Jump to content

2-Carboxy-D-arabitinol 1-phosphate

From Wikipedia, the free encyclopedia

This is an old revision of this page, as edited by The chemistds (talk | contribs) at 12:09, 14 June 2017 (added CSID and InChI(Key)s & pubchemID). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

2-Carboxy-D-arabitinol 1-phosphate
Names
IUPAC name
2-C-[(phosphonooxy)methyl]-D-ribonic acid
Other names
CA1P
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
  • InChI=1S/C6H13O10P/c7-1-3(8)4(9)6(12,5(10)11)2-16-17(13,14)15/h3-4,7-9,12H,1-2H2,(H,10,11)(H2,13,14,15)/t3-,4-,6-/m1/s1
    Key: UJTMIRNFEXKGMS-ZMIZWQJLSA-N
  • OC[C@@H](O)[C@@H](O)[C@](O)(COP(O)(O)=O)C(O)=O
Properties
C6H13O10P
Molar mass 276.134 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

2-Carboxy-D-arabitinol 1-phosphate (or CA1P) is a molecule produced in plants that inhibits the production of RuBisCO, a key enzyme in the Calvin cycle and carbon fixation. In dark conditions, this molecule binds to RuBisCO, preventing it from participating in chemical reactions. As the amount of light present increases, CA1P levels decrease, freeing RuBisCO's reactive ends, allowing more of the molecules to participate in chemical reactions. It can be broken down by the enzyme 2-carboxy-D-arabinitol-1-phosphatase into 2-carboxy-D-arabinitol.[1]

References

  1. ^ Servaites JC (1990). "Inhibition of ribulose 1,5-bisphosphate carboxylase/oxygenase by 2-carboxyarabinitol-1-phosphate". Plant Physiol. 92 (4): 867–70. PMC 1062388. PMID 16667398.