(Pentamethylcyclopentadienyl)titanium trichloride

(Pentamethylcyclopentadienyl)titanium trichloride
Names
	Other names Cp*TiCl3
Identifiers
CAS Number	12129-06-5;
3D model (JSmol)	Interactive image;
ChemSpider	11601864;
ECHA InfoCard	100.152.688
PubChem CID	16212911;
UN number	3261
	InChI InChI=1S/C10H15.3ClH.Ti/c1-6-7(2)9(4)10(5)8(6)3;;;;/h1-5H3;3*1H;/q;;;;+3/p-3 Key: QCEOZLISXJGWSW-UHFFFAOYSA-K;
	SMILES CC1=C([C](C(=C1C)C)C)C.Cl[Ti](Cl)Cl;
Properties
Chemical formula	C10H15Cl3Ti
Molar mass	289.45 g·mol−1
Appearance	Orange solid
Melting point	225 °C (437 °F; 498 K)
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H314
Precautionary statements	P280, P305+P351+P338, P310
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

(Pentamethylcyclopentadienyl)titanium trichloride is an organotitanium compound with the formula Cp*TiCl₃ (Cp* = C₅(CH₃)₅). It is an orange solid. The compound adopts a piano stool geometry. An early synthesis involve the combination of lithium pentamethylcyclopentadienide and titanium tetrachloride.^[2]

The compound is an intermediate in the synthesis of decamethyltitanocene dichloride. In the presence of organoaluminium compounds and other additives, it catalyzes the polymerization of alkenes.^[3]^[4]

References[edit]

^ "Trichloro(pentamethylcyclopentadienyl)titanium(IV) 446289". Sigma-Aldrich.
^ King, R.B.; Bisnette, M.B. (1967). "Organometallic chemistry of the transition metals XXI. Some π-pentamethylcyclopentadienyl derivatives of various transition metals". Journal of Organometallic Chemistry. 8 (2): 287–297. doi:10.1016/S0022-328X(00)91042-8.
^ Ishihara, N.; Kuramoto, M.; Uoi, M. (1988). "Stereospecific polymerization of styrene giving the syndiotactic polymer". Macromolecules. 21 (12): 3356–3360. Bibcode:1988MaMol..21.3356I. doi:10.1021/ma00190a003.
^ Stephan, Douglas W.; Stewart, Jeffrey C.; Guérin, Frédéric; Courtenay, Silke; Kickham, James; Hollink, Emily; Beddie, Chad; Hoskin, Aaron; Graham, Todd; Wei, Pingrong; Spence, Rupert E. v. H.; Xu, Wei; Koch, Linda; Gao, Xiaoliang; Harrison, Daryll G. (2003). "An Approach to Catalyst Design: Cyclopentadienyl-Titanium Phosphinimide Complexes in Ethylene Polymerization". Organometallics. 22 (9): 1937–1947. doi:10.1021/om020954t.