Aquation

Aquation is the chemical reaction involving "incorporation of one or more integral molecules of water" with or without displacement of other atoms or groups.^[1] The term is typically employed to refer to reactions of metal complexes where an anion is displaced by water. For example, bromopentaamminecobalt(III) undergoes the following aquation reaction to give a metal aquo complex:^[2]

[Co(NH₃)₅Br]²⁺ + H₂O → [Co(NH₃)₅(H₂O)]³⁺ + Br⁻

This aquation reaction is catalyzed both by acid and by base. Acid catalysis involves protonation of the bromide, converting it to a better leaving group. Base hydrolysis proceeds by the Sn1CB mechanism, which begins with deprotonation of an ammonia ligand.

References

^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "aquation". doi:10.1351/goldbook.A00426
^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.

[1] IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "aquation". doi:10.1351/goldbook.A00426

[2] Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.

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