Odor detection threshold
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The odor detection threshold is the lowest concentration of a certain odor compound that is perceivable by the human sense of smell. The threshold of a chemical compound is determined in part by its shape, polarity, partial charges and molecular mass. The olfactory mechanisms responsible for a compound's different detection threshold is not well understood, as such, these thresholds cannot yet be accurately predicted. Rather, they must be measured through extensive tests using human subjects in laboratory settings.
Optical isomers can have different detections thresholds since their conformations may cause them to be less perceivable for the human nose. It is only in recent years that such compounds were separated on gas chromatographs.
Values
- The threshold value is the concentration an aroma or taste can be detected (air, water and fat).
- The recognition threshold is the concentration at which you can identify an odor (air, water and fat).
- The odor unit is the concentration divided by the threshold.
- The flavor impact is the value the rate of change in perception with concentration.
- The flavor contribution of an aroma component in a mixture to the total profile can be calculated from the total odor units and the number contributed by that aroma chemical.
Odor detection value
Odor threshold value (OTV) (also aroma threshold value (ATV), Flavor threshold) is defined as the most minimal concentration of a substance that can be detected by a human nose. Some substances can be detected when their concentration is only few milligrams per 1000 tonnes, which is less than a drop in an Olympic swimming pool. Odor threshold value can be expressed as a concentration in water or concentration in air.
Two major types of flavor thresholds can be distinguished: the absolute and the difference threshold. The odor detection threshold and the odor recognition threshold are absolute thresholds; the first is the minimum concentration at which an odor can be detected without any requirements to identify or recognize the stimulus, while the second is the minimum concentration at which a stimulus can be identified or recognized.[1]
The odor threshold value of an odorant is influenced by the medium.
Examples of substances with strong odors:
- (Z)-8-tetradecenal (OTV = 0.009 ppb in water)[2]
- p-vinylguaiacol (OTV = 10 ppb)[3]
Variables
Threshold in a food is dependent upon:
- The threshold of the aroma in air.
- Concentration in the food
- Solubility in oil and water
- Partition coefficient between the air and the food
- The pH of the food, some aroma compounds are affected by the pH - weak organic acids are protonated at low pH making them less soluble and hence more volatile.
- Number & functionality of odorant receptors in the observer's nose
The concentration of an odor above a food is dependent on its solubility in that food and its vapor pressure and concentration in that food.
See also
References
- ^ L.J. van Gemert (2003) Flavour thresholds
- ^ Sabine, Widder. "8-tetradecenal as fragrance and flavoring substance". Patents archive. osdir.com. Retrieved 26 May 2011.
{{cite web}}: Unknown parameter|coauthors=ignored (|author=suggested) (help) - ^ H.H. Baek, K.R. Cadwallader (1999) Contribution of Free and Glycosidically Bound Volatile Compounds to the Aroma of Muscadine Grape Juice Journal of Food Science 64 (3) , 441–444 doi:10.1111/j.1365-2621.1999.tb15059.x