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Valentine de Riquet de Caraman-Chimay

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Countess Valentine de Riquet de Caraman (15 February 1839 - 25 August 1914) was a Belgian princess. She was the daughter of Joseph de Riquet de Caraman-Chimay (1808-1886) and Émilie Pellapra. Her first marriage was to prince Paul de Bauffremont on 13 April 1861, but this ended in divorce in 1875 - she gained custody of her two children and later the same year married Georges Bibescu, son of Gheorghe Bibescu, with whom she had three more children - Georges, Nadège (princess Stirbey) and Georges-Valentin (1880-1941).

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