Ammonium cerium(IV) sulfate: Difference between revisions

{{Chembox

| Verifiedfields = changed

| verifiedrevid = 422716405

| CASNo_Ref = {{cascite|correct|??}}

| PubChem = 71308344

| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}

| ChemSpiderID = 17339565

| InChI=1S/Ce.4H3N.4H2O4S.2H2O/c;;;;;4*1-5(2,3)4;;/h;4*1H3;4*(H2,1,2,3,4);2*1H2/q+4;;;;;;;;;;/p-4

| InChIKey = VCNAMBGKEDPVGQ-UHFFFAOYSA-J

| SMILES = [Ce+4].[O-]S(=O)(=O)[O-].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.O.O.[NH4+].[NH4+].[NH4+].[NH4+]

}}

| Formula = H₂₀N₄S₄O₁₈Ce

| MolarMass = 632.55 g/mol

| Appearance = Orange-colored solid

| MeltingPtC = 130

| Solubility = soluble in water

| MainHazards = Irritant

| NFPA-S = OX

| NFPA-F = 1

| NFPA-H = 2

| NFPA-R =

| FlashPt =

| GHSPictograms = {{GHS07}}

| GHSSignalWord= Warning

| HPhrases = {{H-phrases|315|319|335}}

| PPhrases = {{P-phrases|261|262|264|280|302+352|305+351+338|314|362|332+313|337+313}}<ref name=sds>{{cite web|title = Cerium(IV) Ammonium Sulfate Dihydrate|url = https://www.americanelements.com/cerium-iv-ammonium-sulfate-dihydrate-10378-47-9|publisher = [[American Elements]]|accessdate = September 13, 2018|archive-date = September 14, 2018|archive-url = https://web.archive.org/web/20180914024020/https://www.americanelements.com/cerium-iv-ammonium-sulfate-dihydrate-10378-47-9|url-status = live}}</ref>

| AutoignitionPt =

}}

| Section4 = {{Chembox Related

| OtherCompounds = [[Cerium(IV) sulfate]], [[Ceric ammonium nitrate]]

'''Ammonium cerium(IV) sulfate''' is an [[inorganic compound]] with the formula (NH₄)₄Ce(SO₄)₄·2H₂O. It is an orange-colored solid. It is a strong oxidant, the potential for reduction is about +1.44V. [[Cerium(IV) sulfate]] is a related compound.

==Structure==

A crystallographic study shows that the compound contains the Ce₂(SO₄)₈⁸⁻ anion, where the cerium atoms are 9 coordinated by oxygen atoms belonging to sulfate groups, in a distorted tricapped trigonal prism. The compound is thus sometimes formulated as (NH₄)₈[Ce₂(SO₄)₈]·4H₂O.<ref name="ShanHuang1998">{{cite journal|last1=Shan|first1=Y.|last2=Huang|first2=S. D.|title=(NH₄)₈[Ce₂(SO₄)₈]•4H₂O|journal=Acta Crystallographica Section C|volume=54|issue=12|year=1998|pages=1744–1745|issn=0108-2701|doi=10.1107/S0108270198007057|pmid=9921692|bibcode=1998AcCrC..54.1744S }}</ref>

[[File:Dicerium-octasulfate-ion-from-ammonium-cerium(IV)-sulfate-tetrahydrate-xtal-3D-bs-17.png|250px|Structure of the [Ce₂(SO₄)₈]⁸⁻ ion in the crystal structure of ammonium cerium(IV) sulfate dihydrate]]

==References==

<references/>

{{Cerium compounds}}

{{Ammonium salts}}

[[Category:Cerium(IV) compounds]]

[[Category:Sulfates]]

[[Category:Ammonium compounds]]

[[Category:Oxidizing agents]]