Aluminon: Difference between revisions

Page 1
Page 2
Content deleted Content added
CheMoBot (talk | contribs)
Updating {{chembox}} (no changed fields - added verified revid - updated 'DrugBank_Ref', 'UNII_Ref', 'ChEMBL_Ref', 'ChEBI_Ref', 'KEGG_Ref', 'ChEBI_Ref') per Chem/Drugbox validation (report [[Wikipedia_talk:WikiProject_Chemicals|error
corrected charge on scandium ion
 
(21 intermediate revisions by 18 users not shown)
Line 1: Line 1:
{{chembox
{{chembox
| verifiedrevid = 417209238
| verifiedrevid = 451147151
| Name = Aluminon
| Name = Aluminon
| OtherNames = ammonium aurin-tricarboxylate; 5-[(3-carboxy-4-hydroxyphenyl)(3-carboxy-4-oxo-2,5-cyclohexadien-ylidene)methyl]-2-hydroxybenzoic acid triammonium salt
| OtherNames = ammonium aurin-tricarboxylate; 5-[(3-carboxy-4-hydroxyphenyl)(3-carboxy-4-oxo-2,5-cyclohexadien-ylidene)methyl]-2-hydroxybenzoic acid triammonium salt
| ImageFile = Aluminon.svg
| ImageFile = Aluminon.svg
| ImageSize = 200px
| ImageSize = 200px
| ImageAlt = Skeletal formula of aluminon
| ImageFile1 = Aluminon_ions_spacefill.png
| ImageAlt1 = Space-filling models of the ions in aluminon
| ImageFile2 = Aqueous aluminon.jpg
| Section1 = {{Chembox Identifiers
| Section1 = {{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
Line 15: Line 19:
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = AIPNSHNRCQOTRI-UHFFFAOYSA-N
| StdInChIKey = AIPNSHNRCQOTRI-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 569-58-4
| CASNo = 569-58-4
| UNII_Ref = {{fdacite|correct|FDA}}
| PubChem = 2734958
| UNII = 23J05NR06D
| PubChem = 54729869
| EINECS = 209-319-1
}}
}}
| Section2 = {{Chembox Properties
| Section2 = {{Chembox Properties
Line 25: Line 33:
| SolubleOther = freely soluble in H<sub>2</sub>O
| SolubleOther = freely soluble in H<sub>2</sub>O
}}
}}
| Section7 = {{Chembox Hazards
| GHSPictograms = {{GHS07}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|315|319}}
| PPhrases = {{P-phrases|264|280|302+352|305+351+338|321|332+313|337+313|362}}
}}
}}
}}


'''Aluminon''', the tri[[ammonium]] salt of [[aurintricarboxylic acid]], is a dye commonly used to detect the presence of the aluminium ion in an aqueous solution. In addition to its use in [[qualitative inorganic analysis]], aluminon has applications in pharyngeal aerosols. It forms brilliantly colored [[lake pigments]] with [[aluminum]], [[chromium]], [[iron]], and [[beryllium]].
'''Aluminon''', the tri[[ammonium]] salt of [[aurintricarboxylic acid]], is a dye often used to detect the presence of the aluminium ion in an aqueous solution. Aluminon forms a red [[complex salt]] in combination with Al<sup>3+</sup>.<ref name=":0" />
[[File:Lake pigment made from aluminon and ferric ions.jpg|left|thumb|Deep purple pigment in a neutral aqueous solution. Made from aluminon and ferric (Fe<sup>3+</sup>) ions.]]
In addition to its use in [[qualitative inorganic analysis]], aluminon has applications in pigment production. It forms brilliantly colored [[lake pigment]]s with many metals. The pigments are red in combination with [[Beryllium|Be<sup>2+</sup>]] and [[Gallium|Ga<sup>3+</sup>]]. The pigment is deep purple or reddish-brown in combination with Fe<sup>3+</sup>. Color of a particular pigment in acidic solutions may change: aluminon and [[Scandium|Sc<sup>3+</sup>]] form red pigments if the solution is acidic, but otherwise the solutions are colorless.<ref name=":0">{{Cite journal|last=Clark|first=RA|last2=Krueger|first2=GL|date=1985|title=Aluminon: its limited application as a reagent for the detection of aluminum species.|journal=Journal of Histochemistry & Cytochemistry|volume=33|issue=7|pages=729–732|doi=10.1177/33.7.3891845|pmid=3891845|issn=0022-1554|doi-access=free}}</ref>


Aluminon is prepared by reacting [[sodium nitrite]] with [[salicylic acid]], adding [[formaldehyde]], then treating with [[ammonia]].<ref>''[[Merck Index]]'', 13th Ed.</ref>
Aluminon is prepared by reacting [[sodium nitrite]] with [[salicylic acid]], adding [[formaldehyde]], then treating with [[ammonia]].<ref>''[[Merck Index]]'', 13th Ed.</ref>


==See also==
==See also==
* [[Analytical chemistry]]
*[[Analytical chemistry]]
* [[Colorimetry]]
*[[Colorimetry]]


==References==
==References==
{{reflist|30em}}
{{reflist|30em}}


{{Ammonium salts}}
{{Salicylates}}
{{Salicylates}}


[[Category:Analytical chemistry]]
[[Category:Analytical chemistry]]
[[Category:Analytical reagents]]
[[Category:Chemical tests]]
[[Category:Chemical tests]]
[[Category:Triarylmethane dyes]]
[[Category:Triarylmethane dyes]]
[[Category:Salicylates]]
[[Category:Salicylates]]
[[Category:Ammonium compounds]]
[[Category:Ammonium compounds]]
[[Category:3-Hydroxypropenals]]

[[de:Aluminon]]
[[es:Aluminón]]
[[pl:Aluminon]]