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3,3-Bis(chloromethyl)oxetane

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3,3-Bis(chloromethyl)oxetane
Names
IUPAC name
3,3-Bis(chloromethyl)oxetane
Other names
3,3-Dichloromethyloxycyclobutane; BCMO
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.001.033 Edit this at Wikidata
  • InChI=1S/C5H8Cl2O/c6-1-5(2-7)3-8-4-5/h1-4H2
    Key: CXURGFRDGROIKG-UHFFFAOYSA-N
  • InChI=1/C5H8Cl2O/c6-1-5(2-7)3-8-4-5/h1-4H2
    Key: CXURGFRDGROIKG-UHFFFAOYAZ
  • ClCC1(CCl)COC1
Properties
C5H8Cl2O
Molar mass 155.02 g·mol−1
Appearance Black or olive green solid[1]
Melting point 18.9 °C (66.0 °F; 292.0 K)[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

3,3-Bis(chloromethyl)oxetane (BCMO) is classified as an extremely hazardous substance in the United States as defined in Section 302 of the U.S. Emergency Planning and Community Right-to-Know Act (42 U.S.C. 11002), and is subject to strict reporting requirements by facilities which produce, store, or use it in significant quantities.[2] It can cause kidney damage, lacrimation, and somnolence if consumed.[1]

BCMO is a useful pre-polymer in the field of energetic materials for synthesis of Poly-BAMO which is under extensive research in numerous military departments around the world. Poly-BAMO is an energetic polymer that have potential to replace the current propellant binder formulations.[3]

References

  1. ^ a b c Oxetane, 3,3-bis(chloromethyl)- at hazmap.nlm.nih.gov.
  2. ^ "40 C.F.R.: Appendix A to Part 355—The List of Extremely Hazardous Substances and Their Threshold Planning Quantities" (PDF) (July 1, 2008 ed.). Government Printing Office. Retrieved October 29, 2011. {{cite journal}}: Cite journal requires |journal= (help)CS1 maint: postscript (link)
  3. ^ [2]http://www.dtic.mil/dtic/tr/fulltext/u2/a377866.pdf