Jump to content

Manganese(II) phthalocyanine

From Wikipedia, the free encyclopedia
Manganese(II) phthalocyanine

STM image of a manganese(II) phthalocyanine monolayer on Pb, scale bar is 2 nm.[1]
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C32H16N8.Mn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2 ☒N
    Key: ICIFYHOILPYQKB-UHFFFAOYSA-N ☒N
  • InChI=1/C32H16N8.Mn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2
    Key: ICIFYHOILPYQKB-UHFFFAOYAW
  • ionic form: C1=CC=C2C(=C1)C3=NC4=NC(=NC5=C6C=CC=CC6=C([N-]5)N=C7C8=CC=CC=C8C(=N7)N=C2[N-]3)C9=CC=CC=C94.[Mn+2]
  • coordination form: C1=CC=C2C(=C1)C1=NC4=[N+]3C(=NC5=C6C=CC=CC6=C(N5[Mn]378)N=C5C6=CC=CC=C6C(=[N+]57)N=C2[N]18)C1=CC=CC=C14
Properties
C32H16MnN8
Molar mass 567.461 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Manganese(II) phthalocyanine is a coordination complex of manganese and phthalocyanine.[2]

References

[edit]
  1. ^ Hatter, Nino; Heinrich, Benjamin W.; Ruby, Michael; Pascual, Jose I.; Franke, Katharina J. (2015). "Magnetic anisotropy in Shiba bound states across a quantum phase transition". Nature Communications. 6: 8988. doi:10.1038/ncomms9988. PMC 4674822. PMID 26603561.
  2. ^ ABP Lever; JP Wilshire; SK Quan (1981). "Oxidation of manganese (II) phthalocyanine by molecular oxygen". Inorganic Chemistry. 20 (3): 761–768. doi:10.1021/ic50217a025.