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Verrucosidin

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Verrucosidin
Names
IUPAC name
4-Methoxy-3,5-dimethyl-6-[(2R,3S)-2-methyl-3-[(2E,4E)-4-methyl-5-[(1R,2R,4S,5S)-1,2,4-trimethyl-3,6-dioxabicyclo[3.1.0]hexan-4-yl]penta-2,4-dien-2-yl]oxiran-2-yl]pyran-2-one
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C24H32O6/c1-12(11-22(6)21-23(7,30-21)16(5)28-22)10-13(2)18-24(8,29-18)19-14(3)17(26-9)15(4)20(25)27-19/h10-11,16,18,21H,1-9H3/b12-11+,13-10+/t16-,18+,21+,22+,23-,24-/m1/s1
    Key: JSVLNARHSWZARV-FOOXNAEUSA-N
  • C[C@@H]1[C@@]2([C@@H](O2)[C@](O1)(C)/C=C(\C)/C=C(\C)/[C@H]3[C@](O3)(C)C4=C(C(=C(C(=O)O4)C)OC)C)C
Properties
C24H32O6
Molar mass 416.514 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Verrucosidin is a toxic pyrone-type polyketide produced by Penicillium aurantiogriseum, Penicillium melanoconidium, and Penicillium polonicum.[1]

References

  1. ^ Frisvad, JC; Smedgaard, J; Larsen, TO; Samson, RA (2004). "Mycotoxins, drugs, and other extrolites produced by species in Penicillium subgenus Penicillium". Studies in Mycology. 49: 201–241. ISSN 0166-0616.