Refining (glass)

Refining is the removal of bubbles from the molten glass. Alternatively the term "Fining" is used, in this case, "refining" refers to the chemical processes only.

Refining is supported by high temperature and stirring, as well as chemical reactions caused by refining agents. Refining agents increase the volume of bubbles and “seeds” (small bubbles), facilitating their ascension. For the most common types of glass production sulfate raw materials are used, in particular, Na₂SO₄, decomposing into SO₂ and O₂. Glass types that melt at comparatively high temperature, such as borosilicate glasses, use chlorides, such as NaCl, having a sufficiently high vapour pressure at refining temperatures. Alkali-free glasses with high melting temperature, such as LCD display glasses, use tin oxide, SnO₂. In the following cooling process gases from bubbles are reabsorbed in the melt. Redox agents such as Sb₂O₃ may release or absorb oxygen depending on temperature and composition. Apart from chemical refining, bubbling, i.e. direct blowing of gas into the melt is used. Less common are methods like ultrasonic refining or low-pressure refining.^[1]^[2]^[3]

References

^ Shelby, James E. (2005).Introduction to Glass Science and Technology. Royal Society of Chemistry. ISBN 9781847551160
^ de Jong, B. H. W. S. (1989) "Glass"; in "Ullmann's Encyclopedia of Industrial Chemistry"; 5th edition, vol. A12, VCH Publishers, Weinheim, Germany, ISBN 978-3-527-20112-9, pp. 365–432.
^ Pfaender, Heinz G. (1996). Schott guide to glass. Springer. pp. 135, 186. ISBN 978-0-412-62060-7.

[1] Shelby, James E. (2005).Introduction to Glass Science and Technology. Royal Society of Chemistry. ISBN 9781847551160

[2] Jong, B. H. W. S. (1989) "Glass"; in "Ullmann's Encyclopedia of Industrial Chemistry"; 5th edition, vol. A12, VCH Publishers, Weinheim, Germany, ISBN 978-3-527-20112-9, pp. 365–432.

[3] Pfaender, Heinz G. (1996). Schott guide to glass. Springer. pp. 135, 186. ISBN 978-0-412-62060-7.

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