Kalinite
Kalinite | |
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![]() Kalinite from the Virgin Valley District, Nevada, USA. Specimen size 5.4 cm | |
General | |
Category | Sulfate minerals |
Formula (repeating unit) | KAl(SO4)2·11H2O |
Strunz classification | 7.CC.15 |
Dana classification | 29.5.4.2 |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) H-M symbol: (2/m) |
Space group | C2/c |
Unit cell | a = 19.92(16), b = 9.27(3) c = 8.304(13) Å β = 98.79(19)°; Z = 4 |
Identification | |
Formula mass | 456.37 g/mol |
Color | White to pale blue |
Crystal habit | Fibrous |
Fracture | Conchoidal |
Mohs scale hardness | 2 to 2.5 |
Luster | Vitreous |
Streak | White |
Diaphaneity | Transparent |
Specific gravity | 1.75 (observed) 2.0 (calculated) |
Optical properties | Biaxial (-) |
Refractive index | nα = 1.429 to 1.430, nβ = 1.452, nγ = 1.456 to 1.458 |
Birefringence | None |
2V angle | 52° (measured), 82° (calculated) |
Solubility | Soluble in water |
Other characteristics | Not fluorescent, barely detectable radioactivity |
References | [1][2][3][4] |
Kalinite is a mineral composed of hydrated potassium aluminium sulfate (a type of alum). It is a fibrous monoclinic alum, distinct from isometric potassium alum,[5] named in 1868. Its name comes from kalium (derived from Arabic: القَلْيَه al-qalyah “plant ashes”) which is the Latin name for potassium, hence its chemical symbol, "K".
A proposal to remove recognition of kalinite as a mineral species is scheduled to be submitted to the International Mineralogical Association,[4] currently (March 2010), kalinite is still on the list of approved minerals.[6] Many older samples, however, have been found to be potassium alum.[2]
Environment
Kalinite is a rare secondary mineral observed in the oxidized zone of mineral deposits, as efflorescence on alum slates, in caves, and as a volcanic sublimate.[7] It is associated with jarosite, KFe3+3(SO4)2(OH)6, and cuprian melanterite (pisanite), (Fe2+,Cu2+)SO4·7H2O, at Quetena, Chile.[8]
References
- ^ Gaines et al (1997) Dana’s New Mineralogy, Wiley
- ^ a b http://www.handbookofmineralogy.org/pdfs/kalinite.pdf
- ^ http://www.webmineral.com/data/Kalinite.shtml
- ^ a b http://www.mindat.org/min-2137.html
- ^ American Mineralogist (1923) 8:15
- ^ http://rruff.info/ima
- ^ American Mineralogist (1927) 12:14
- ^ American Mineralogist (1938) 23:721