Barium sulfite: Difference between revisions
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{{chembox |
{{chembox |
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| verifiedrevid = |
| verifiedrevid = 455116033 |
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| Name = Barium sulfite |
| Name = Barium sulfite |
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| ImageFile = |
| ImageFile = Barium sulfite.svg |
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| ImageSize = |
| ImageSize =240px |
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| ImageName = |
| ImageName = Structure of barium sulfite |
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| IUPACName = Barium sulfite |
| IUPACName = Barium sulfite |
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| OtherNames = |
| OtherNames = |
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|Section1={{Chembox Identifiers |
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| CASNo = 7787-39-5 |
| CASNo = 7787-39-5 |
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| CASNo_Ref = |
| CASNo_Ref = {{cascite|correct|??}} |
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| CASNoOther = |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| UNII = D71W8VF49C |
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| ChemSpiderID = 450991 |
| ChemSpiderID = 450991 |
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| SMILES = [Ba+2].[O-]S([O-])=O |
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| InChI = 1/Ba.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+2;/p-2 |
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| InChIKey = ARSLNKYOPNUFFY-NUQVWONBAA |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChI = 1S/Ba.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+2;/p-2 |
| StdInChI = 1S/Ba.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+2;/p-2 |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = ARSLNKYOPNUFFY-UHFFFAOYSA-L |
| StdInChIKey = ARSLNKYOPNUFFY-UHFFFAOYSA-L |
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| RTECS = |
| RTECS = |
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| EINECS = |
| EINECS = |
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}} |
}} |
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|Section2={{Chembox Properties |
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| Formula = BaSO<sub>3</sub> |
| Formula = BaSO<sub>3</sub> |
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| MolarMass = 217.391 g/mol |
| MolarMass = 217.391 g/mol |
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| Density = 4.44 g/cm<sup>3</sup> |
| Density = 4.44 g/cm<sup>3</sup> |
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| MeltingPt = decomposes |
| MeltingPt = decomposes |
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| BoilingPt = |
| BoilingPt = |
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| Solubility = 0.0011 g/100 mL |
| Solubility = 0.0011 g/100 mL |
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| SolubleOther = insoluble in [[ethanol]]<ref name="hand"> |
| SolubleOther = insoluble in [[ethanol]]<ref name="hand"> |
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| last = Lide |
| last = Lide |
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| first = David R. |
| first = David R. |
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| author-link = |
| author-link = |
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| last2 = |
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| first2 = |
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| author2-link = |
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| publication-date = |
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| date = |
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| year = 1998 |
| year = 1998 |
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| title = Handbook of Chemistry and Physics |
| title = Handbook of Chemistry and Physics |
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| edition = 87 |
| edition = 87 |
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| volume = |
| volume = |
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| series = |
| series = |
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| location = Boca Raton, Florida |
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| place = |
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| publisher = CRC Press |
| publisher = CRC Press |
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| id = |
| id = |
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| oclc = |
| oclc = |
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| pages = 4–45 |
| pages = 4–45 |
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| url = |
| url = |
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| accessdate = |
| accessdate = |
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}}</ref> |
}}</ref> |
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}} |
}} |
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|Section3={{Chembox Structure |
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| Coordination = |
| Coordination = |
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| CrystalStruct = |
| CrystalStruct = |
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}} |
}} |
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|Section7={{Chembox Hazards |
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| ExternalSDS = |
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| NFPA-H = |
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| NFPA-H = |
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| NFPA-F = |
| NFPA-F = |
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| NFPA-R = |
| NFPA-R = |
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| FlashPt = |
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| SPhrases = |
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| FlashPt = |
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}} |
}} |
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|Section8={{Chembox Related |
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| OtherAnions = [[Barium sulfate]]<br/>[[Barium fluoride]]<br/>[[Barium chloride]]<br/>[[Barium bromide]]<br/>[[Barium iodide]] |
| OtherAnions = [[Barium sulfate]]<br/>[[Barium fluoride]]<br/>[[Barium chloride]]<br/>[[Barium bromide]]<br/>[[Barium iodide]] |
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| OtherCations = [[Calcium sulfite]]<br/>[[Magnesium sulfite]] |
| OtherCations = [[Calcium sulfite]]<br/>[[Magnesium sulfite]] |
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'''Barium sulfite''' is the [[ |
'''Barium sulfite''' is the [[inorganic compound]] with the [[chemical formula]] BaSO<sub>3</sub>. It is a white powder that finds few applications. It is an intermediate in the [[carbothermal reduction]] of [[barium sulfate]] to [[barium sulfide]]:<ref>{{Ullmann |doi=10.1002/14356007.a03_325.pub2|title=Barium and Barium Compounds|year=2007|last1=Kresse|first1=Robert|last2=Baudis|first2=Ulrich|last3=Jäger|first3=Paul|last4=Riechers|first4=H. Hermann|last5=Wagner|first5=Heinz|last6=Winkler|first6=Jochen|last7=Wolf|first7=Hans Uwe|isbn=978-3527306732}}</ref> |
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:{{chem2 | BaSO4 + CO -> BaSO3 + CO2 }} |
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It may be formed by the action of [[sulfur dioxide]] on [[barium oxide]] or [[barium hydroxide]]. |
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==References== |
==References== |
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{{ |
{{reflist}} |
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{{Barium compounds}} |
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{{Sulfites}} |
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[[Category:Barium compounds]] |
[[Category:Barium compounds]] |
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[[Category:Sulfites]] |
[[Category:Sulfites]] |
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[[ja:亜硫酸バリウム]] |
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