File:Asymmetric Friedel-Crafts alkylation2.svg
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Original file (SVG file, nominally 469 × 266 pixels, file size: 56 KB)
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See also Wikipedia:Manual of Style/Chemistry/Structure drawing Usage: {{low quality chem|reason}} If there is a better version of the image available, please link it (e.g. using {{Superseded}} or {{Vector version available}}). |  |
Summary
| Description |
English: Asymmetric Friedel-Crafts alkylation of Indole. "Chiral Brønsted Acid Catalyzed Enantioselective Friedel–Crafts Reaction of Indoles and α-Aryl Enamides: Construction of Quaternary Carbon Atoms". Angewandte Chemie International Edition 46 (29): 5565–5567. DOI:10.1002/anie.200701067. |
| Date | |
| Source | Own work |
| Author | Krishnavedala |
| SVG development |  This structural formula was created with an unknown SVG tool.  |
LaTeX source code
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\documentclass[12pt,border=1pt,crop,multi=false,tikz,class=scrartcl]{standalone}
\usepackage[T1]{fontenc}
\usepackage[utf8]{inputenc}
\usepackage{chemfig,chemmacros,chemformula}
\usepackage{lmodern}
\usetikzlibrary{decorations.pathmorphing}
\chemsetup[chemformula]{font-shape=sf,format=\sffamily}
\renewcommand*{\familydefault}{\sfdefault}
\renewcommand*\printatom[1]{\ensuremath{\mathsf{#1}}}
\setatomsep{2em}
\setdoublesep{.6ex}
\setarrowdefault{,1,semithick}
\setbondstyle{thick}
%\setarrowlabelsep{1em}
\makeatletter
\begin{document}
\definesubmol\nobond{-[,0.25,,,draw=none]}
%\schemedebug{true}
\schemestart
\chemfig{*6(-= (*5(-\chembelow{N}{H}-=--)) -=-=)}
\arrow{->[\parbox{3cm}{\scriptsize\centering\chemfig{=[:60](-[::60,,,1]NH-[2]Ac)-[::-60]*6(=-=-=-)}\\\ch{C6H5CH3}, MS 4A, rt}][\parbox{3.5cm}{
\centering\scriptsize0.1 eq.\tiny\chemfig[black!60]{
P(=[:60]O)(-[:-60]OH)
(-[:120]O-[::30]*6(-(-R)=- *6(-=-=--) =-?=))
-[:-120]O-[::-30]*6(=?- *6(-=-=--) =-=(-R)-)
}\\R= \tiny\chemfig[black!60]{-*6(=(-(-[::-60])-[::60])-=(-(-[::-60])-[::60])-=(-(-[::-60])-[::60])-)}}]}[,2.5]
\chemfig{*6(-= *5(-\chembelow{N}{H}-= (-(-[::30,,,1]NH-[2,,1]Ac)(-[::80])-[0]*6(=-=-=-)) --) -=-=)}
\hspace{-3.5em}\parbox{1.25cm}{\small98\%\\94\% ee}
\schemestop
\end{document}
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Licensing
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This image of a simple structural formula is ineligible for copyright and therefore in the public domain, because it consists entirely of information that is common property and contains no original authorship. |  |
File history
Click on a date/time to view the file as it appeared at that time.
| Date/Time | Thumbnail | Dimensions | User | Comment | |
|---|---|---|---|---|---|
| current | 20:22, 15 August 2014 | | 469 × 266 (56 KB) | Krishnavedala | added text |
| 20:15, 15 August 2014 |  | 471 × 266 (51 KB) | Krishnavedala | User created page with UploadWizard |
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