Dibromochloromethane: Difference between revisions
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| verifiedrevid = 414418191 |
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| ImageFile = Dibromochloromethane.png |
| ImageFile = Dibromochloromethane.png |
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| ImageFile_Ref = {{chemboximage|correct|??}} |
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| ImageSize = 100 |
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| ImageName = Skeletal formula of dibromochloromethane |
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| OtherNames = chlorodibromomethane, monochlorodibromomethane, CDBM |
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| ImageFile1_Ref = {{chemboximage|correct|??}} |
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| ImageSize1 = 100 |
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| ImageName1 = Spacefill model of dibromochloromethane |
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| PIN = Dibromo(chloro)methane <!-- Parentheses are used according to Subsection P-16.5.1.3 of Nomenclature of Organic Chemistry – IUPAC Recommendations and Preferred Names 2013 (Blue Book) --> |
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| OtherNames = {{unbulleted list|Dibromochloromethane|Chlorodibromomethane{{citation needed|date=June 2012}}|Monochlorodibromomethane{{citation needed|date=June 2012}} |
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| Abbreviations = CDBM{{citation needed|date=June 2012}} |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| UNII = 3T4AJR1H24 |
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| ChemSpiderID = 29036 |
| ChemSpiderID = 29036 |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| InChIKey = GATVIKZLVQHOMN-UHFFFAOYAQ |
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| KEGG = C14692 |
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| KEGG_Ref = {{keggcite|correct|kegg}} |
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| MeSHName = chlorodibromomethane |
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| ChEMBL = 157093 |
| ChEMBL = 157093 |
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| ChEMBL_Ref = {{ebicite|correct|EBI}} |
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| RTECS = PA6360000 |
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| Beilstein = 1731046 |
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| StdInChI = 1S/CHBr2Cl/c2-1(3)4/h1H |
| StdInChI = 1S/CHBr2Cl/c2-1(3)4/h1H |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = GATVIKZLVQHOMN-UHFFFAOYSA-N |
| StdInChIKey = GATVIKZLVQHOMN-UHFFFAOYSA-N |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| C=1 | H=1 | Br=2 | Cl=1 |
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| InChI = 1/CHBr2Cl/c2-1(3)4/h1H |
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| MeltingPtC = -22 |
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| BoilingPtC = 119 to 120 |
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| BoilingPt_notes = at 99.7 kPa |
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| LogP = 2.206 |
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| HenryConstant = 8.6 μmol Pa<sup>−1</sup> kg<sup>−1</sup> |
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| Formula = CHBr<sub>2</sub>Cl |
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| RefractIndex = 1.547 |
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| MagSus = -75.1·10<sup>−6</sup> cm<sup>3</sup>/mol |
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| MeltingPt = -22 °C |
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| GHSPictograms = {{gHS exclamation mark}} |
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| BoilingPt = 119-120 °C |
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| GHSSignalWord = '''WARNING''' |
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| Solubility = |
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| HPhrases = {{h-phrases|302}} |
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| LD50 = 370 mg kg<sup>−1</sup> <small>(oral, rat)</small> |
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| MainHazards = Harmful ('''Xn''') |
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|Section4={{Chembox Related |
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| RPhrases = {{R22}} |
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| OtherFunction_label = alkanes |
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| SPhrases = |
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| OtherFunction = {{unbulleted list|[[Chloromethane]]|[[Chloroiodomethane]]|[[Bromochloromethane]]}} |
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| FlashPt = |
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| OtherCompounds = [[2-Chloroethanol]] |
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| Autoignition = |
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'''Dibromochloromethane''' is a colorless to yellow, heavy and nonflammable [[Compound (chemistry)|compound]] with formula {{chem|C|H|Br|2|Cl}}.<ref>{{cite web|title=Dibromochloromethane|url=http://www.sigmaaldrich.com/catalog/product/aldrich/206326?lang=en®ion=RU|website=[[Sigma Aldrich]]|publisher=sigmaaldrich.com|accessdate=7 June 2017}}</ref><ref>{{cite web|title=Public Health Statement for Bromoform and Dibromochloromethane|url=https://www.atsdr.cdc.gov/phs/phs.asp?id=711&tid=128|publisher=atsdr.cdc.gov|accessdate=7 June 2017}}</ref> It is a [[trihalomethane]]. |
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'''Dibromochloromethane''' is a [[Compound (chemistry)|compound]] with formula CHBr<sub>2</sub>Cl. It is a [[trihalomethane]]. |
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The substance has a sweet odour.<ref>{{cite web|title=BROMOFORM AND DIBROMOCHLOROMETHANE|url=https://www.atsdr.cdc.gov/toxfaqs/tfacts130.pdf|publisher=atsdr.cdc.gov|accessdate=7 June 2017}}</ref> Small quantities of dibromochloromethane are produced in ocean by algae.{{cn|date=November 2022}} |
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==Applications== |
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Dibromochloromethane was formerly used as a flame retardant and as an intermediate in chemicals manufacturing. Today it is used only as a laboratory reagent. |
Dibromochloromethane was formerly used as a flame retardant and as an intermediate in chemicals manufacturing. Today it is used only as a laboratory reagent. Dibromochloromethane is also a disinfection byproduct, formed by the reaction of chlorine with natural organic matter and bromide ions in the raw water supply. As a result, it is commonly found in chlorinated drinking water. |
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Also, it is able to reduce methane production in ruminants by 79 %<ref>[https://www.researchgate.net/publication/299274346_Identification_of_bioactives_from_the_red_seaweed_Asparagopsis_taxiformis_that_promote_antimethanogenic_activity_in_vitro Identification of bioactives from the red seaweed Asparagopsis taxiformis that promote antimethanogenic activity in vitro]</ref> |
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==See also== |
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Small quantities of dibromochloromethane are produced in ocean by algae. |
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* [[Asparagopsis taxiformis]] |
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==References== |
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{{reflist}} |
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==External links== |
==External links== |
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* [http://www.greenfacts.org/glossary/def/dibromochloromethane.htm Dibromochlormethane in greenfacts.org glossary] |
* [http://www.greenfacts.org/glossary/def/dibromochloromethane.htm Dibromochlormethane in greenfacts.org glossary] |
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* [http://www.epa.gov/iris/subst/0222.htm Dibromochloromethane toxicological review] |
* [http://www.epa.gov/iris/subst/0222.htm Dibromochloromethane toxicological review] |
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* [ |
* [https://www.atsdr.cdc.gov/toxfaqs/tfacts130.pdf ToxFAQ for bromoform at ATSDR] |
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{{ |
{{halomethanes}} |
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[[Category:Organochlorides]] |
[[Category:Organochlorides]] |
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[[Category:Organobromides]] |
[[Category:Organobromides]] |
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{{organic-compound-stub}} |
{{organic-compound-stub}} |
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[[ja:ジブロモクロロメタン]] |