Jump to content

Rotane

From Wikipedia, the free encyclopedia

This is the current revision of this page, as edited by DMacks (talk | contribs) at 06:56, 28 November 2017 (→‎top: too obvious to mention in caption). The present address (URL) is a permanent link to this version.

(diff) ← Previous revision | Latest revision (diff) | Newer revision → (diff)
[4]Rotane consists of a cyclobutane core, with a spiro-cyclopropane on each corner of it

A rotane is a hydrocarbon consisting of a central cycloalkane ring with cyclopropane units spiro-linked to each corner. The systematic naming pattern for these molecules is "[n]rotane", where n is the number of atoms in the central ring.

The simplest such chemical, [3]rotane, consists solely of a branched array of spiro-cyclopropane units, and is thus a branched triangulane.

References

[edit]
  • de Meijere, Armin; Kozhushkov, Sergei I.; Fokin, Andrey A.; Emme, Ingo; Redlich, Stefan; Schreiner, Peter R. (2003). "New structurally interesting cyclopropane derivatives. A world of wonders and surprises" (PDF). Pure Appl. Chem. 75 (5): 549–562. doi:10.1351/pac200375050549.