1,3-Dithiole
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Names | |
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IUPAC name
1,3-Dithiole
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Other names
1,3-Dithiacyclopentene
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Identifiers | |
3D model (JSmol)
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PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
C3H4S2 | |
Molar mass | 104.19 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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In organosulfur chemistry, a 1,3-dithiole is a type of heterocycle. The parent of this class of compounds is 1,3-dithiacyclopentene. The ligand dmit2- is a 1,3-dithiole.[1] Heating solutions of Na2dmit gives the isomeric disulfide, a 1,2-dithiole.
![](http://upload.wikimedia.org/wikipedia/commons/thumb/2/28/DOQXOW.png/220px-DOQXOW.png)
References
- ^ "The Organic Chemistry of 1,3-Dithiole-2-thione-4,5-dithiolate (DMIT)". Synthesis: 215–235. 1995. doi:10.1055/s-1995-3910.
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(help) - ^ "Crystal structures of three [bis(1,3-dithiole-2-thione-4,5-dithiolato)zincate]2− salts: [Q]2[Zn(dmit)2] (Q = 1,4-Me2-pyridinium or NEt4) and [PPh4]2[Zn(dmit)2]·DMSO. Comparison of the dianion packing arrangements in [Q]2[Zn(dmit)2]". Polyhedron. 19: 821–827. doi:10.1016/S0277-5387(00)00322-3.
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