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Iodate

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Iodate

The iodate anion, IO3

Space-filling model of the iodate anion
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
1676
UNII
  • InChI=1S/HIO3/c2-1(3)4/h(H,2,3,4)/p-1
    Key: ICIWUVCWSCSTAQ-UHFFFAOYSA-M
  • [O-]I(=O)=O
Properties
IO3
Molar mass 174.902 g·mol−1
Related compounds
Related compounds
Periodate, Fluoroiodate, Bromate, Chlorate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

An iodate is the polyatomic anion with the formula IO3. It is the most common form of iodine in nature, as it comprises the major iodine-containing ores.[1] Iodate salts are often colorless. They are the salts of iodic acid.

Structure

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Iodate is pyramidal in structure. The O–I–O angles range from 97° to 105°, somewhat smaller than the O–Cl–O angles in chlorate.[2]

Reactions

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Redox

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Iodate is one of several oxyanions of iodine, and has an oxidation number of +5. It participates in several redox reactions, such as the iodine clock reaction. Iodate shows no tendency to disproportionate to periodate and iodide, in contrast to the situation for chlorate.

Iodate is reduced by sulfite:[1]

6HSO3 + 2IO3 → 2I + 6HSO4

Iodate oxidizes iodide:

5I + IO3 + 3H2SO4 → 3I2 + 3H2O + 3SO2−4

Similarly, chlorate oxidizes iodide to iodate:

I + ClO3 → Cl + IO3

Iodate is also obtained by reducing a periodate with a sulfide. The byproduct of the reaction is a sulfoxide.[3]

Acid-base

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Iodate is unusual in that it forms a strong hydrogen bond with its parent acid:[2]

IO3 + HIO3 → H(IO3)2

The anion H(IO3)2 is referred to as biiodate.

Principal compounds

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Natural occurrence

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Minerals containing iodate are found in the caliche deposits of Chile. The most important iodate minerals are lautarite and brüggenite, but also copper-bearing iodates such as salesite are known.[7]

Natural waters contain iodine in the form of iodide and iodate, their ratio being dependent on redox conditions and pH. Iodate is the second most abundant form in water. It is mostly associated with alkaline waters and oxidizing conditions.[8]

References

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  1. ^ a b Lyday, Phyllis A. (2005). "Iodine and Iodine Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. pp. 382–390. doi:10.1002/14356007.a14_381. ISBN 978-3527306732.
  2. ^ a b Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
  3. ^ Qiu, Chao; Sheng Han; Xingguo Cheng; Tianhui Ren (2005). "Distribution of Thioethers in Hydrotreated Transformer Base Oil by Oxidation and ICP-AES Analysis". Industrial & Engineering Chemistry Research. 44 (11): 4151–4155. doi:10.1021/ie048833b. Thioethers can be oxidized to sulfoxides by periodate, and periodate is reduced to iodate
  4. ^ "Radiological Protection Institute of Ireland | | Media | Press releases | Radioactivity released from Wylfa nuclear power plant is extremely low and of no health significance". Archived from the original on 2013-10-17. Retrieved 2013-04-08.
  5. ^ "Decision to Discontinue the Future Distribution of Iodine Tablets". Archived from the original on 2013-10-18. Retrieved 2013-05-22.
  6. ^ Arroyave, Guillermo; Pineda, Oscar; Scrimshaw, Nevin S. (1956) [May 1955]. "The stability of potassium iodate in crude table salt". Bulletin of the World Health Organization. 14 (1): 183–185. PMC 2538103. PMID 13329845.
  7. ^ "Home". mindat.org.
  8. ^ Sweden (13 December 2013). "Iodine (including PVP-iodine) Product types 1, 3, 4, 22 (EU 528/2012 assessment)". pp. 29–30.