Aluminon: Difference between revisions
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{{chembox |
{{chembox |
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| verifiedrevid = |
| verifiedrevid = 451147151 |
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| Name = Aluminon |
| Name = Aluminon |
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| OtherNames = ammonium aurin-tricarboxylate; 5-[(3-carboxy-4-hydroxyphenyl)(3-carboxy-4-oxo-2,5-cyclohexadien-ylidene)methyl]-2-hydroxybenzoic acid triammonium salt |
| OtherNames = ammonium aurin-tricarboxylate; 5-[(3-carboxy-4-hydroxyphenyl)(3-carboxy-4-oxo-2,5-cyclohexadien-ylidene)methyl]-2-hydroxybenzoic acid triammonium salt |
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| ImageFile = Aluminon.svg |
| ImageFile = Aluminon.svg |
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| ImageSize = 200px |
| ImageSize = 200px |
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| ImageAlt = Skeletal formula of aluminon |
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| ImageFile1 = Aluminon_ions_spacefill.png |
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| ImageAlt1 = Space-filling models of the ions in aluminon |
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| ImageFile2 = Aqueous aluminon.jpg |
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| Section1 = {{Chembox Identifiers |
| Section1 = {{Chembox Identifiers |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = AIPNSHNRCQOTRI-UHFFFAOYSA-N |
| StdInChIKey = AIPNSHNRCQOTRI-UHFFFAOYSA-N |
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| CASNo_Ref = {{cascite|correct|??}} |
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| CASNo = 569-58-4 |
| CASNo = 569-58-4 |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| UNII = 23J05NR06D |
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| EINECS = 209-319-1 |
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| Section2 = {{Chembox Properties |
| Section2 = {{Chembox Properties |
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| SolubleOther = freely soluble in H<sub>2</sub>O |
| SolubleOther = freely soluble in H<sub>2</sub>O |
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| Section7 = {{Chembox Hazards |
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| GHSPictograms = {{GHS07}} |
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| GHSSignalWord = Warning |
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| HPhrases = {{H-phrases|315|319}} |
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| PPhrases = {{P-phrases|264|280|302+352|305+351+338|321|332+313|337+313|362}} |
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'''Aluminon''', the tri[[ammonium]] salt of [[aurintricarboxylic acid]], is a dye |
'''Aluminon''', the tri[[ammonium]] salt of [[aurintricarboxylic acid]], is a dye often used to detect the presence of the aluminium ion in an aqueous solution. Aluminon forms a red [[complex salt]] in combination with Al<sup>3+</sup>.<ref name=":0" /> |
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[[File:Lake pigment made from aluminon and ferric ions.jpg|left|thumb|Deep purple pigment in a neutral aqueous solution. Made from aluminon and ferric (Fe<sup>3+</sup>) ions.]] |
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In addition to its use in [[qualitative inorganic analysis]], aluminon has applications in pigment production. It forms brilliantly colored [[lake pigment]]s with many metals. The pigments are red in combination with [[Beryllium|Be<sup>2+</sup>]] and [[Gallium|Ga<sup>3+</sup>]]. The pigment is deep purple or reddish-brown in combination with Fe<sup>3+</sup>. Color of a particular pigment in acidic solutions may change: aluminon and [[Scandium|Sc<sup>3+</sup>]] form red pigments if the solution is acidic, but otherwise the solutions are colorless.<ref name=":0">{{Cite journal|last=Clark|first=RA|last2=Krueger|first2=GL|date=1985|title=Aluminon: its limited application as a reagent for the detection of aluminum species.|journal=Journal of Histochemistry & Cytochemistry|volume=33|issue=7|pages=729–732|doi=10.1177/33.7.3891845|pmid=3891845|issn=0022-1554|doi-access=free}}</ref> |
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Aluminon is prepared by reacting [[sodium nitrite]] with [[salicylic acid]], adding [[formaldehyde]], then treating with [[ammonia]].<ref>''[[Merck Index]]'', 13th Ed.</ref> |
Aluminon is prepared by reacting [[sodium nitrite]] with [[salicylic acid]], adding [[formaldehyde]], then treating with [[ammonia]].<ref>''[[Merck Index]]'', 13th Ed.</ref> |
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==See also== |
==See also== |
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* |
*[[Analytical chemistry]] |
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* |
*[[Colorimetry]] |
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==References== |
==References== |
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{{reflist|30em}} |
{{reflist|30em}} |
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{{Ammonium salts}} |
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{{Salicylates}} |
{{Salicylates}} |
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[[Category:Analytical chemistry]] |
[[Category:Analytical chemistry]] |
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[[Category:Analytical reagents]] |
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[[Category:Chemical tests]] |
[[Category:Chemical tests]] |
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[[Category:Triarylmethane dyes]] |
[[Category:Triarylmethane dyes]] |
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[[Category:Salicylates]] |
[[Category:Salicylates]] |
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[[Category:Ammonium compounds]] |
[[Category:Ammonium compounds]] |
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[[Category:3-Hydroxypropenals]] |
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[[de:Aluminon]] |
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[[es:Aluminón]] |
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[[pl:Aluminon]] |