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add info from 1905 NIE
 
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{{chembox
{{chembox
| Verifiedfields = changed
| verifiedrevid = 370213683
| verifiedrevid = 433643349
| ImageFile = Beta-1,3-1,4-glucan.png
| ImageFile = Beta-1,3-1,4-glucan.png
| ImageSize = 200px
| IUPACName =
| IUPACName =
| OtherNames = Lichenan; Moss starch
| OtherNames = Lichenan; Moss starch
| Section1 = {{Chembox Identifiers
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 1402-10-4
| CASNo = 1402-10-4
| UNII_Ref = {{fdacite|correct|FDA}}
| PubChem =
| UNII = M7F3LRN53I
| ChEBI_Ref = {{ebicite|changed|EBI}}
| ChEBI = 6452
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| ChemSpiderID = none
| PubChem = 439241
| PubChem_Comment = monomer
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| Section2 = {{Chembox Properties
|Section2={{Chembox Properties
| Formula = (C<sub>6</sub>H<sub>10</sub>O<sub>5</sub>)<sub>x</sub>
| Formula = (C<sub>6</sub>H<sub>10</sub>O<sub>5</sub>)<sub>x</sub>
| MolarMass = Variable
| MolarMass = Variable
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| BoilingPt =
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| Solubility = }}
| Section3 = {{Chembox Hazards
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'''Lichenin''', also known as '''lichenan''' or '''moss starch''', is a complex [[glucan]] occurring in certain species of [[lichen]]s. It can be extracted from ''Cetraria islandica'' ([[Iceland moss]]).<ref>{{cite journal | coauthors = Perlin AS, Suzuki S | year = 1962 | title = The Structure Of Lichenin: Selective Enzymolysis Studies | journal = [[Canadian Journal of Chemistry]] | volume = 40 | issue = 1 | pages = 50–56 | publisher = [[National Research Council of Canada]] | location = Canada | doi = 10.1139/v62-009 | author = Perlin, A.S. }}</ref> It has been studied since about 1957.<ref>{{cite journal | coauthors = Cunningham WL, Manners DJ | year = 1964 | month = March | title = Studies on carbohydrate-metabolizing enzymes. 11. The hydrolysis of lichenin by enzyme preparations from malted barley and Rhizopus arrhizus | journal = The Biochemical journal | volume = 90 | issue = 3 | pages = 596–602 | publisher = Published by Portland Press on behalf of the Biochemical Society | location = England | issn = 0264-6021 | pmid = 5833367 | last1 = Cunningham | first1 = WL | pmc = 1202740}}</ref> Chemically, lichenin consists of repeating [[glucose]] units linked by β-1,3 and β-1,4 glycosidic bonds.<ref>{{cite journal | title = The Structure of Lichenin: Selective Enzymolysis Studies | author = A.S. Perlin and S. Suzuki | journal = Canadian Journal of Chemistry | volume = 40 | pages = 50–56 | doi = 10.1139/v62-009 | year = 1962}}</ref>
'''Lichenin''', also known as '''lichenan''' or '''moss starch''', is a complex [[glucan]] occurring in certain species of [[lichen]]s. It can be extracted from ''Cetraria islandica'' ([[Iceland moss]]).<ref name="PerlinSuzuki">{{cite journal |last1=Perlin |first1=A. S. |last2=Suzuki |first2=S. |year=1962 |title=The Structure of Lichenin: Selective Enzymolysis Studies |journal=[[Canadian Journal of Chemistry]] |volume=40 |issue=1 |pages=50–56 |publisher=[[National Research Council of Canada]] |location=Canada |doi=10.1139/v62-009|doi-access=free }}</ref> It has been studied since about 1957.<ref>{{cite journal |last1=Cunningham |first1=WL |last2=Manners |first2=DJ |date=March 1964 |title=Studies on carbohydrate-metabolizing enzymes. 11. The hydrolysis of lichenin by enzyme preparations from malted barley and Rhizopus arrhizus |journal=The Biochemical Journal |volume=90 |issue=3 |pages=596–602 |publisher=Portland Press on behalf of the Biochemical Society |location=England |issn=0264-6021 |pmid=5833367 |pmc=1202740 |doi=10.1042/bj0900596}}</ref>


== Structure ==
It is an important carbohydrate for [[reindeer]]s and [[northern flying squirrel]]s, which eat the lichen [[wila]].
Chemically, lichenin is a [[mixed-linkage glucan]], consisting of repeating [[glucose]] units linked by β-1,3 and β-1,4 glycosidic bonds.<ref name="PerlinSuzuki" />


== Uses ==
It can be extracted by digesting Iceland moss in a cold, weak solution of [[sodium bicarbonate|carbonate of soda]] for some time, and then boiling. By this process the lichenin is dissolved and on cooling separates as a colorless jelly. [[Iodine]] imparts no color to it.<ref>{{Cite NIE|Lichenin|year=1905|vb=1}}</ref>
It is an important carbohydrate for [[reindeer]]s and [[northern flying squirrel]]s, which eat the lichen ''[[Bryoria fremontii]]''.

It can be extracted by digesting Iceland moss in a cold, weak solution of [[sodium bicarbonate|carbonate of soda]] for some time, and then boiling. By this process the lichenin is dissolved and on cooling separates as a colorless jelly. [[Iodine]] imparts no color to it.<ref>{{NIE|wstitle=Lichenin|year=1905|inline=1}}</ref>


==Other uses of the name==
==Other uses of the name==
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[[Category:Polysaccharides]]
[[Category:Polysaccharides]]
[[Category:Lichens]]
[[Category:Lichen products]]




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