of a high diffusion coefficient, thermal convection, Marangoni convection, etc. ($\ D_{L}=\infty$)
3. Equilibrium exists at the solid-liquid interface, and so compositions from the phase diagram are valid
4. Solidus and liquidus are straight segments

The fourth condition (straight solidus/liquidus segments) may be relaxed when numerical techniques are used, such as those used in CALPHAD software packages, though these calculations rely on calculated equilibrium phase diagrams. Calculated diagrams may include odd artifacts (i.e. retrograde solubility) that influence Scheil calculations.

Derivation

The hatched areas in the figure represent the amount of solute in the solid and liquid. Considering that the total amount of solute in the system must be conserved, the areas are set equal as follows:

$(C_{L}-C_{S})\ df_{S}=(f_{L})\ dC_{L}$.

Since the partition coefficient (related to solute distribution) is

$k={\frac {C_{S}}{C_{L}}}$ (determined from the phase diagram)

and mass must be conserved

$\ f_{S}+f_{L}=1$

the mass balance may be rewritten as

$C_{L}(1-k)\ df_{S}=(1-f_{S})\ dC_{L}$.

Using the boundary condition

$\ C_{L}=C_{o}$ at $\ f_{S}=0$

the following integration may be performed:

$\displaystyle \int _{0}^{f_{S}}{\frac {df_{S}}{1-f_{S}}}={\frac {1}{1-k}}\displaystyle \int _{C_{o}}^{C_{L}}{\frac {dC_{L}}{C_{L}}}$.

Integrating results in the Scheil-Gulliver equation for composition of the liquid during solidification:

$\ C_{L}=C_{o}(f_{L})^{k-1}$

or for the composition of the solid:

$\ C_{S}=kC_{o}(1-f_{S})^{k-1}$.

Applications of the Scheil equation: Calphad Tools for the Metallurgy of Solidification

Nowdayas, several Calphad softwares are available - in a framework of computational thermodynamics - to simulate solidification in systems with more than two components; these have recently been defined as Calphad Tools for the Metallurgy of Solidification. In recent years, Calphad-based methodologies have reached maturity in several important fields of metallurgy, and especially in solidification-related processes such as semi-solid casting, 3d printing, and welding, to name a few. While there are important studies devoted to the progress of Calphad methodology, there is still space for a systematization of the field, which proceeds from the ability of most Calphad-based software to simulate solidification curves and includes both fundamental and applied studies on solidification, to be substantially appreciated by a wider community than today.The three applied fields mentioned above could be widened by specific successful examples of simple modeling related to the topic of this issue, with the aim of widening the application of simple and effective tools related to Calphad and Metallurgy. See also "Calphad Tools for the Metallurgy of Solidification" in an ongoing issue of an Open Journal. https://www.mdpi.com/journal/metals/special_issues/Calphad_Solidification

Given a specific chemical composition, using a software for computational thermodyamics - which might be open or commercial - the calculation of the Scheil curve is possible if a thermodynamic database is available. A good point in favour of some specific commercial softwares is that the install is easy indeed and you can use it on a windows based system - for instance with students or for self training.

One should get some open databases (extension *.tdb), one could find - after registering - at Computational Phase Diagram Database (CPDDB) of the National Institute for Materials Science of Japan, NIMS. They are available - for free - and the collection is rather complete; in fact currently 507 binary systems are available in the thermodynamic data base (tdb) format. Some wider and more specific alloy systems partly open - with tdb compatible format - are available with minor corrections for Pandat use at Matcalc

References

• Gulliver, G.H., J. Inst. Met., 9:120, 1913.
• Kou, S., Welding Metallurgy, 2nd Edition, Wiley -Interscience, 2003.
• Porter, D. A., and Easterling, K. E., Phase Transformations in Metals and Alloys (2nd Edition), Chapman & Hall, 1992.
• Scheil, E., Z. Metallk., 34:70, 1942.
• Karl B. Rundman Principles of Metal Casting Textbook - Michigan Technological University
• H. Fredriksson, Y. Akerlind, Materials Processing during Casting, Chapter 7, Wiley:Hoboken, 2006.

External Links

• "Scheil Solidification Simulation of 332.1 Foundry Aluminium Alloy, Thermocalc Youtube Channel". Retrieved 12 January 2020.

• "Computational Phase Diagram Database of the National Institute for Materials Science of Japan, NIMS". Retrieved 12 January 2020.

• "Special Issue "Calphad Tools for the Metallurgy of Solidification"".