Aluminium nitrate: Difference between revisions
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{{distinguish|Aluminium nitride}} |
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{{chembox |
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| ImageFile = Aluminium nitrate.png |
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<!-- | ImageSize = 200px --> |
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| verifiedrevid = 449203454 |
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| ImageFile = Aluminium nitrate.png |
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| ImageFile1 = Dusičnan hlinitý.JPG |
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| ImageSize = 150px |
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| IUPACName = Aluminium nitrate |
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| ImageFile1 = Dusičnan hlinitý.JPG |
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| OtherNames = Nitric acid, aluminum salt <br> aluminum nitrate <br> aluminium(III) nitrate |
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| IUPACName = Aluminium nitrate |
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| Section1 = {{Chembox Identifiers |
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| OtherNames = Nitric Aluminum salt <br /> aluminum nitrate <br /> aluminium(III) nitrate |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| Section1 = {{Chembox Identifiers |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID = 24267 |
| ChemSpiderID = 24267 |
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| InChI = 1/Al.3NO3/c;3*2-1(3)4/q+3;3*-1 |
| InChI = 1/Al.3NO3/c;3*2-1(3)4/q+3;3*-1 |
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| StdInChIKey = JLDSOYXADOWAKB-UHFFFAOYSA-N |
| StdInChIKey = JLDSOYXADOWAKB-UHFFFAOYSA-N |
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| CASNo = 13473-90-0 |
| CASNo = 13473-90-0 |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| CASNo2_Ref = {{cascite|correct|CAS}} |
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| CASOther = <br/>7784-27-2 (nonahydrate) |
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| CASNo2 = 7784-27-2 |
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| CASNo2_Comment = (nonahydrate) |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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}} |
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| UNII = HUO854648Y |
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| Section2 = {{Chembox Properties |
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| UNII2_Ref = {{fdacite|correct|FDA}} |
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| Appearance = White crystals |
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| UNII2 = 8MC6621V1H |
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| Formula = Al(NO<sub>3</sub>)<sub>3</sub> |
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| UNII2_Comment = (nonhydrate) |
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| MolarMass = 212.996 g/mol (anhydrous) <br> 375.134 g/mol (nonahydrate) |
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| PubChem = 26053 |
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| Appearance = white solid <br> [[hygroscopic]] |
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| RTECS = BD1040000 (anhydrous) <br /> BD1050000 (nonahydrate) |
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| Odor = odorless |
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| EC_number = 236-751-8 |
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| Density = 1.72 g/cm<sup>3</sup> (nonahydrate) |
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| UNNumber = 1438 |
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| Solubility = ''anhydrous:'' <br> 60.0 g/100 mL (0°C) <br> 73.4 g/100 mL (20 °C) <br> 160 g/100 mL (100 °C) <hr> ''nonahydrate:'' <br> 67.3 g/100 mL |
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}} |
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| Solubility1 = 14.45 g/ 100mL |
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| Section2 = {{Chembox Properties |
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| Solvent1 = methanol |
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| Formula = Al(NO<sub>3</sub>)<sub>3</sub> |
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| Solubility2 = 8.63 g/ 100mL |
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| MolarMass = 212.996 g/mol (anhydrous) <br /> 375.134 g/mol (nonahydrate) |
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| Solvent2 = ethanol |
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| Appearance = White crystals, solid <br /> [[hygroscopic]] |
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| Solubility3 = 18.32 g/100 mL |
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| Odor = odorless |
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| Solvent3 = ethylene glycol |
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| Density = 1.72 g/cm<sup>3</sup> (nonahydrate) |
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| MeltingPtC = 72.8 |
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| Solubility = ''anhydrous:'' <br /> 60.0 g/100ml (0°C) <br /> 73.9 g/100ml (20 °C) <br /> 160 g/100ml (100 °C) <br /> ''nonahydrate:'' <br /> 67.3 g/100 mL |
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| Melting_notes = nonahydrate |
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| Solubility1 = 14.45 g/100ml |
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| BoilingPtC = 135 |
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| Solvent1 = methanol |
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| Boiling_notes = nonahydrate, decomp. |
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| Solubility2 = 8.63 g/100ml |
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| RefractIndex = 1.54 |
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| Solvent2 = ethanol |
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| Solubility3 = 18.32 g/100ml |
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| pKb = |
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| Solvent3 = ethylene glycol |
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| Viscosity = |
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| MeltingPtC = 66 |
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}} |
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| MeltingPt_notes = (anhydrous)<ref>{{cite web|url=http://chemister.ru/Database/properties-en.php?dbid=1&id=8810|title=aluminum nitrate}}</ref> <br /> {{convert|73.9|C|F K}} (nonahydrate) |
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| Section7 = {{Chembox Hazards |
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| BoilingPtC = 150 |
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| ExternalMSDS = [http://physchem.ox.ac.uk/MSDS/AL/aluminium_nitrate_nonahydrate.html External MSDS] |
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| BoilingPt_notes = (nonahydrate) decomposes |
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| MainHazards = |
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| RefractIndex = 1.54 |
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| FlashPt = 135 °C (nonahydrate) |
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| pKa = |
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| pKb = |
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| Viscosity = |
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| NFPA-H = 2 | NFPA-F = 0 | NFPA-R = 1 | NFPA-O = OX |
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}} |
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| LD50 = 4280 mg/kg, oral (rat) |
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| Section7 = {{Chembox Hazards |
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}} |
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| ExternalSDS = [https://beta-static.fishersci.com/content/dam/fishersci/en_US/documents/programs/education/regulatory-documents/sds/chemicals/chemicals-a/S25148A.pdf External MSDS] |
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| MainHazards = |
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| FlashPtC = 35 |
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| FlashPt_notes = (nonahydrate) |
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| NFPA-H = 2 | NFPA-F = 0 | NFPA-R = 1 | NFPA-S = OX |
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| LD50 = 4280 mg/kg, oral (rat) |
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| IDLH = N.D.<ref name=PGCH>{{PGCH|0024}}</ref> |
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| PEL = none<ref name=PGCH /> |
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| REL = 2 mg/m<sup>3</sup><ref name=PGCH /> |
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| GHSPictograms = {{GHS03}}{{GHS05}}{{GHS06}}{{GHS07}}{{GHS08}} |
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| GHSSignalWord = Danger |
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| HPhrases = {{H-phrases|271|272|301|315|318|319|361}} |
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| PPhrases = {{P-phrases|201|202|210|220|221|264|270|280|281|283|301+310|302+352|305+351+338|306+360|308+313|310|321|330|332+313|337+313|362|370+378|371+380+375|405|501}} |
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'''Aluminium nitrate''' is a [[Salt (chemistry)|salt]] of [[aluminium]] and [[nitric acid]], |
'''Aluminium nitrate''' is a white, water-soluble [[Salt (chemistry)|salt]] of [[aluminium]] and [[nitric acid]], most commonly existing as the crystalline [[hydrate]], aluminium nitrate nonahydrate, Al(NO<sub>3</sub>)<sub>3</sub>·9H<sub>2</sub>O. |
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==Preparation== |
== Preparation == |
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Aluminium nitrate |
Aluminium nitrate cannot be synthesized by the reaction of aluminium with concentrated nitric acid, as the aluminium forms a [[Passivation (chemistry)|passivation]] layer. |
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Aluminium nitrate |
Aluminium nitrate may instead be prepared by the reaction of [[nitric acid]] with [[Aluminium chloride|aluminium(III) chloride]]. [[Nitrosyl chloride]] is produced as a by-product; it bubbles out of the solution as a gas. More conveniently, the salt can be made by reacting [[nitric acid]] with [[aluminium hydroxide]]. |
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Aluminium nitrate may also be prepared a metathesis reaction between [[aluminium sulfate]] and a nitrate salt with a suitable cation such as barium, strontium, calcium, silver, or lead. e.g. Al<sub>2</sub>(SO<sub>4</sub>)<sub>3</sub> + 3 Ba(NO<sub>3</sub>)<sub>2</sub> → 2 Al(NO<sub>3</sub>)<sub>3</sub> + 3 BaSO<sub>4</sub>. |
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Aluminum nitrate nonahydrate can also be made by adding a [[lead nitrate]] solution to an [[aluminum sulfate]] solution. The insoluble [[lead sulfate]] is precipitated out of the solution, leaving a solution of aluminum nitrate. |
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==Uses== |
== Uses == |
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Aluminium nitrate is a strong oxidizing agent. It is used in tanning leather, antiperspirants, corrosion |
Aluminium nitrate is a strong oxidizing agent. It is used in [[Tanning (leather)|tanning]] leather, [[deodorant|antiperspirants]], [[corrosion inhibitor]]s, extraction of [[uranium]], [[oil refinery|petroleum refining]], and as a [[nitration|nitrating]] agent. |
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The nonahydrate and other hydrated |
The nonahydrate and other hydrated aluminium nitrates have many applications. These salts are used to produce [[alumina]] for preparation of insulating [[paper]]s, in [[cathode ray tube]] heating elements, and on [[transformer]] core laminates. The hydrated salts are also used for the extraction of [[actinide]] elements.<ref>Pradyot Patnaik. ''Handbook of Inorganic Chemicals''. McGraw-Hill, 2002, {{ISBN|0-07-049439-8}}.</ref> |
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It is used in the laboratory and classroom such as in the reaction |
It is used in the laboratory and classroom such as in the reaction |
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: Al(NO<sub>3</sub>)<sub>3</sub> + 3 NaOH → Al(OH)<sub>3</sub> + 3 NaNO<sub>3</sub> |
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It is, however, much less often encountered than aluminium chloride and aluminium sulfate. |
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== References == |
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Al(NO<sub>3</sub>)<sub>3</sub> + 3NaOH → Al(OH)<sub>3</sub> + 3NaNO<sub>3</sub> |
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==References== |
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{{reflist}} |
{{reflist}} |
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==External links== |
== External links == |
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* [https://web.archive.org/web/20150704002145/http://avogadro.chem.iastate.edu/MSDS/Al(NO3)3-9H2O.htm MSDS of nonahydrate] |
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* http://www.eol.ucar.edu/~beaton/ChemWeb/worksheets/rxnws.html |
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* [http://avogadro.chem.iastate.edu/MSDS/Al(NO3)3-9H2O.htm MSDS of nonahydrate] |
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* [http://www.chemicalsubstanceschimiques.gc.ca/fact-fait/alum-salts-sels-eng.php Government of Canada Fact Sheets and Frequently Asked Questions: Aluminum Salts] |
* [http://www.chemicalsubstanceschimiques.gc.ca/fact-fait/alum-salts-sels-eng.php Government of Canada Fact Sheets and Frequently Asked Questions: Aluminum Salts] |
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{{Aluminium compounds}} |
{{Aluminium compounds}} |
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{{nitrates}} |
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{{Authority control}} |
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[[Category:Aluminium compounds]] |
[[Category:Aluminium compounds]] |
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[[Category:Nitrates]] |
[[Category:Nitrates]] |
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[[Category:Deliquescent |
[[Category:Deliquescent materials]] |
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[[Category:Oxidizing agents]] |
[[Category:Oxidizing agents]] |
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{{inorganic-compound-stub}} |
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[[ar:نترات الألومنيوم]] |
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[[de:Aluminiumnitrat]] |
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[[fa:آلومینیم نیترات]] |
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[[fr:Nitrate d'aluminium]] |
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[[it:Nitrato di alluminio]] |
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[[nl:Aluminiumnitraat]] |
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[[ja:硝酸アルミニウム]] |
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[[pl:Azotan(V) glinu]] |
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[[ru:Нитрат алюминия]] |
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[[sv:Aluminiumnitrat]] |
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[[zh:硝酸铝]] |