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2,2'-Biquinoline

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2,2'-Biquinoline
Names
Other names
2,2'-Biquinolyl; 2-Quinolin-2-ylquinoline; Cuproin
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.003.961 Edit this at Wikidata
EC Number
  • 204-357-5
UNII
  • InChI=1S/C18H12N2/c1-3-7-15-13(5-1)9-11-17(19-15)18-12-10-14-6-2-4-8-16(14)20-18/h1-12H
    Key: WPTCSQBWLUUYDV-UHFFFAOYSA-N
  • C1=CC=C2C(=C1)C=CC(=N2)C3=NC4=CC=CC=C4C=C3
Properties
C18H12N2
Molar mass 256.308 g·mol−1
Appearance White solid
Melting point 194.5 °C (382.1 °F; 467.6 K)
Hazards
GHS labelling:
GHS07: Exclamation mark
Warning
H315, H319, H335
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

2,2'-Biquinoline is an organic compound with the formula (C9H6N)2. It is one of several dimers of the bicyclic heterocycle called quinoline. It is prepared by reductive coupling of 2-chloroquinoline.[1] It is a colorimetric indicator for organolithium compounds.[2]

References

  1. ^ Nelson, Todd D.; Crouch, R. David (2004). "Cu, Ni, and Pd Mediated Homocoupling Reactions in Biaryl Syntheses: The Ullmann Reaction". Org. Reactions. 15. doi:10.1002/0471264180.or063.03.
  2. ^ Watson, Spencer Charles; Eastham, Jerome F. (1967). "Colored Indicators for Simple Direct Titration of Magnesium and Lithium Reagents". Journal of Organometallic Chemistry. 9: 165-8. doi:10.1016/S0022-328X(00)92418-5. {{cite journal}}: Cite has empty unknown parameter: |1= (help)