Legrandite

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Legrandite
Yellow radiating prismatic crystals on limonite, from Ojuela Mine, Mun. de Mapimí, Durango, Mexico. Large crystal is 1.4 cm. long.
General
CategoryArsenate minerals
Formula
(repeating unit)
Zn2(AsO4)(OH)·(H2O)
Strunz classification8.DC.10
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
H-M symbol: (2/m)
Space groupMonoclinic
Space group: P21/c
Unit cella = 12.805(2), b = 7.933(1)
c = 10.215(2) [Å]; β = 104.23°; Z = 8
Identification
ColorBright yellow, wax-yellow, colorless
Crystal habitCrystalline, prismatic, typically in sprays or sheaflike aggregates
CleavageImperfect, poor one {100}
FractureConchoidal
TenacityBrittle
Mohs scale hardness4.5-5
LusterVitreous
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity3.98–4.01
Optical propertiesBiaxial (+)
Refractive indexnα = 1.675 - 1.702 nβ = 1.690 - 1.709 nγ = 1.735 - 1.740
Birefringenceδ = 0.060
PleochroismX = Y = Colorless to yellow Z = Yellow
2V angleMeasured: 50°
References[1][2][3]

Legrandite is a rare zinc arsenate mineral, Zn2(AsO4)(OH)·(H2O).

It is an uncommon secondary mineral in the oxidized zone of arsenic bearing zinc deposits and occurs rarely in granite pegmatite. Associated minerals include: adamite, paradamite, kottigite, scorodite, smithsonite, leiteite, renierite, pharmacosiderite, aurichalcite, siderite, goethite and pyrite.[1][2] It has been reported from Tsumeb, Namibia; the Ojuela mine in Durango, Mexico and at Sterling Hill, New Jersey, US.[1]

It was first described in 1934 for an occurrence in the Flor de Peña Mine, Nuevo Leon, Mexico and named after M. Legrand, a Belgian mining engineer .[2]

References

Radiating cluster of legrandite crystals to nearly 4 cm, on limonite matrix. Ojuela mine, Mun. de Mapimí, Durango. Size: 6 x 3.8 x 3 cm.