List of gases: Difference between revisions

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This is a list of gases at [[standard conditions]], which means substances that boil or sublime at or below 25 °C (77 °F) and 1 atm pressure and are reasonably stable.
This is a list of gases at [[standard conditions]], which means substances that boil or sublime at or below 25 °C (77 °F) and 1 atm pressure and are reasonably stable.


DONT USE WIKI
==List==
This list is sorted by boiling point of gases in ascending order, but can be sorted on different values. "sub" and "triple" refer to the [[sublimation point]] and the [[triple point]], which are given in the case of a substance that sublimes at 1 atm; "dec" refers to [[Chemical decomposition|decomposition]]. "~" means approximately.
<!-- Note: in the source code, the list is sorted by ascending boiling point. -->
{| class="wikitable sortable"
!Name
!Formula
!Boiling pt (°C)
!Melting pt (°C)
!Molecular weight
!CAS No
|-
|[[Helium-3]]
|<sup>3</sup>He
|−269.96
|na<ref name="ReferenceA">Helium does not solidify at atmosphere pressure.</ref>
|3
|14762-55-1
|-
|[[Helium]]-4
|<sup>4</sup>He
|−268.928
|na<ref name="ReferenceA"/>
|4
|7440-59-7
|-
|[[Hydrogen]]
|H<sub>2</sub>
|−252.879
|−259.16
|2
|1333-74-0
|-
|[[Deuterium]]<ref>{{Cite web|url=https://pubchem.ncbi.nlm.nih.gov/compound/24523|title=Deuterium|last=PubChem|website=pubchem.ncbi.nlm.nih.gov|language=en|access-date=2020-02-14}}</ref>
|D<sub>2</sub>
|−249.49
|−254.43
|4
|7782-39-0
|-
|[[Tritium]]<ref>{{Cite web|url=https://pubchem.ncbi.nlm.nih.gov/compound/24824|title=Tritium|last=PubChem|website=pubchem.ncbi.nlm.nih.gov|language=en|access-date=2020-02-14}}</ref>
|T<sub>2</sub>
|−248.12
|−254.54
|6
|10028-17-8
|-
|[[Neon]]
|Ne
|−246.046
|−248.59
|20
|7440-01-9
|-
|[[Nitrogen]]
|N<sub>2</sub>
|−195.795
|−210.0
|28
|7727-37-9
|-
|[[Carbon monoxide]]
|CO
|−191.5
|−205.02
|28
|630-08-0
|-
|[[Fluorine]]
|F<sub>2</sub>
|−188.11
|−219.67
|38
|7782-41-4
|-
|[[Argon]]
|Ar
|−185.848
|−189.34
|40
|7440-37-1
|-
|[[Oxygen]]
|O<sub>2</sub>
|−182.962
|−218.79
|32
|7782-44-7
|-
|[[Methane]]
|CH<sub>4</sub>
|−161.5
|−182.50
|16
|74-82-8
|-
|[[Krypton]]
|Kr
|−153.415
|−157.37
|84
|7439-90-9
|-
|[[Nitric oxide]]
|NO
|−151.74
|−163.6
|30
|10102-43-9
|-
|[[Fluorine monoxide]]
|F<sub>2</sub>O
|−144.3
|−223.8
|54
|7783-41-7
|-
|[[Tetrafluoromethane]]
|CF<sub>4</sub>
|−127.8
|−183.6
|88
|75-73-0
|-
|[[Nitrogen trifluoride]]
|NF<sub>3</sub>
|−128.74
|−206.79
|71
|7783-54-2
|-
|[[Silane]]
|SiH<sub>4</sub>
|−111.9
|−185
|32
|7803-62-5
|-
|[[trans-Difluorodiazine]]
|N<sub>2</sub>F<sub>2</sub>
|−111.45
|−172
|66
|13776-62-0
|-
|[[Ozone]]
|O<sub>3</sub>
|−111.35
|−193
|48
|10028-15-6
|-
|[[Xenon]]
|Xe
|−108.099
|−111.75
|131
|7440-63-3
|-
|[[cis-Difluorodiazine]]
|N<sub>2</sub>F<sub>2</sub>
|−105.75
|−195
|66
|13812-43-6
|-
|[[Ethylene]]
|CH<sub>2</sub>=CH<sub>2</sub>
|−103.7
|−169.2
|28
|74-85-1
|-
|[[Phosphorus(III) fluoride]]
|PF<sub>3</sub>
|−101.8
|−151.5
|88
|7783-55-3
|-
|[[Chlorine fluoride]]
|ClF
|−101.1
|−155.6
|54.5
|7790-89-8
|-
|[[Boron trifluoride]]
|BF<sub>3</sub>
|−99.9
|−126.8
|68
|7637-07-2
|-
|[[Fluorosilane]]
|SiH<sub>3</sub>F
|−98.6
|
|50
|13537-33-2
|-
|[[Trifluorosilane]]
|SiHF<sub>3</sub>
|−95
|−131
|86
|13465-71-9
|-
|[[Trifluoromethylhypofluorite]]<ref name=yaws/>
|CF<sub>3</sub>OF
|−95
|−215
|104
|373-91-1
|-
|[[Diborane]]
|B<sub>2</sub>H<sub>6</sub>
|−92.49
|−164.85
|28
|19287-45-7
|-
|[[3,3-Difluorodiazirine]]<ref>Journal of Heterocyclic Chemistry. - 1964. - Vol. 1, No. 1. - pp. 59-60</ref>
|CF<sub>2</sub>N<sub>2</sub>
|−91.3
|
|78
|693-85-6
|-
|[[Acetylene]]
|CH≡CH
|−84.7
|−81.5
|26
|74-86-2
|-
|[[Ethane]]
|CH<sub>3</sub>CH<sub>3</sub>
|−88.5
|−182.8
|30
|74-84-0
|-
|[[Germane]]
|GeH<sub>4</sub>
|−88.1
|−165
|77
|7782-65-2
|-
|[[Nitrous oxide]]
|N<sub>2</sub>O
|−88.48
|−90.8
|44
|10024-97-2
|-
|[[Phosphine]]
|PH<sub>3</sub>
|−87.75
|−133.8
|34
|7803-51-2
|-
|[[Trifluoramine oxide]]
|NOF<sub>3</sub>
|−87.5
|−161
|87
|13847-65-9
|-
|[[Tetrafluorosilane]]
|SiF<sub>4</sub>
|−86
|−90.2
|104
|7783-61-1
|-
|[[Trifluoronitrosomethane]]
|CF<sub>3</sub>NO
|−85
|−196.6
|99
|334-99-6
|-
|[[Azidotrifluoromethane]]
|CF<sub>3</sub>N<sub>3</sub>
|−85
|−152
|111
|3802-95-7
|-
|[[Hydrogen chloride]]
|HCl
|−85
|−114.17
|36.5
|7647-01-0
|-
|[[1,1-Difluoroethene]]
|CF<sub>2</sub>=CH<sub>2</sub>
|−85.5
|−144
|64
|75-38-7
|-
|[[Phosphorus(V) fluoride]]
|PF<sub>5</sub>
|−84.6
|−93.8
|126
|7647-19-0
|-
|[[Carbonyl fluoride]]
|COF<sub>2</sub>
|−84.5
|−111.2
|66
|353-50-4
|-
|[[Trifluoromethane]]
|CHF<sub>3</sub>
|−82.1
|−155.2
|70
|75-46-7
|-
|[[Chlorotrifluoromethane]]
|CClF<sub>3</sub>
|−81.5
|−181
|104.5
|75-72-9
|-
|[[Bis(difluoroboryl)methane]]<ref name=yaws/>
|BF<sub>2</sub>CF<sub>2</sub>BF<sub>2</sub>
|−81.4 ?
|
|148
|55124-14-6
|-
|[[Trifluoroisocyanomethane]]
|CF<sub>3</sub>NC
|−80
|
|95
|105879-13-8
|-
|[[Difluoromethylborane]]
|CH<sub>3</sub>BF<sub>2</sub>
|−78.5
|
|64
|373-64-8
|-
|[[Carbon dioxide]]
|CO<sub>2</sub>
|−78.464 sub
|−56.561 triple
|44
|124-38-9
|-
|[[Fluoromethane]]
|CH<sub>3</sub>F
|−78.4
|−137.8
|34
|593-53-3
|-
|[[Hexafluoroethane]]
|CF<sub>3</sub>CF<sub>3</sub>
|−78.1
|−100.015
|138
|76-16-4
|-
|[[Pentafluoromethanamine]]
|CF<sub>3</sub>NF<sub>2</sub>
|−78
|−130
|121
|335-01-3
|-
|[[Difluorosilane]]
|SiH<sub>2</sub>F<sub>2</sub>
|−77.8
|−122
|68
|13824-36-7
|-
|[[Tetrafluoroethene]]
|CF<sub>2</sub>=CF<sub>2</sub>
|−76
|−131.14
|100
|116-14-3
|-
|[[Fluoroacetylene]]
|FCCH
|−74
|−196
|44
|2713-09-9
|-
|[[Tetrafluorohydrazine]]
|N<sub>2</sub>F<sub>4</sub>
|−74
|−164.5
|104
|10036-47-2
|-
|[[Nitryl fluoride]]
|NO<sub>2</sub>F
|−72.4
|−166
|65
|10022-50-1
|-
|[[Fluoroethene]]
|CH<sub>2</sub>FCH<sub>3</sub>
|−72
|−160.5
|48
|75-02-5
|-
|[[Chlorotrifluorosilane]]
|SiClF<sub>3</sub>
|−70
|−138
|120.5
|14049-36-6
|-
|[[Trifluoroacetonitrile]]
|CF<sub>3</sub>CN
|−68.8
|
|95
|353-85-5
|-
|[[Nitrogen chloride difluoride]]
|NClF<sub>2</sub>
|−67
|−195
|87.5
|13637-87-1
|-
|[[Hydrogen bromide]]
|HBr
|−66.38
|−86.80
|81
|10035-10-6
|-
|[[Difluorophosphine]]<ref>{{cite book |last1=Corbridge |first1=D. E. C. |title=Phosphorus: Chemistry, Biochemistry and Technology, Sixth Edition |date=2016 |publisher=CRC Press |isbn=9781439840894 |page=1265 |url=https://books.google.com/books?id=YWzRBQAAQBAJ&pg=PA1263 |language=en}}</ref>
|PHF<sub>2</sub>
|−65
|−124
|70
|14984-74-8
|-
|[[Borane carbonyl]]
|BH<sub>3</sub>CO
|−64
|−137
|42
|13205-44-2
|-
|[[Fluoroperoxytrifluoromethane]]<ref>{{cite journal |last1=DesMarteau |first1=Darryl D. |title=Fluoroperoxytrifluoromethane, CF3OOF. Preparation from trifluoromethyl hydroperoxide and fluorine in the presence of cesium fluoride |journal=Inorganic Chemistry |date=January 1972 |volume=11 |issue=1 |pages=193–195 |doi=10.1021/ic50107a047}}</ref>
|CF<sub>3</sub>OOF
|−64
|
|120
|
|-
|[[Bis(fluoroxy)difluoromethane]]<ref>Journal of Fluorine Chemistry. - 2013. - Vol. 155. - pp. 29-31 full citation needed</ref>
|CF<sub>2</sub>(OF)<sub>2</sub>
|−64
|
|120
|16282-67-0
|-
|[[Sulfur hexafluoride]]
|SF<sub>6</sub>
|−63.8
|−49.596 triple
|146
|2551-62-4
|-
|[[Tetrafluorooxirane]]{{citation needed|date=September 2018}}
|C<sub>2</sub>F<sub>4</sub>O
|−63.5
|
|116
|694-17-7
|-
|[[Arsine]]
|AsH<sub>3</sub>
|−62.5
|−166
|78
|7784-42-1
|-
|[[Thiocarbonyl fluoride]]<ref>{{cite journal |last1=Downs |first1=A. J. |title=846. Thiocarbonyl fluoride |journal=Journal of the Chemical Society (Resumed) |date=1962 |pages=4361 |doi=10.1039/JR9620004361}}</ref>
|CSF<sub>2</sub>
|−62.1
|−163.5
|82
|420-32-6
|-
|[[Radon]]
|Rn
|−61.7
|−71
|222
|10043-92-2
|-
|[[Difluorocyanamide]]<ref name=yaws/><ref>{{cite journal |last1=Meyers |first1=M. D. |last2=Frank |first2=S. |title=Difluorocyanamide |journal=Inorganic Chemistry |date=August 1966 |volume=5 |issue=8 |pages=1455–1457 |doi=10.1021/ic50042a040}}</ref>
|NF<sub>2</sub>CN
|−61
|−196
|78
|7127-18-6
|-
|[[Nitrosyl fluoride]]
|ONF
|−59.9
|−132.5
|49
|7789-25-5
|-
|[[Hydrogen sulfide]]
|H<sub>2</sub>S
|−59.55
|−85.5
|34
|7783-06-4
|-
|[[Trifluoroacetyl fluoride]]<ref>{{cite web|title=Trifluoroacetyl fluoride|url=https://webbook.nist.gov/cgi/cbook.cgi?ID=C354347&Mask=4|website=webbook.nist.gov|language=en}}</ref>
|CF<sub>3</sub>COF
|−59
|−159.5
|116
|354-34-7
|-
|[[Hexafluorodimethyl ether]]<ref>Advances in Inorganic Chemistry and Radiochemistry. - 1961. - Vol. 3. - p. 406</ref>
|CF<sub>3</sub>OCF<sub>3</sub>
|−59
|
|154
|333-36-8
|-
|[[Bromotrifluoromethane]]
|CBrF<sub>3</sub>
|−57.75
|−167.78
|149
|75-63-8
|-
|[[Difluoroaminooxyperfluoromethane]]<ref name=yaws/><ref>{{cite journal |last1=Shreeve |first1=Jean'ne M. |last2=Duncan |first2=Leonard Clinton |last3=Cady |first3=George H. |title=Difluoroaminooxyperfluoromethane, CF3ONF2 |journal=Inorganic Chemistry |date=October 1965 |volume=4 |issue=10 |pages=1516–1517 |doi=10.1021/ic50032a045}}</ref>
|CF<sub>3</sub>ONF<sub>2</sub>
|−57.63
|
|137
|4217-93-0
|-
|[[Methylsilane]]
|CH<sub>3</sub>SiH<sub>3</sub>
|−57.5
|−156.5
|46
|992-94-9
|-
|[[Difluorine dioxide]]
|F<sub>2</sub>O<sub>2</sub>
|−57 dec
|−163.5
|70
|7783-44-0
|-
|[[Sulfuryl fluoride]]
|SO<sub>2</sub>F<sub>2</sub>
|−55.4
|−135.8
|102
|2699-79-8
|-
|[[Dichlorofluorosilane]]
|SiHCl<sub>2</sub>F
|−54.3
|
|119
|19382-74-2
|-
|[[trans-1,2-Difluoroethene]]
|CHF=CHF
|−53.1
|
|64
|1630-78-0
|-
|[[Trifluoroethene]]
|CF<sub>2</sub>=CHF
|−53
|
|82
|359-11-5
|-
|[[Arsenic(V) fluoride]]
|AsF<sub>5</sub>
|−52.8
|−79.8
|170
|7784-36-3
|-
|[[Phosphorothioic trifluoride]]
|PSF<sub>3</sub>
|−52.25
|−148.8
|120
|2404-52-6
|-
|[[Difluoromethane]]
|CH<sub>2</sub>F<sub>2</sub>
|−52
|−136
|52
|75-10-5
|-
|[[Difluoroamino carbonyl fluoride]]<ref name=handbook>{{cite book |last1=Stephenson |first1=Richard Montgomery |title=Handbook of the Thermodynamics of Organic Compounds |date=2012 |publisher=Springer Science & Business Media |isbn=9789400931732 |page=7 |url=https://books.google.com/books?id=X9PsCAAAQBAJ&pg=PA7 |language=en}}</ref><ref>{{cite journal |last1=Fraser |first1=George W. |last2=Shreeve |first2=Jean'ne M. |title=Difluoraminocarbonyl Fluoride |journal=Inorganic Chemistry |date=October 1965 |volume=4 |issue=10 |pages=1497–1498 |doi=10.1021/ic50032a034}}</ref>
|F<sub>2</sub>NCOF
|−52
|−152.2
|99
|2368-32-3
|-
|[[Stannane]]
|SnH<sub>4</sub>
|−51.8
|−146
|123
|2406-52-2
|-
|[[Tetrafluoropropyne]]<ref>Landolt-Bornstein Numerical Data and Functional Relationships in Science and Technology. Group IV, Volume 20: Vapor Pressure of Chemicals. Subvolume A: Vapor Pressure and Antoine Constants for Hydrocarbons, and Sulfur, Selenium, Tellurium, and Halogen Containing Organic Compounds. - 1999. - p. 197</ref>
|CF<sub>3</sub>C≡CF
|−50.39
|
|112
|20174-11-2
|-
|[[Carbon oxysulfide]]
|OCS
|−50.2
|−138.8
|60
|463-58-1
|-
|[[Pentafluoroethyl hypofluorite]]<ref>Journal of the American Chemical Society. - 1965. - Vol. 87, No. 2. - pp. 231-233</ref>
|C<sub>2</sub>F<sub>5</sub>OF
|−50
|
|154
|
|-
|[[Chlorodifluorosilane]]<ref>Advances in Inorganic Chemistry and Radiochemistry. - 1961. - Vol. 3. - p. 226</ref>
|SiHClF<sub>2</sub>
|−50~
|
|102.5
|80003-43-6
|-
|[[Digallane]]
|Ga<sub>2</sub>H<sub>6</sub>
|−50~
|
|145.494
|12140-58-8
|-
|[[Ethenone]]
|CH<sub>2</sub>=C=O
|−49.7
|−151
|42
|463-51-4
|-
|[[Sulfur fluoride oxide]]
|SOF<sub>4</sub>
|−48.5
|−99.6
|124
|13709-54-1
|-
|[[3,3,3-Trifluoro-1-propyne]]
|CF<sub>3</sub>CCH
|−48.3
|
|94
|661-54-1
|-
|[[Pentafluoroethane]]
|CF<sub>3</sub>CHF<sub>2</sub>
|−48.1
|−100.6
|120
|354-33-6
|-
|[[Propene]]
|C<sub>3</sub>H<sub>6</sub>
|−47.6
|−185.2
|42
|115-07-1
|-
|[[Phosphorus(III) chloride difluoride]]
|PClF<sub>2</sub>
|−47.3
|−164.8
|104.5
|14335-40-1
|-
|[[Carbonyl chloride fluoride]]
|COClF
|−47.2
|−148
|82.5
|353-49-1
|-
|[[1,1,1-Trifluoroethane]]
|CF<sub>3</sub>CH<sub>3</sub>
|−47
|−111.8
|84
|420-46-2
|-
|[[Trifluoromethylhypochlorite]]<ref name=yaws/>
|CF<sub>3</sub>OCl
|−47
|−164
|120.5
|22082-78-6
|-
|[[Perchloryl fluoride]]
|ClO<sub>3</sub>F
|−46.75
|−147
|102.5
|7616-94-6
|-
|[[Selenium hexafluoride]]
|SeF<sub>6</sub>
|−46.6 sub
|−34.6 triple
|193
|7783-79-1
|-
|[[Cyanogen fluoride]]
|FCN
|−46
|−82
|45
|1495-50-7
|-
|[[Fluorine nitrate]]
|FNO<sub>3</sub>
|−46
|−175
|81
|7789-26-6
|-
|[[Pentafluoronitrosoethane]]<ref name="barr">{{cite journal |last1=Barr |first1=D. A. |last2=Haszeldine |first2=R. N. |title=663. Perfluoroalkyl derivatives of nitrogen. Part III. Heptafluoronitrosopropane, perfluoro-2-n-propyl-1 : 2-oxazetidine, perfluoro-(methylene-n-propylamine), and related compounds |journal=Journal of the Chemical Society (Resumed) |date=1956 |pages=3416 |doi=10.1039/JR9560003416}}</ref>
|C<sub>2</sub>F<sub>5</sub>NO
|−45.7
|
|137
|354-72-3
|-
|[[Difluoromethylene dihypofluorite]]<ref name=sos>{{cite book |title=Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 18: Four Carbon-Heteroatom Bonds |date=2014 |publisher=Georg Thieme Verlag |isbn=9783131719119 |page=1147 |url=https://books.google.com/books?id=Kh-GAwAAQBAJ&pg=PA1147 |language=en}}</ref>
|CF<sub>2</sub>(OF)<sub>2</sub>
|−45.8
|−142
|120
|16282-67-0
|-
|[[cis-1,2-Difluoroethene]]
|CHF=CHF
|−45
|
|64
|1630-77-9
|-
|[[1,1-Difluoropropene]]<ref name=yaws/>
|CH<sub>3</sub>CH=CF<sub>2</sub>
|−44
|
|78
|430-63-7
|-
|[[Dimethylfluoroborane]]{{citation needed|date=September 2018}}
|(CH<sub>3</sub>)<sub>2</sub>BF
|−44
|
|60
|353-46-8
|-
|[[Fluoro(trifluoromethyl)silane]]<ref>Bivens D.B., Minor B.H. Fluoroethers and other next generation fluids / International Journal of Refrigeration. - 1998. - Vol. 21, No. 7. - p. 570</ref>
|CF<sub>3</sub>SiH<sub>2</sub>F
|−44
|
|118
|
|-
|[[Thionyl fluoride]]
|SOF<sub>2</sub>
|−43.8
|−110.5
|86
|7783-42-8
|-
|[[Phosphorus(V) chloride tetrafluoride]]
|PClF<sub>4</sub>
|−43.4
|−132
|142.5
|13498-11-8
|-
|[[Methyldiborane]]
|CH<sub>3</sub>B<sub>2</sub>H<sub>5</sub>
|−43
|
|42
|23777-55-1
|-
|[[Difluoro(trifluoromethyl)phosphine]]<ref>Advances in Inorganic Chemistry and Radiochemistry. - 1970. - Vol. 13. - p. 368</ref>
|CF<sub>3</sub>PF<sub>2</sub>
|−43
|
|138
|1112-04-5
|-
|[[N,N,1,1-Tetrafluoromethylamine]]<ref>Bivens D.B., Minor B.H. Fluoroethers and other next generation fluids / International Journal of Refrigeration. - 1998. - Vol. 21, No. 7. - p. 569</ref>
|CHF<sub>2</sub>NF<sub>2</sub>
|−43
|
|103
|24708-53-0
|-
|[[Propane]]
|C<sub>3</sub>H<sub>8</sub>
|−42.25
|−187.7
|44
|74-98-6
|-
|[[Trifluoro(trifluoromethyl)silane]]<ref>Inorganic Chemistry. - 1972. - Vol. 11, No. 6. - p. 1259-1264</ref>
|CF<sub>3</sub>SiF<sub>3</sub>
|−42
|
|154
|335-06-8
|-
|[[Bromotrifluorosilane]]
|BrSiF<sub>3</sub>
|−41.7
|−70.5
|169
|14049-39-9
|-
|[[Hydrogen selenide]]
|H<sub>2</sub>Se
|−41.25
|−65.73
|81
|7783-07-5
|-
|[[Chlorodifluoromethane]]
|CHClF<sub>2</sub>
|−40.7
|−175.42
|86.5
|75-45-6
|-
|[[Sulfur tetrafluoride]]
|SF<sub>4</sub>
|−40.45
|−125
|108
|7783-60-0
|-
|[[Hexafluorodiazomethane]] cis<ref>{{cite journal |last1=Ruff |first1=O. |last2=Giese |first2=M. |title=Die Fluorierung des Silbercyanids. (I.) |journal=Berichte der Deutschen Chemischen Gesellschaft (A and B Series) |date=4 March 1936 |volume=69 |issue=3 |pages=598–603 |doi=10.1002/cber.19360690325 |language=de}}</ref>
|CF<sub>3</sub>NNCF<sub>3</sub>
|−40
|−127
|166
|73513-59-4
|-
|[[Phosphoryl fluoride]]
|POF<sub>3</sub>
|−39.7 sub
|−39.1 triple
|104
|13478-20-1
|-
|[[Chloropentafluoroethane]]
|CF<sub>3</sub>CClF<sub>2</sub>
|−39.1
|−99
|135.5
|76-15-3
|-
|[[Tetrafluoro(trifluoromethyl)phosphorane]]<ref>Inorganic Chemistry. - 1963. - Vol. 2, No. 1. - p. 230</ref>
|CF<sub>3</sub>PF<sub>4</sub>
|−39
|−113
|176
|
|-
|[[tetrafluorophosphorane]]<ref name="holst">{{cite journal |last1=Holmes |first1=Robert R. |last2=Storey |first2=Raymond N. |title=Pentacoordinated Molecules. VIII. Preparation and Nuclear Magnetic Resonance Study of PH2F3 and PHF4 |journal=Inorganic Chemistry |date=December 1966 |volume=5 |issue=12 |pages=2146–2150 |doi=10.1021/ic50046a015}}</ref>
|PHF<sub>4</sub>
|−39.0
|−100
|108
|13659-66-0
|-
|[[Tellurium hexafluoride]]
|TeF<sub>6</sub>
|−38.9
|−37.6 triple
|242
|7783-80-4
|-
|[[Vinyldifluoroborane]]<ref>Journal of the American Chemical Society. - 1960. - Vol. 82, No. 24. - p. 6219</ref>
|CH<sub>2</sub>=CHBF<sub>2</sub>
|−38.8
|−133.4
|76
|
|-
|[[(Trifluoromethyl)silane]]
|CF<sub>3</sub>SiH<sub>3</sub>
|−38.3
|−124
|100
|10112-11-5
|-
|[[Heptafluoroethanamine]]<ref name=yaws/>
|C<sub>2</sub>F<sub>5</sub>NF<sub>2</sub>
|−38.1
|−183
|171
|354-80-3
|-
|[[Tetrafluoroallene]]<ref>Journal of the American Chemical Society. - 1959. - Vol. 81, No. 3. - p. 607</ref>
|CF<sub>2</sub>=C=CF<sub>2</sub>
|−38
|
|112
|461-68-7
|-
|[[Hexafluorooxetane]]<ref>Bivens D.B., Minor B.H. Fluoroethers and other next generation fluids / International Journal of Refrigeration. - 1998. - Vol. 21, No. 7. - p. 568</ref>
|C<sub>3</sub>F<sub>6</sub>O
|−38
|
|166
|425-82-1
|-
|[[Trifluoromethanethiol]]<ref>{{cite journal |last1=Dininny |first1=R. E. |last2=Pace |first2=E. L. |title=Thermodynamic Properties of Trifluoromethanethiol from 12°K to Its Boiling Point. Entropy from Molecular and Spectroscopic Data |journal=The Journal of Chemical Physics |date=March 1960 |volume=32 |issue=3 |pages=805–809 |doi=10.1063/1.1730801}}</ref>
|CF<sub>3</sub>SH
|−37.99
|−157.11
|102
|1493-15-8
|-
|[[Fluoroethane]]
|CH<sub>3</sub>CH<sub>2</sub>F
|−37.7
|−143.2
|48
|353-36-6
|-
|[[Bis(trifluoromethyl)peroxide]]
|CF<sub>3</sub>OOCF<sub>3</sub>
|−37
|
|170
|927-84-4
|-
|[[Pentafluoropropanenitrile]]<ref>Journal of the American Chemical Society. - 1959. - Vol. 81, No. 14. - p. 3602</ref>
|C<sub>2</sub>F<sub>5</sub>CN
|−37
|
|145
|422-04-8
|-
|[[Perfluorodimethylamine]]<ref name="pfta">{{cite journal |last1=Haszeldine |first1=R. N. |title=22. Perfluoro-tert.-amines |journal=Journal of the Chemical Society (Resumed) |date=1951 |volume=0 |pages=102 |doi=10.1039/jr9510000102 |language=en |issn=0368-1769}}</ref>
|(CF<sub>3</sub>)<sub>2</sub>NF
|−37
|
|171
|359-62-6
|-
|[[Perfluoropropane]]
|C<sub>3</sub>F<sub>8</sub>
|−36.8
|−147.7
|188
|76-19-7
|-
|[[Germanium(IV) fluoride]]
|GeF<sub>4</sub>
|−36.5
|−15 triple
|149
|7783-58-6
|-
|[[Cyclopropene]]
|C<sub>3</sub>H<sub>4</sub>
|−36
|
|40
|2781-85-3
|-
|[[Trifluoromethyl fluoroformate]]<ref>{{cite journal |last1=Aymonino |first1=P. J. |title=Trifluoromethyl fluoroformate |journal=Chemical Communications (London) |date=1965 |issue=12 |pages=241 |doi=10.1039/C19650000241}}</ref>
|CF<sub>3</sub>OC(O)F
|−36
|−120
|132
|3299-24-9
|-
|[[Trifluoromethyl isocyanate]]<ref name=chambers/>
|CF<sub>3</sub>NCO
|−36
|
|111
|460-49-1
|-
|[[Tetrafluoro-1,2-diazetidine]]<!-- formula does not match name-->
|C<sub>2</sub>F<sub>4</sub>N<sub>2</sub>H<sub>2</sub>
|−36
|
|130
|
|-
|[[Hydrogen iodide]]
|HI
|−35.5
|−50.76
|128
|10034-85-2
|-
|[[Sulfur fluoride hypofluorite]]
|SOF<sub>6</sub>
|−35.1
|−86
|162
|15179-32-5
|-
|[[Trifluoromethyl difluoromethyl ether]]
|CF<sub>3</sub>OCHF<sub>2</sub>
|−35.0
|−157
|136
|3822-68-2
|-
|[[Propadiene]]
|CH<sub>2</sub>=C=CH<sub>2</sub>
|−34.8
|−136
|40
|463-49-0
|-
|[[Chlorine]]
|Cl<sub>2</sub>
|−34.04
|−101.5
|71
|7782-50-5
|-
|[[Trifluoromethyl fluoroformate]]<ref name=yaws/><ref name="US Patent 3226418">US Patent 3226418</ref>
|CF<sub>3</sub>OC(O)F
|−34
|
|132
|3299-24-9
|-
|[[Tetrafluorodiborane]]
|B<sub>2</sub>F<sub>4</sub>
|−34
|−56
|98
|13965-73-6
|-
|[[Ammonia]]
|NH<sub>3</sub>
|−33.33
|−77.73
|17
|7664-41-7
|-
|[[Trifluoronitromethane]]<ref>{{cite web |last1=HAUPTFLEISCH |first1=John O. |title=SYNTHESIS OF TRIFLUORONITROMETHANE, CF3NO2: PHOTOCHEMICAL SCALE-UP AND A NEW THERMOGENERATION METHOD WITH A REFINED PURIFICATION TECHNIQUE |url=https://ir.ua.edu/bitstream/handle/123456789/694/file_1.pdf?sequence=1&isAllowed=y |publisher=University of Alabama |page=28 |date=2009}}</ref>
|CF<sub>3</sub>NO<sub>2</sub>
|−32
|
|115
|335-02-4
|-
|[[Dichlorodifluorosilane]]
|SiCl<sub>2</sub>F<sub>2</sub>
|−32
|−44
|137
|18356-71-3
|-
|[[(Difluoroamino)difluoroacetonitrile]]<ref>{{cite journal |last1=Dresdner |first1=R. D |last2=Merritt |first2=Jack |last3=Royal |first3=Joyce P. |title=Photochemical Fluorinations of C2N2 and RfN=-SF2 with N2F4 |journal=Inorganic Chemistry |date=August 1965 |volume=4 |issue=8 |pages=1228–1230 |doi=10.1021/ic50030a033}}</ref>
|NF<sub>2</sub>CF<sub>2</sub>CN
|−32
|
|128
|5131-88-4
|-
|[[Hexafluoromethanediamine]]<ref name=yaws/><ref>{{cite journal |last1=Bohon |first1=Robert L. |title=Separation of Tris(difluoroamino)fluoromethane and Bis(difluoroamino)fluoromethane with Crystalline Zeolites |journal=Industrial & Engineering Chemistry Product Research and Development |date=1 December 1969 |volume=8 |issue=4 |pages=443–445 |doi=10.1021/i360032a024}}</ref>
|(NF<sub>2</sub>)<sub>2</sub>CF<sub>2</sub>
|−31.9
|−161.9
|154
|4394-93-8
|-
|[[Bis(trifluoromethyl)diazene]] trans<ref name=yaws/>
|CF<sub>3</sub>NNCF<sub>3</sub>
|−31.1
|
|166
|372-63-4
|-
|[[Cyclopropane]]
|C<sub>3</sub>H<sub>6</sub>
|−31
|−127.6
|42
|75-19-4
|-
|[[Chlorosilane]]
|SiH<sub>3</sub>Cl
|−30.4
|−118
|66.5
|13465-78-6
|-
|[[Perfluoropropene]]
|CF<sub>2</sub>=CFCF<sub>3</sub>
|−30.2
|−156.6
|150
|116-15-4
|-
|[[Chloroacetylene]]
|HCCCl
|−30
|−126
|60.5
|593-63-5
|-
|[[Methyltrifluorosilane]]
|CH<sub>3</sub>SiF<sub>3</sub>
|−30
|−73
|100
|373-74-0
|-
|[[Fluorine azide]]<ref>{{Cite journal|last1=Gholivand|first1=Khodayar|last2=Schatte|first2=Gabriele|last3=Willner|first3=Helge|date=1987-07-01|title=Properties of triazadienyl fluoride, N3F|journal=Inorganic Chemistry|volume=26|issue=13|pages=2137–2140|doi=10.1021/ic00260a025|issn=0020-1669}}</ref>
|FN<sub>3</sub>
|−30
|−139
|61.019
|14986-60-8
|-
|[[Dichlorodifluoromethane]]
|CCl<sub>2</sub>F<sub>2</sub>
|−29.8
|−157.7
|121
|75-71-8
|-
|[[2,3,3,3-Tetrafluoropropene]]<ref>{{cite journal |last1=Fedele |first1=Laura |last2=Bobbo |first2=Sergio |last3=Groppo |first3=Fabio |last4=Brown |first4=J. Steven |last5=Zilio |first5=Claudio |title=Saturated Pressure Measurements of 2,3,3,3-Tetrafluoroprop-1-ene (R1234yf) for Reduced Temperatures Ranging from 0.67 to 0.93 |journal=Journal of Chemical & Engineering Data |date=12 May 2011 |volume=56 |issue=5 |pages=2608–2612 |doi=10.1021/je2000952}}</ref>
|CF<sub>3</sub>CF=CH2<sub></sub>
|−29.5
|−152.2
|114
|754-12-1
|-
|[[Tetrafluorodiaziridine]]<ref name=yaws/>
|CF<sub>4</sub>N<sub>2</sub>
|−29
|
|116
|17224-09-8
|-
|[[fluoroxypentafluoroselenium]]<ref>{{cite journal |last1=Smith |first1=James Everett |last2=Cady |first2=George H. |title=Reactions of fluoroxypentafluoroselenium |journal=Inorganic Chemistry |date=June 1970 |volume=9 |issue=6 |pages=1442–1445 |doi=10.1021/ic50088a029}}</ref>
|F<sub>5</sub>SeOF
|−29
|
|209
|<ref>{{cite book |last1=Emeléus |first1=H. J. |title=The Chemistry of Fluorine and Its Compounds |date=2013 |publisher=Elsevier |isbn=9781483273044 |page=25 |url=https://books.google.com/books?id=9SkSBQAAQBAJ&pg=PA25 |language=en}}</ref>
|-
|[[Perfluorooxetane]]
|C<sub>3</sub>OF<sub>6</sub>
|−28.6
|−117
|166
|425-82-1
|-
|[[Chlorotrifluoroethene]]
|CClF=CF<sub>2</sub>
|−28.3
|−158.14
|116.5
|79-38-9
|-
|[[Methyldifluorophosphine]]
|CH<sub>3</sub>PF<sub>2</sub>
|−28
|−110
|84
|753-59-3
|-
|[[Perfluoroacetone]]
|CF<sub>3</sub>COCF<sub>3</sub>
|−27.4
|−125.45
|166
|684-16-2
|-
|[[Trifluoro(trifluoromethyl)oxirane]]
|C<sub>2</sub>OF<sub>3</sub>CF<sub>3</sub>
|−27.4
|
|166
|428-59-1
|-
|[[Thiazyl trifluoride]]
|N≡SF<sub>3</sub>
|−27.1
|−72.6
|103
|15930-75-3
|-
|[[Trifluoroacetyl chloride]]
|CF<sub>3</sub>COCl
|−27
|−146
|132.5
|354-32-5
|-
|[[3,3,3-Trifluoropropene]]
|CF<sub>3</sub>CH=CH<sub>2</sub>
|−27
|
|96
|677-21-4
|-
|[[Phosphonium chloride]]
|PH<sub>4</sub>Cl
|−27 sub
|
|70.5
|24567-53-1
|-
|[[Formyl fluoride]]
|HCOF
|−26.5
|−142.2
|48
|1493-02-3
|-
|[[1,1,1,2-Tetrafluoroethane]]
|CF<sub>3</sub>CH<sub>2</sub>F
|−26.1
|−103.296
|102
|811-97-2
|-
|[[Trifluoromethyl trifluorovinyl ether]]<ref name=yaws/>
|CF<sub>3</sub>OCF=CF<sub>2</sub>
|−26
|
|166
|5930-63-2
|-
|[[Methyl trifluoromethyl ether]]
|CF<sub>3</sub>OCH<sub>3</sub>
|−25.2
|−149.1
|100
|421-14-7
|-
|[[Bis(trifluoromethyl)nitroxide]]<ref>{{cite journal |last1=Blackley |first1=W. D. |last2=Reinhard |first2=R. R. |title=A New Stable Radical, Bis(trifluoromethyl) Nitroxide |journal=Journal of the American Chemical Society |date=February 1965 |volume=87 |issue=4 |pages=802–805 |doi=10.1021/ja01082a019}}</ref>
|(CF<sub>3</sub>)<sub>2</sub>NO
|−25
|−70
|168
|2154-71-4
|-
|[[Sulfur cyanide pentafluoride]]<ref name=losk>{{cite journal |last1=Lösking |first1=Oliver |last2=Willner |first2=Helge |title=Sulfur Cyanide Pentafluoride SF5 CN |journal=Angewandte Chemie International Edition in English |date=September 1989 |volume=28 |issue=9 |pages=1255–1256 |doi=10.1002/anie.198912551}}</ref>
|SF<sub>5</sub>CN
|−25
|−107
|153
|1512-13-6<ref>{{cite web |title=Cyanopentafluorosulfur (CF5NS)|work=Landolt-Börnstein Substance/Property Index |url=https://lb.chemie.uni-hamburg.de/static/RN/1_1489-60-7%20...%201518-72-5.php?content=116/KW9HikLm}}</ref>
|-
|[[Dimethyl ether]]
|CH<sub>3</sub>OCH<sub>3</sub>
|−24.8
|−141.49
|46
|115-10-6
|-
|[[1,1,1,4,4,4-Hexafluoro-2-butyne]]
|CF<sub>3</sub>C≡CCF<sub>3</sub>
|−24.6
|−117.4
|162
|692-50-2
|-
|[[1-Chloro-1-fluoroethene]]<ref name=yaws/>
|CClF=CH<sub>2</sub>
|−24.1
|
|80.5
|2317-91-1
|-
|[[1,1-Difluoroethane]]
|CHF<sub>2</sub>CH<sub>3</sub>
|−24.05
|−118.6
|66
|75-37-6
|-
|[[2-Fluoropropene]]<ref name=CRC-95ed/>
|CH<sub>3</sub>CF=CH<sub>2</sub>
|−24
|
|60
|1184-60-7
|-
|[[Borirane]]
|C<sub>2</sub>H<sub>4</sub>BH
|−24
|−129
|40
|39517-80-1
|-
|[[Chloromethane]]
|CH<sub>3</sub>Cl
|−23.8
|−97.4
|50.5
|74-87-3
|-
|[[Trifluoronitrosoethylene]]<ref>{{cite journal |last1=Griffin |first1=C. E. |last2=Haszeldine |first2=R. N. |title=279. Perfluoroalkyl derivatives of nitrogen. Part VIII. Trifluoronitrosoethylene and its polymers |journal=Journal of the Chemical Society (Resumed) |date=1960 |pages=1398 |doi=10.1039/JR9600001398}}</ref>
|CF<sub>2</sub>=CFNO
|−23.7
|
|111
|2713-04-4
|-
|[[Pentafluoro(trifluoromethoxy)ethane]]<ref>{{CRC96|page=6-70}}</ref>
|C<sub>2</sub>F<sub>5</sub>OCF<sub>3</sub>
|−23.6
|
|204
|665-16-7
|-
|[[1,1-Difluorocyclopropane]]<ref name=mis/>
|CF<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>
|−23.5
|
|78
|558-29-2
|-
|[[Propyne]] or methylacetylene
|CH<sub>3</sub>CCH
|−23.2
|−103.0
|40
|74-99-7
|-
|[[Diazomethane]]
|CH<sub>3</sub>NNCH<sub>3</sub>
|−23
|−145
|58
|334-88-3
|-
|[[Methylgermane]]
|CH<sub>3</sub>GeH<sub>3</sub>
|−23
|−158
|91
|1449-65-6
|-
|[[Difluoramine]]
|NHF<sub>2</sub>
|−23
|−116
|53
|10405-27-3
|-
|[[1-Propen-1-one]] or methylketene
|CH<sub>3</sub>CH=CO
|−23
|−80
|56
|6004-44-0
|-
|[[Vinylsilane]]
|CH<sub>2</sub>=CHSiH<sub>3</sub>
|−22.8
|
|58
|7291-09-0
|-
|[[Trifluoroiodomethane]]
|CF<sub>3</sub>I
|−22.5
|−110
|196
|2314-97-8
|-
|[[Ethynylsilane]]
|HC≡CSiH<sub>3</sub>
|−22.5
|
|56
|1066-27-9
|-
|hexafluoro-1,3-dioxolane<ref name=":0">{{Cite journal|last1=Salvi-Narkhede|first1=M.|last2=Wang|first2=Bao-Huai|last3=Adcock|first3=James L.|last4=Alexander Van Hook|first4=W.|date=October 1992|title=Vapor pressures, liquid molar volumes, vapor non-ideality, and critical properties of some partially fluorinated ethers (CF3OCF2CF2H, CF3OCF2H, and CF3OCH3), some perfluoroethers (CF3OCF2OCF3, c-CF2OCF2OCF2, and c-CF2CF2CF2O), and of CHF2Br and CF3CFHCF3|journal=The Journal of Chemical Thermodynamics|language=en|volume=24|issue=10|pages=1065–1075|doi=10.1016/S0021-9614(05)80017-5}}</ref>
|c-CF2OCF2OCF2-
|−22.1
|
|182.02
|21297-65-4
|-
|[[Chloromethane sulfonyl chloride]]<ref name=yaws/>
|CH<sub>2</sub>ClS(O)(O)Cl
|−22
|
|149
|3518-65-8
|-
|[[Trifluoromethyl peroxychloride]]<ref name=yaws/>
|CF<sub>3</sub>OOCl
|−22
|−132
|136.5
|32755-26-3
|-
|[[Carbon oxyselenide]]
|COSe
|−21.7
|−124.4
|107
|1603-84-5
|-
|[[Trifluoromethanesulfonyl fluoride]]
|CF<sub>3</sub>SOF
|−21.7
|
|136
|335-05-7
|-
|[[Chloryl trifluoride]]
|ClO<sub>2</sub>F<sub>3</sub>
|−21.6
|−81.2
|124.5
|38680-84-1
|-
|[[Carbonyl bromide fluoride]]
|COBrF
|−21
|
|127
|753-56-0
|-
|[[Bromopentafluoroethane]]
|C<sub>2</sub>BrF<sub>5</sub>
|−21
|
|199
|354-55-2
|-
|[[Cyanogen]]
|NCCN
|−21
|−27.83
|52
|460-19-5
|-
|[[Methyl silyl ether]]
|CH<sub>3</sub>OSiH<sub>3</sub>
|−21
|−98.5
|62
|2171-96-2
|-
|[[Carbonic bromide fluoride]]<ref name="yaws">{{cite book |last1=Yaws |first1=Carl L. |title=The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals: Physical Properties for More Than 54,000 Organic and Inorganic Chemical Compounds, Coverage for C1 to C100 Organics and Ac to Zr Inorganics |date=2015 |publisher=Gulf Professional Publishing |isbn=9780128011461 |page=3 |url=https://books.google.com/books?id=GutDBAAAQBAJ&pg=PA4 |language=en}}</ref>
|CBrFO
|−20.6
|
|127
|753-56-0
|-
|[[Trifluoromethylsulfur pentafluoride]]<ref name=yaws/>
|CF<sub>3</sub>SF<sub>5</sub>
|−20.4
|−87
|196
|373-80-8
|-
|[[Chlorotrifluorogermane]]
|GeClF<sub>3</sub>
|−20.3
|−66.2
|165.5
|14188-40-0
|-
|[[Trimethylborane]]
|(CH<sub>3</sub>)<sub>3</sub>B
|−20.2
|−159.93
|56
|593-90-8
|-
|[[Dimethylsilane]]
|(CH<sub>3</sub>)<sub>2</sub>SiH<sub>2</sub>
|−20
|−150
|60
|1111-74-6
|-
|[[1,1,2,2-Tetrafluoroethane]]
|CHF<sub>2</sub>CHF<sub>2</sub>
|−20
|−89
|66
|359-35-3
|-
|[[Formaldehyde]]
|H<sub>2</sub>CO
|−19.1
|−92
|30
|50-00-0
|-
|[[Hexafluorodisilane]]
|SiF<sub>3</sub>SiF<sub>3</sub>
|−19.1
|−18.7 triple
|170
|13830-68-7
|-
|[[Sulfur chloride pentafluoride]]
|SClF<sub>5</sub>
|−19.05
|−64
|158.5
|13780-57-9
|-
|[[1-Chloro-2,2-difluoroethene]]
|CHCl=CF<sub>2</sub>
|−18.8
|−138.5
|98.5
|359-10-4
|-
|[[1,1,1,2,2-Pentafluoropropane]]
|CF<sub>3</sub>CF<sub>2</sub>CH<sub>3</sub>
|−18
|
|133
|1814-88-6
|-
|[[Difluoroamino sulfur pentafluoride]]<ref>{{cite journal |last1=Logothetis |first1=A. L. |last2=Sausen |first2=G. N. |last3=Shozda |first3=R. J. |title=The Preparation of Difluoroamino Sulfur Pentafluoride |journal=Inorganic Chemistry |date=February 1963 |volume=2 |issue=1 |pages=173–175 |doi=10.1021/ic50005a044}}</ref>
|NF<sub>2</sub>SF<sub>5</sub>
|−17.5
|
|179
|13693-10-2
|-
|[[Stibine]]
|SbH<sub>3</sub>
|−17
|−88
|125
|7803-52-3
|-
|[[1,1,2,2,3,3,3-Heptafluoropropane]]<ref name=miller/>
|CF<sub>2</sub>HCF<sub>2</sub>CF<sub>3</sub>
|−17
|−148.5
|170
|2252-84-8
|-
|[[1,1,1,2,3,3,3-Heptafluoropropane]]
|CF<sub>3</sub>CHFCF<sub>3</sub>
|−16.34
|−126.8
|170
|431-89-0
|-
|[[Phosphorus(III) bromide difluoride]]
|PBrF<sub>2</sub>
|−16.1
|−133.8
|149
|15597-40-7
|-
|[[Methylphosphine]]
|CH<sub>3</sub>PH<sub>2</sub>
|−16
|
|48
|593-54-4
|-
|[[N,N-Difluoromethanamine]]<ref name=yaws/><ref name=frazer>{{cite journal |last1=Frazer |first1=J.W. |title=Preparation of N,N-difluoromethylamine and N,N-difluoroethylamine |journal=Journal of Inorganic and Nuclear Chemistry |date=November 1960 |volume=16 |issue=1–2 |pages=63–66 |doi=10.1016/0022-1902(60)80088-7}}</ref>
|CH<sub>3</sub>NF<sub>2</sub>
|−16
|−114.8
|67
|753-58-2
|-
|[[Fluorine perchlorate]]
|FOClO<sub>3</sub>
|−16
|−167.3
|118.5
|10049-03-3
|-
|[[Bis(trifluoromethyl) trioxide]]<ref>Advances in Inorganic Chemistry and Radiochemistry. - 1974. - Vol. 16. - p. 168</ref>
|CF<sub>3</sub>OOOCF<sub>3</sub>
|−16
|−138
|186
|
|-
|[[1,3,3,3-Tetrafluoropropene]]<ref name=yaws/>
|CF<sub>3</sub>CH=CHF
|−16
|−104.53
|114
|1645-83-6
|-
|[[1-Trifluoromethyl-1,2,2-trifluorocyclopropane]]<ref name=mis/>
|CF<sub>3</sub>CH<sub>2</sub>F<sub>3</sub>
|−15.8
|
|152
|
|-
|[[Disiloxane]]
|(SiH<sub>3</sub>)<sub>2</sub>O
|−15.2
|−144
|78
|13597-73-4
|-
|[[cis-1-Fluoropropene]]
|CH<sub>3</sub>CH=CHF
|−15
|
|60
|19184-10-2
|-
|[[trans-1-Fluoropropene]]
|CH<sub>3</sub>CH=CHF
|−15?
|
|60
|20327-65-5
|-
|[[Nitryl chloride]]
|NO<sub>2</sub>Cl
|−15
|−145
|81.5
|13444-90-1
|-
|[[Chlorazide]]
|ClN<sub>3</sub>
|−15
|−100
|77.47
|13973-88-1
|-
|[[Disilane]]
|Si<sub>2</sub>H<sub>6</sub>
|−14.8
|−129.4
|62
|1590-87-0
|-
|[[Bromodifluoromethane]]
|CHBrF<sub>2</sub>
|−14.6
|−145
|131
|1511-62-2
|-
|[[Chloroethene]]
|CH<sub>2</sub>=CHCl
|−13.8
|−153.84
|62.5
|75-01-4
|-
|[[Monoethylsilane]]<ref name=grif/>
|CH<sub>3</sub>CH<sub>2</sub>SiH<sub>3</sub>
|−13.7
|−180
|60
|
|-
|[[Chlorine pentafluoride]]
|ClF<sub>5</sub>
|−13.1
|−103
|130.5
|13637-63-3
|-
|[[1,1,1-Trifluoropropane]]
|CF<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub>
|−13
|
|98
|421-07-8
|-
|[[1-Chloro-1,1,2,2-tetrafluoroethane]]
|CClF<sub>2</sub>CHF<sub>2</sub>
|−13
|−117
|135.5
|354-25-6
|-
|[[Carboimidic difluoride]]
|CF<sub>2</sub>NH
|−13 dec
|−90
|65
|2712-98-3
|-
|[[Plumbane]]
|PbH<sub>4</sub>
|−13
|
|211
|15875-18-0
|-
|[[Methyl nitrite]]
|CH<sub>3</sub>NO<sub>2</sub>
|−12
|−16
|61
|624-91-9
|-
|[[Trifluoromethylarsine]]<ref name="Hall Ltd 1986. p. 19">Dictionary of organometallic compounds. - 2nd supplement. - Chapman and Hall Ltd, 1986. - p. 19</ref>
|CF<sub>3</sub>AsH<sub>2</sub>
|−12
|
|146
|
|-
|[[1-Chloro-1,2,2,2-tetrafluoroethane]]
|CHClFCF<sub>3</sub>
|−11.96
|−199.15
|136.5
|2837-89-0
|-
|[[Isobutane]]
|(CH<sub>3</sub>)<sub>2</sub>CHCH<sub>2</sub>CH<sub>3</sub>
|−11.7
|−159.42
|58
|75-28-5
|-
|[[Trifluoromethoxy sulfur pentafluoride]]<ref>{{cite journal |last1=Duncan |first1=Leonard C. |last2=Cady |first2=George H. |title=The Preparation and Properties of Trifluoromethoxy Sulfur Pentafluoride [CF3OSF5] and cis-Bis(trifluoromethoxy)tetrafluorosulfur(VI) [(CF3 O)2SF4 ] |journal=Inorganic Chemistry |date=June 1964 |volume=3 |issue=6 |pages=850–852 |doi=10.1021/ic50016a015}}</ref>
|CF<sub>3</sub>OSF<sub>5</sub>
|−11
|−143
|212
|1873-23-0
|-
|[[Thiothionyl fluoride]]
|SSF<sub>2</sub>
|−10.6
|−164.6
|102
|101947-30-2
|-
|[[Sulfur dioxide]]
|SO<sub>2</sub>
|−10.05
|−75.5
|64
|7446-09-5
|-
|[[2-Fluoropropane]]
|CH<sub>3</sub>CHFCH<sub>3</sub>
|−10
|
|62
|420-26-8
|-
|[[Pentafluoroethyl hypochlorite]]<ref name=gould/>
|C<sub>2</sub>F<sub>5</sub>OCl
|−10±
|
|170.5
|22675-67-8
|-
|[[Fluoroformyl sulfurpentafluoride]]<ref name=marco/>
|SF<sub>5</sub>C(O)F
|−10
|
|174
|
|-
|[[Trifluoromethyl fluoroformyl peroxide]]<ref>{{cite journal |last1=Anderson |first1=Lowell Ray |last2=Fox |first2=William B. |title=New preparation for trifluoromethyl fluoroformyl peroxide and bis(trifluoromethyl) trioxide |journal=Inorganic Chemistry |date=September 1970 |volume=9 |issue=9 |pages=2182–2183 |doi=10.1021/ic50091a045}}</ref>
|CF<sub>3</sub>OOC(O)F
|−10~
|
|148
|16118-40-4
|-
|[[Perfluorodimethoxymethane]]
|CF<sub>3</sub>OCF<sub>2</sub>OCF<sub>3</sub>
|−10
|−161
|220
|53772-78-4
|-
|[[1-Chloro-1,1-difluoroethane]]
|CClF<sub>2</sub>CH<sub>3</sub>
|−9.6
|−130.8
|100.5
|75-68-3
|-
|[[Chlorofluoromethane]]
|CH<sub>2</sub>ClF
|−9.1
|−133.0
|68.5
|593-70-4
|-
|[[Pentafluoroethyl isocyanate]]<ref>UNITED STATES PATENT 2,617,817 PERFLUOROALKYL ISOCYANATES Arthur H. Ahlbrecht, 11 November 1952</ref>
|C<sub>2</sub>F<sub>5</sub>NCO
|−9
|
|157
|356-74-1
|-
|[[Bis(trifluoromethyl)chloramine]]<ref name="ang">{{cite book |last1=Ang |first1=H. G. |last2=Syn |first2=Y. C. |title=Advances in Inorganic Chemistry and Radiochemistry |date=1974 |publisher=Academic Press |isbn=9780080578651 |url=https://books.google.com/books?id=qi0vujzNSz4C&pg=PA8 |language=en}}</ref>
|(CF<sub>3</sub>)<sub>2</sub>NCl
|−9
|
|187.5
|
|-
|[[Selenium dioxydifluoride]]
|SeO<sub>2</sub>F<sub>2</sub>
|−8.4
|−99.5
|149
|14984-81-7
|-
|[[Fluoro(trifluoro-methyl)diazine]]<ref name=yaws/>
|CF<sub>4</sub>N<sub>2</sub>O
|−7.63
|
|132
|815-10-1
|-
|[[Isobutene]]
|(CH<sub>3</sub>)<sub>2</sub>C=CH<sub>2</sub>
|−7.0
|−140.7
|56
|115-11-7
|-
|[[3-Fluoropropene]]
|CH<sub>2</sub>=CHCH<sub>2</sub>F
|−7
|
|60
|818-92-8
|-
|[[Bis(trifluromethyl)amine]]<ref name=yaws/>
|(CF<sub>3</sub>)<sub>2</sub>NH
|−7
|
|153
|371-77-7
|-
|[[Ethoxytrifluorosilane]]<ref>{{cite journal |last1=Emeléus |first1=H. J. |last2=Heal |first2=H. G. |title=363. The ethoxyfluorosilanes |journal=J. Chem. Soc. |date=1949 |volume=0 |pages=1696–1699 |doi=10.1039/JR9490001696}}</ref>
|CH<sub>3</sub>H<sub>2</sub>OSiF<sub>3</sub>
|−7
|−122
|118
|460-55-9
|-
|[[Trifluoromethylsulfur trifluoride]]<ref name="rat"/>
|CF<sub>3</sub>SF<sub>3</sub>
|−7
|−110
|158
|374-10-7
|-
|[[Perfluoro-2-methyl-1,2-oxazetidine]]<ref name=bu418/>
|(CF<sub>3</sub>-N)CF<sub>2</sub>CF<sub>2</sub>O
|−6.8
|
|199
|
|-
|[[Tris(trifluoromethyl)-amine]]<ref name=pfta/>
|(CF<sub>3</sub>)<sub>3</sub>N
|−6.5
|
|221
|432-03-1
|-
|[[Methylamine]]
|CH<sub>3</sub>NH<sub>2</sub>
|−6.4
|−93.42
|31
|74-89-5
|-
|[[1-Butene]]
|CH<sub>2</sub>=CHCH<sub>2</sub>CH<sub>3</sub>
|−6.3
|−185.33
|56
|106-98-9
|-
|[[Diphosphorus tetrafluoride]]
|P<sub>2</sub>F<sub>4</sub>
|−6.2
|−86.5
|138
|13824-74-3
|-
|[[Chloryl fluoride]]
|ClO<sub>2</sub>F
|−6
|−115
|86.5
|13637-83-7
|-
|[[Trifluoromethyl iminosulfur difluoride]]<ref name=smith>{{cite journal |last1=Smith |first1=William C. |last2=Tullock |first2=Charles W. |last3=Smith |first3=Ronald D. |last4=Engelhardt |first4=Vaughn A. |title=Chemistry of Sulfur Tetrafluoride. III. Organoiminosulfur Difluorides |journal=Journal of the American Chemical Society |date=February 1960 |volume=82 |issue=3 |pages=551–555 |doi=10.1021/ja01488a013}}</ref>
|CF<sub>3</sub>N=SF<sub>2</sub>
|−6
|
|153
|1512-14-7
|-
|[[Perfluorocyclobutane]]
| -CF<sub>2</sub>CF<sub>2</sub>CF<sub>2</sub>CF<sub>2</sub>-
|−5.91
|−40.16
|200
|115-25-3
|-
|[[Perfluoro-2-butene]]
|CF<sub>3</sub>CCF=CF<sub>3</sub>
|−5.9
|
|200
|360-89-4 trans
|-
|[[Nitrosyl chloride]]
|ONCl
|−5.55
|−59.4
|65.5
|2696-92-6
|-
|[[Difluorocarbamoylchloride]]
|CClF<sub>2</sub>NO
|−5.5
|
|115.5
|16847-30-6
|-
|[[Hexafluoro 1,2-dioxolane]]<ref>{{Cite journal|last1=Jin|first1=Anding|last2=Mack|first2=Hans-Georg|last3=Waterfeld|first3=Alfred|last4=Dakkouri|first4=Marwan|last5=Oberhammer|first5=Heinz|date=November 1992|title=Perfluoro-1,2-dioxolane. A new synthesis and its gas-phase structure|journal=Journal of Molecular Structure|language=en|volume=274|pages=163–170|doi=10.1016/0022-2860(92)80155-B}}</ref>
| -CF<sub>2</sub>CF<sub>2</sub>CF2OO-
|−5
|−115.5
|182.02
|
|-
|[[1,3-Butadiene]]
|CH<sub>2</sub>=CHCH=CH<sub>2</sub>
|−4.6
|−108.9
|54
|106-99-0
|-
|[[Ethyltrifluorosilane]]<ref>{{cite journal |last1=Emeléus |first1=H. J. |last2=Wilkins |first2=C. J. |title=122. Some new ethyl and phenyl silicon fluorides |journal=J. Chem. Soc. |date=1944 |volume=0 |pages=454–456 |doi=10.1039/JR9440000454}}</ref>
|CH<sub>3</sub>CH<sub>2</sub>SiF<sub>3</sub>
|−4.4
|−105
|114
|353-89-9
|-
|[[Difluoro-N-fluoromethanimine]]
|F<sub>2</sub>C=NF
|−4
|
|83
|338-66-9
|-
|[[1,1-Dimethyldiborane]]
|(CH<sub>3</sub>)<sub>2</sub>B(μ-H)<sub>2</sub>BH<sub>2</sub>
|−4
|−150.2
|56
|16924-32-6
|-
|[[Bromochlorodifluoromethane]]
|CF<sub>2</sub>ClBr
|−3.7
|−159.5
|165.5
|353-59-3
|-
|[[N-Nitroso-bis(trifluoromethyl)amine]]<ref>{{cite book |title=Advances in Inorganic Chemistry and Radiochemistry|author1=H. G. Ang|author2=Y. C. Syn |date=1974 |publisher=Academic Press |isbn=9780080578651 |page=29 |chapter-url=https://books.google.com/books?id=qi0vujzNSz4C&pg=PA29|chapter=The chemistry of bis(trifluoromethyl)amine compounds |language=en}}</ref>
|ONN(CF<sub>3</sub>)<sub>2</sub>
|−3.5
|
|182
|
|-
|[[Trifluoromethyl 1,1,2,2-tetrafluoroethyl ether]]<ref name=":0" />
|CF<sub>3</sub>OCF<sub>2</sub>CF<sub>2</sub>H
|−3.3
|−141
|186
|2356-61-8
|-
|[[1-Fluoropropane]]<ref name=yaws/>
|CH<sub>2</sub>FCH<sub>2</sub>CH<sub>3</sub>
|−3.2
|−159
|62
|460-13-9
|-
|[[3-Fluoropropene]]<ref name=CRC-95ed>{{cite book |last1=Haynes |first1=W. M. |title=CRC Handbook of Chemistry and Physics 95ed |date=2014 |publisher=CRC Press |isbn=97814822-08689 |url=https://books.google.com/books?id=bNDMBQAAQBAJ |language=en}}</ref>
|CH<sub>2</sub>CHCH<sub>2</sub>F
|−3
|
|60
|
|-
|[[Dimethylperoxide]]
|CH<sub>3</sub>OOCH<sub>3</sub>
|−3
|−100
|62
|690-02-8
|-
|[[Trifluoromethyl thionitrite]]<ref>{{cite journal |last1=(Banus) Mason |first1=Joan |title=Trifluoromethyl thionitrite |journal=Journal of the Chemical Society A: Inorganic, Physical, Theoretical |date=1969 |pages=1587 |doi=10.1039/J19690001587}}</ref>
|CF<sub>3</sub>SNO
|−3
|
|131
|
|-
|[[Dichlorodifluorogermane]]
|GeCl<sub>2</sub>F<sub>2</sub>
|−2.8
|−51.8
|182
|24422-21-7
|-
|[[Bromotrifluoroethene]]
|CBrF=CF<sub>2</sub>
|−2.5
|
|161
|598-73-2
|-
|[[Trifluoromethane sulfinyl fluoride]]<ref name=yaws/>
|CF<sub>3</sub>SOF
|−2.5
|
|136
|812-12-4
|-
|[[Perfluorobutane]]
|C<sub>4</sub>F<sub>10</sub>
|−2.1
|−129
|238
|355-25-9
|-
|[[Hydrogen telluride]]
|H<sub>2</sub>Te
|−2
|−49
|130
|7783-09-7
|-
|[[1-Chloroheptafluoropropane]]<ref name=Haupt>{{cite journal |last1=Hauptschein |first1=Murray |last2=Nodiff |first2=Edward A. |last3=Grosse |first3=Aristid V. |title=Perfluoroalkyl Halides Prepared from Silver Perfluoro-fatty Acid Salts. II. Perfluoroalkyl Bromides and Chlorides |journal=Journal of the American Chemical Society |date=March 1952 |volume=74 |issue=5 |pages=1347–1350 |doi=10.1021/ja01125a511}}</ref>
|CF<sub>3</sub>CF<sub>2</sub>CF<sub>2</sub>Cl
|−2
|
|204.5
|422-86-6
|-
|[[2-Chloroheptafluoropropane]]<ref name=Haupt/>
|CF<sub>3</sub>CFClCF<sub>3</sub>
|−2
|
|204.5
|76-18-6
|-
|[[Bis(trifluoromethyl)selenium]]<ref name="dic25"/>
|(CF<sub>3</sub>)<sub>2</sub>Se
|−2
|
|217
|371-79-9
|-
|Trifluoromethyl sulfinyl fluoride<ref name="rat">{{cite journal |last1=Ratcliffe |first1=Charles T. |last2=Shreeve |first2=Jean'ne M. |title=Some perfluoroalkylsulfinyl halides. New preparations of trifluoromethylsulfur trifluoride |journal=Journal of the American Chemical Society |date=September 1968 |volume=90 |issue=20 |pages=5403–5408 |doi=10.1021/ja01022a013}}</ref>
|CF<sub>3</sub>S(O)F
|−1.6
|
|136
|812-12-4
|-
|[[1,1,1,2,2,3-Hexafluoropropane]]
|CF<sub>3</sub>CF<sub>2</sub>CFH<sub>2</sub>
|−1.44
|−98.38
|152
|677-56-5
|-
|[[1,1,1,3,3,3-Hexafluoropropane]]
|CF<sub>3</sub>CH<sub>2</sub>CF<sub>3</sub>
|−1.4
|−93.6
|152
|690-39-1
|-
|[[Pentafluoroguanidine]]<ref>{{cite journal |last1=Davis |first1=Ralph Anderson |last2=Kroon |first2=James L. |last3=Rausch |first3=Douglas A. |title=Pentafluoroguanidine |journal=The Journal of Organic Chemistry |date=May 1967 |volume=32 |issue=5 |pages=1662–1663 |doi=10.1021/jo01280a103}}</ref>
|CF<sub>5</sub>N<sub>3</sub>
|−1
|
|149
|10051-06-6
|-
|[[1,1,2,2-Tetrafluoropropane]]<ref>{{cite web |title=1,1,2,2-Tetrafluoropropane {{!}} C3H4F4 {{!}} ChemSpider |url=http://www.chemspider.com/Chemical-Structure.148999.html |website=www.chemspider.com}}</ref>
|CHF<sub>2</sub>CF<sub>2</sub>CH<sub>3</sub>
|−0.8
|−121.1
|116
|40723-63-5
|-
|[[Heptafluoronitrosopropane]]<ref name="barr"/>
|C<sub>3</sub>F<sub>7</sub>NO
|−0.7
|
|199
|354-72-3
|-
|[[Trifluoromethanesulfenylchloride]]<ref name=yaws/>
|CF<sub>3</sub>SCl
|−0.6
|
|136.5
|421-17-0
|-
|[[1,1,1,2-Tetrafluoropropane]]
|CF<sub>3</sub>CHFCH<sub>3</sub>
|−1-0
|
|116
|421-48-7
|-
|[[1,1,2,2,3,3-Hexafluoropropane]]<ref name=yaws/>
|CHF<sub>2</sub>CF<sub>2</sub>CHF<sub>2</sub>
|−0.3
|−98.38
|152
|680-00-2
|-
|[[Butane]]
|C<sub>4</sub>H<sub>10</sub>
|0
|−140
|58
|106-97-8
|-
|[[2,2-Difluoropropane]]
|CH<sub>3</sub>CF<sub>2</sub>CH<sub>3</sub>
|0
|−104.8
|80
|420-45-1
|-
|[[Perfluoroisobutane]]
|C<sub>4</sub>F<sub>10</sub>
|0
|
|238
|354-92-7
|-
|[[Nitrosyl bromide]]
|NOBr
|0
|−56
|110
|13444-87-6
|-
|[[Xenon tetroxide]]
|XeO<sub>4</sub>
|0 dec
|−35.9
|195
|12340-14-6
|-
|[[Trifluoromethylsulfonyl hypofluorite]]<ref name="dic18"/>
|CF<sub>3</sub>SO<sub>2</sub>OF
|0
|−87
|168
|
|-
|[[Trifluoromethyl chloroformate]]<ref>{{cite journal |last1=Young |first1=D.E. |last2=Anderson |first2=L.R. |last3=Gould |first3=D.E. |last4=Fox |first4=W.B. |title=Perfluoroalkyl chloroformates and chlorosulfates |journal=Tetrahedron Letters |date=January 1969 |volume=10 |issue=9 |pages=723–726 |doi=10.1016/S0040-4039(01)87792-3}}</ref>
|CF<sub>3</sub>OC(O)Cl
|0
|
|148.5
|23213-83-4
|-
|[[Decafluorodiethyl ether]] perfluoro ether<ref>{{cite book |last1=Burns |first1=T. H. S. |last2=Bracken |first2=A. |title=Modern Inhalation Anesthetics |date=1972 |publisher=Springer Berlin Heidelberg |isbn=9783642650574 |page=413 |language=en |chapter=Exploratory and Newer Compounds|doi=10.1007/978-3-642-65055-0_19 }}</ref>
|CF<sub>3</sub>CF<sub>2</sub>OCF<sub>2</sub>CF<sub>3</sub>
|0
|
|254
|358-21-4
|-
|[[Perfluorocyclobutanone]]<ref name="depa">{{cite web |last1=De Pasquale |first1=Ralph J. |last2=Padgett |first2=Calvin D. |last3=Patton |first3=Jerry R. |title=PERFLUOROCARBON EPOXIDES Part I TECHNICAL REPORT AFML-TR-73-144 |url=http://www.dtic.mil/dtic/tr/fulltext/u2/912520.pdf |publisher=PCR, Inc. |date=May 1973}}</ref>
| -CF<sub>2</sub>CF<sub>2</sub>CF<sub>2</sub>C(O)-
|0
|
|178
|
|-
|[[Trifluoromethyl peroxonitrate]]<ref name=yaws/>
|CF<sub>3</sub>OON<sub>2</sub>
|0.4
|
|129
|50311-48-3
|-
|[[Perfluorotetrahydrofuran]]
| -OCF<sub>2</sub>CF<sub>2</sub>CF<sub>2</sub>CF<sub>2</sub>-
|0.6
|−85
|216
|773-14-8
|-
|Tetrafluoro(trifluoromethylimino)-λ<sup>6</sup>-sulfane<ref name=tull/>
|F<sub>4</sub>S=NCF<sub>3</sub>
|0.75±0.25
|
|191
|
|-
|[[trans-2-Butene]]
|CH<sub>3</sub>CH=CHCH<sub>3</sub>
|0.9
|−43.3
|56
|624-64-6
|-
|[[Methylcyclopropane]]
|CH<sub>3</sub>CHCH<sub>2</sub>CH<sub>2</sub>
|1
|−177.2
|56
|594-11-6
|-
|[[Bis(trifluoromethyl)phosphine]]<ref>{{cite journal |last1=Burg |first1=Anton B. |title=A New Synthesis of Bis-Trifluoromethyl-Phosphine, (CF3)2PH |last2=Mahler |first2=Walter |journal=Journal of the American Chemical Society |date=August 1957 |volume=79 |issue=15 |pages=4242 |doi=10.1021/ja01572a072}}</ref>
|(CF<sub>3</sub>)<sub>2</sub>PH
|1
|
|170
|
|-
|[[Oxalyl fluoride]]<ref name=handbook/>
|CFOCFO
|1±1
|−12.42
|94
|359-40-0
|-
|[[Methylstannane]]
|CH<sub>3</sub>SnH<sub>3</sub>
|1.4
|
|137
|1631-78-3
|-
|[[trans-Dimethyldiazene]] = azomethane
|CH<sub>3</sub>N=NCH<sub>3</sub>
|1.5
|−78
|58
|503-28-6
|-
|[[Bromosilane]]
|SiH<sub>3</sub>Br
|1.9
|−94
|111
|13465-73-1
|-
|[[Methylarsine]]
|CH<sub>3</sub>AsH<sub>2</sub>
|2
|−143
|92
|593-52-2
|-
|[[Hexafluorocyclobutene]]
|C<sub>4</sub>F<sub>6</sub>
|2
|−60
|162
|697-11-0
|-
|[[Chlorine monoxide]]
|Cl<sub>2</sub>O
|2.2
|−120.6
|87
|7791-21-1
|-
|[[Cyclobutene]]
|C<sub>4</sub>H<sub>6</sub>
|2.5
|
|54
|822-35-5
|-
|[[Difluorodimethylsilane]]
|(CH<sub>3</sub>)<sub>2</sub>SiF<sub>2</sub>
|2.5
|−87.5
|96
|353-66-2
|-
|[[1,1,1-Trifluoroazomethane]]<ref name=yaws/>
|CF<sub>3</sub>NNCH<sub>3</sub>
|2.5
|
|112
|690-21-1
|-
|[[dichorotrifluorophosphorane]]<ref name="holst"/>
|PCl<sub>2</sub>F<sub>3</sub>
|2.5
|−124
|159
|13659-65-9
|-
|[[Trimethylamine]]
|(CH<sub>3</sub>)<sub>3</sub>N
|2.8
|−117.1
|59
|75-50-3
|-
|[[1,1-Dichloro-1,2,2,2-tetrafluoroethane]]
|CCl<sub>2</sub>CF<sub>3</sub>
|3
|−56.6
|152
|374-07-2
|-
|[[Sulfur bromide pentafluoride]]
|SBrF<sub>5</sub>
|3.1
|−79
|207
|15607-89-3
|-
|[[1,1,2-Trifluoroethane]]
|CHF<sub>2</sub>CH<sub>2</sub>F
|3.5
|−84
|84
|430-66-0
|-
|[[1,2-Dichloro-1,1,2,2-tetrafluoroethane]]
|CClF<sub>2</sub>CClF<sub>2</sub>
|3.6
|−92.52
|171
|76-14-2
|-
|[[cis-2-Butene]]
|CH<sub>3</sub>CH=CHCH<sub>3</sub>
|3.72
|−138.9
|56
|590-18-1
|-
|[[Phosphorus dihydride trifluoride]]<ref name="holst"/>
|PH<sub>2</sub>F<sub>3</sub>
|3.9
|−52
|90
|
|-
|[[Bromomethane]]
|CH<sub>3</sub>Br
|4
|−93.66
|95
|74-83-9
|-
|[[1,2-Dimethyldiborane]]
|[(CH<sub>3</sub>)BH<sub>2</sub>]<sub>2</sub>
|4
|−124.9
|56
|17156-88-6
|-
|[[Selenium chloride pentafluoride]]
|SeClF<sub>5</sub>
|4.5
|−19
|209.5
|34979-62-9
|-
|[[1,1,4,4-Tetrafluoro-1,3-butadiene]]<ref>{{cite web |title=1,1,4,4-Tetrafluoro-1,3-butadiene {{!}} C4H2F4 {{!}} ChemSpider |url=http://www.chemspider.com/Chemical-Structure.120032.html |website=www.chemspider.com}}</ref>
|CF<sub>2</sub>=CFCF=CF<sub>2</sub>
|4.5±
|
|162
|407-70-5
|-
|[[Trifluoromethyl phosphorodifluoridate]]<ref name="dic18"/>
|CF<sub>3</sub>OP(O)F<sub>2</sub>
|4.6
|−96.2
|170
|39125-43-4
|-
|[[Bromoacetylene]]
|C<sub>2</sub>HBr
|4.7
|
|105
|593-61-3
|-
|[[Iodine heptafluoride]]
|IF<sub>7</sub>
|4.8
|6.5 triple
|250
|16921-96-3
|-
|[[Dimethylchloroborane]]<ref name=yaws/>
|(CH<sub>3</sub>)<sub>2</sub>BCl
|4.9
|−39.9
|76.5
|1803-36-7
|-
|[[Perfluoro-1-butene]]<ref name=yaws/>
|CF<sub>3</sub>CF<sub>2</sub>CF=CF<sub>2</sub>
|5
|
|200
|357-26-6
|-
|[[Sulfur pentafluoride cyanate]]<ref>{{cite journal |last1=Schmuck |first1=Arno |last2=Seppelt |first2=Konrad |title=Sulfur Pentafluoride Cyanate, F<sub>5</sub>S-O-C≡N |journal=Angewandte Chemie International Edition in English |date=February 1987 |volume=26 |issue=2 |pages=134–135 |doi=10.1002/anie.198701341}}</ref>
|F<sub>5</sub>SOCN
|5
|−60
|169
|
|-
|[[Pentafluorosulfanyl cyanate]]<ref name="tull">{{cite journal |last1=Tullock |first1=C. W. |last2=Coffman |first2=D. D. |last3=Muetterties |first3=E. L. |title=Synthesis and Chemistry of SF5Cl |journal=Journal of the American Chemical Society |date=February 1964 |volume=86 |issue=3 |pages=357–361 |doi=10.1021/ja01057a013}}</ref>
|F<sub>5</sub>SOCN
|5-5.5
|
|169
|
|-
|[[1,1,2,3,4,4-Hexafluoro-1,3-butadiene]]
|CF<sub>2</sub>CFCFCF<sub>2</sub>
|5.4
|−132
|162
|685-63-2
|-
|[[Bis(difluoromethyl) ether]]
|CHF<sub>2</sub>OCHF<sub>2</sub>
|5.5
|
|118
|1691-17-4
|-
|[[Methyl pentafluoroethyl ether]]
|CH<sub>3</sub>OC<sub>2</sub>F<sub>5</sub>
|5.6
|
|140
|22410-44-2
|-
|[[Tris(difluoroamine)fluoromethane]]<ref name=yaws/>
|(NF<sub>2</sub>)<sub>3</sub>CF
|5.6
|−136.9
|187
|14362-68-6
|-
|[[Perfluoro ethyl methyl ether]]
|C<sub>2</sub>F<sub>5</sub>OCF<sub>3</sub>
|5.61
|
|204
|
|-
|[[1-Bromo-2,2-difluoro-ethylene]]<ref name="demiel">{{cite journal |last1=Demiel |first1=Arye |title=Structure and Stability of the Bromofluoroethylenes. II. The Geometric Isomers of 1-Bromo-1,2-difluoro- and 1,2-Dibromo-1,2-difluoroethylene |journal=The Journal of Organic Chemistry |date=July 1965 |volume=30 |issue=7 |pages=2121–2126 |doi=10.1021/jo01018a002}}</ref>
|CHBr=CF<sub>2</sub>
|5.7
|
|143
|
|-
|[[Methanethiol]]<ref name=yaws/>
|CH<sub>3</sub>SH
|5.95
|−123
|48
|74-93-1
|-
|[[1-Buten-3-yne]]
|CH<sub>2</sub>CHC≡CH
|6
|
|54
|689-97-4
|-
|[[Ethyl methyl ether]]
|CH<sub>3</sub>OC<sub>2</sub>H<sub>5</sub>
|6
|−113
|60
|540-67-0
|-
|[[Methyl vinyl ether]]
|CH<sub>3</sub>OCH=CH<sub>2</sub>
|6
|−122
|58
|107-25-5
|-
|[[1,1,1-Trifluoro-2-chloroethane]]
|CF<sub>3</sub>CH<sub>2</sub>Cl
|6.1
|−105.5
|118.5
|75-88-7
|-
|[[1,1,1,2,3,3-Hexafluoropropane]]
|CF<sub>3</sub>CH<sub>2</sub>CF<sub>3</sub>
|6.2
|
|152
|431-63-0
|-
|[[Phosphorothioic chloride difluoride]]
|PSClF<sub>2</sub>
|6.3
|−155.2
|136.5
|2524-02-9
|-
|[[Perfluoro-2-methoxypropionylfluoride]]<ref name=depa/>
|CF<sub>3</sub>OCF(CF<sub>3</sub>)C(O)F
|5-8
|
|232
|
|-
|[[Trimethylsilane]]
|(CH<sub>3</sub>)<sub>3</sub>SiH
|6.7
|−153.9
|74
|993-07-7
|-
|[[Carbon suboxide]]
|OCCCO
|6.8
|−111.3
|68
|504-64-3
|-
|[[2-Chloropentafluoropropene]]<ref name=miller/>
|CF<sub>3</sub>CCl=CF<sub>2</sub>
|6.8
|
|166.5
|2804-50-4
|-
|[[Perfluoroisobutene]]
|(CF<sub>3</sub>)<sub>2</sub>C=CF<sub>2</sub>
|7
|−130
|200
|382-21-8
|-
|[[Pentafluoroethyl trifluorovinyl ether]]
|CF<sub>3</sub>CF<sub>2</sub>OCFCF<sub>2</sub>
|7
|
|216
|10493-43-3
|-
|[[1,1-Difluoropropane]]
|CHF<sub>2</sub>CH<sub>2</sub>CH<sub>3</sub>
|7-8
|
|80
|430-61-5
|-
|[[1,1,1,2,4,4,4-Heptafluoro-2-butene]]<ref name=bu418/>
|CF<sub>3</sub>CF=CHCF<sub>3</sub>
|7-8
|
|182
|
|-
|[[Chloromethylsilane]]
|CH<sub>3</sub>ClSi
|7
|−135
|78.5
|993-00-0
|-
|[[Fluoromethyldifluoroborane]]<ref>{{cite book |title=Advances in Organometallic Chemistry |date=1964 |publisher=Academic Press |isbn=9780080580029 |page=[https://archive.org/details/advancesinorgano0041unse/page/154 154] |url=https://archive.org/details/advancesinorgano0041unse |url-access=registration |language=en}}</ref><ref>{{cite journal |last1=Parsons |first1=Theran D. |title=A Trifluoromethylboron Compound, CF3BF2 |last2=Baker |first2=Everett D. |last3=Burg |first3=Anton B. |last4=Juvinall |first4=Gordon L. |journal=Journal of the American Chemical Society |date=January 1961 |volume=83 |issue=1 |pages=250–251 |doi=10.1021/ja01462a053}}</ref>
|CH<sub>2</sub>FBF<sub>2</sub>
|7
|−47
|82
|
|-
|[[Nitryl cyanide]]<ref>{{Cite journal|last1=Rahm|first1=Martin|last2=Bélanger-Chabot|first2=Guillaume|last3=Haiges|first3=Ralf|last4=Christe|first4=Karl O.|date=2014-07-01|title=Nitryl Cyanide, NCNO 2|journal=Angewandte Chemie International Edition|language=en|volume=53|issue=27|pages=6893–6897|doi=10.1002/anie.201404209|pmid=24861214}}</ref>
|NCNO<sub>2</sub>
|7
|−85
|
|
|-
|[[Phosphorus(V) dichloride trifluoride]]
|PCl<sub>2</sub>F<sub>3</sub>
|7.1
|−125
|159
|13454-99-4
|-
|[[Sulfuryl chloride fluoride]]
|SO<sub>2</sub>ClF
|7.1
|−124.7
|118.5
|13637-84-8
|-
|[[Dimethylamine]]
|(CH<sub>3</sub>)<sub>2</sub>NH
|7.3
|−93
|45
|124-40-3
|-
|[[3-Chloropentafluoropropene]]<ref name="miller">{{cite journal |last1=Miller |first1=William T. |last2=Fried |first2=John H. |last3=Goldwhite |first3=Harold |title=Substitution and Addition Reactions of the Fluoroölefins. IV. Reactions of Fluoride Ion with Fluoroölefins |journal=Journal of the American Chemical Society |date=June 1960 |volume=82 |issue=12 |pages=3091–3099 |doi=10.1021/ja01497a028}}</ref>
|CF<sub>2</sub>ClCF=CF<sub>2</sub>
|7.4
|
|166.5
|79-47-0
|-
|[[Carbonyl chloride]] (Phosgene)
|COCl<sub>2</sub>
|7.5
|−127.77
|99
|75-44-5
|-
|[[Chloropentafluoroacetone]]
|CClF<sub>2</sub>COCF<sub>3</sub>
|7.8
|−133
|182.5
|79-53-8
|-
|[[1-Butyne]]
|CH<sub>3</sub>CH<sub>2</sub>C≡CH
|8.08
|−125.7
|54
|107-00-6
|-
|[[Dichlorosilane]]
|SiH<sub>2</sub>Cl<sub>2</sub>
|8.3
|−122
|101
|4109-96-0
|-
|[[trans-1,1,1,4,4,4-hexafluoro-2-butene]]<ref>{{Cite web|title=(2E)-1,1,1,4,4,4-Hexafluoro-2-butene {{!}} C4H2F6 {{!}} ChemSpider|url=http://www.chemspider.com/Chemical-Structure.4647246.html|access-date=2020-07-14|website=www.chemspider.com}}</ref>
|CF<sub>3</sub>CH=CHCF<sub>3</sub>
|8.5
|
|
|407-60-3
|-
|[[Teflurane|2-Bromo-1,1,1,2-tetrafluoroethane]]<ref name=bu418/>
|CF<sub>3</sub>CHFBr
|8.65
|
|181
|
|-
|[[Methyl chlorosilane]]<ref name=yaws/>
|CH<sub>3</sub>SiH<sub>2</sub>Cl
|8.7
|−134.1
|80.5
|993-00-0
|-
|[[Pentafluorosulfanyl hypochlorite]]{{citation needed|date=November 2018}}
|SF<sub>5</sub>OCl
|8.9
|
|178.5
|
|-
|[[Dichlorofluoromethane]]
|CHCl<sub>2</sub>F
|8.92
|−135
|103
|75-43-4
|-
|[[Neopentane]]
|(CH<sub>3</sub>)<sub>4</sub>C
|9.5
|−16.5
|72
|463-82-1
|-
|[[Trifluoromethylperchlorate]]
|CF<sub>3</sub>OClO<sub>3</sub>
|9.5
|
|168.5
|52003-45-9
|-
|[[1-Chloro-2-fluoroethene]]<ref name=yaws/>
|CClF=CH<sub>2</sub>
|9.8
|
|80.5
|460-16-2
|-
|[[1,3-Butadiyne]]
|HC≡CC≡CH
|10
|−35
|50
|460-12-8
|-
|[[N-Nitroso-O,N-bis(trifluoromethyl)-hydroxylamine]] or <br/>[[O-Nitroso-bis(trifluoromethy1)hydroxylamine]]<ref>{{cite journal |last1=Jander |first1=J. |last2=Haszeldine |first2=R. N. |title=Addition of free radicals to unsaturated systems. Part VI. Free-radical addition to the nitroso-group |journal=Journal of the Chemical Society (Resumed) |date=1954 |pages=696 |doi=10.1039/JR9540000696}}</ref><ref>red brown gas</ref>
|CF<sub>3</sub>(CF<sub>3</sub>O)NNO or<br/> (CF<sub>3</sub>)<sub>2</sub>NONO
|10
|
|198
|367-54-4
|-
|[[Ethylene oxide]]
|CH<sub>2</sub>OCH<sub>2</sub>
|10.4
|−112.46
|44
|75-21-8
|-
|[[1,2-Difluoroethane]]<ref name=yaws/>
|CH<sub>2</sub>FCH<sub>2</sub>F
|10.5
|−118.6
|66
|624-72-6
|-
|[[1,2-Butadiene]] = methylallene
|CH<sub>3</sub>CH=C=CH<sub>2</sub>
|11
|−136.20
|54
|590-19-2
|-
|[[Dichloromethylborane]]
|CH<sub>3</sub>BCl<sub>2</sub>
|11
|
|97
|7318-78-7
|-
|[[Chlorine dioxide]]
|ClO<sub>2</sub>
|11
|−59
|103
|10049-04-4
|-
|[[2-Chloro-2,3,3,3-tetrafluoropropanoyl fluoride]]<ref>{{cite book |title=Houben-Weyl Methods of Organic Chemistry Vol. E 10b/2, 4th Edition Supplement: Organo-Fluorine Compounds - Synthesis of Fluorinated Compounds II, Transformations of Fluorinated Compounds |date=2014 |publisher=Georg Thieme Verlag |isbn=9783131815644 |page=23 |url=https://books.google.com/books?id=HzSGAwAAQBAJ&pg=PA23 |language=en}}</ref>
|CF<sub>3</sub>CFClC(O)F
|11
|
|182.5
|28627-00-1
|-
|[[Methyl trifluorovinyl ether]]<ref>{{cite web |last1=O'Neill |first1=Gerald J. |title=Stabilization of methyl trifluorovinyl ether US Patent 4127613 |url=https://patents.google.com/patent/US4127613 |date=20 October 1977}}</ref>
|CH<sub>3</sub>OCF=CF<sub>2</sub>
|11
|
|112
|3823-94-7
|-
|[[Trifluoromethyl hydroperoxide]]<ref name=yaws/><ref>{{cite journal |last1=Talbott |first1=Richard L. |title=Fluorocarbon peroxides. Novel peroxides prepared from bis(fluoroformyl) peroxide |journal=The Journal of Organic Chemistry |date=May 1968 |volume=33 |issue=5 |pages=2095–2099 |doi=10.1021/jo01269a084}}</ref>
|CF<sub>3</sub>OOH
|11.3
|
|102
|16156-36-8
|-
|[[Methyl trifluoromethyl sulfide]]<ref name=dic25/>
|CH<sub>3</sub>SCF<sub>3</sub>
|11.5
|
|116
|421-16-9
|-
|[[Chlorine trifluoride]]
|ClF<sub>3</sub>
|11.75
|−76.34
|128
|7790-91-2
|-
|[[1-bromoheptafluoropropane]]<ref name=Haupt/>
|CF<sub>3</sub>CF<sub>2</sub>CF<sub>2</sub>Br
|12
|
|249
|422-85-5
|-
|[[Tert-butylfluoride]]<ref name="toro">{{cite journal |last1=Toropov |first1=Andrey |last2=Toropova |first2=Alla |title=Nearest neighboring code and hydrogen bond index in labeled hydrogen-filled graph and graph of atomic orbitals: application to model of normal boiling points of haloalkanes |journal=Journal of Molecular Structure: THEOCHEM |date=December 2004 |volume=711 |issue=1–3 |pages=173–183 |doi=10.1016/j.theochem.2004.10.003}}</ref>
|(CH<sub>3</sub>)<sub>3</sub>CF
|12
|
|76
|353-61-7
|-
|[[2-Fluoro-2-methylpropane]]
|CH<sub>3</sub>(CH<sub>3</sub>)CFCH<sub>3</sub>
|12.1
|
|76
|353-61-7
|-
|[[Trichlorofluorosilane]]
|SiCl<sub>3</sub>F
|12.25
|
|153.5
|14965-52-7
|-
|[[Chloroethane]]
|CH<sub>3</sub>CH<sub>2</sub>Cl
|12.27
|−138
|64.5
|75-00-3
|-
|[[Pentafluoroiodoethane]]<ref>{{cite web |title=Pentafluoroethyl iodide {{!}} C2F5I |url=http://www.chemspider.com/Chemical-Structure.9259.html |website=www.chemspider.com}}</ref>
|CF<sub>3</sub>CF<sub>2</sub>I
|12.5
|−92
|246
|354-64-3
|-
|[[Cyclobutane]]
|C<sub>4</sub>H<sub>8</sub>
|12.5
|−90.7
|56
|287-23-0
|-
|<ref name=tull/>
|F<sub>5</sub>SN=CF<sub>2</sub>
|12.5±0.5
|
|191
|
|-
|2-diazo-1,1,1,3,3,3-hexafluoropropane<ref>{{OrgSynth | author = W. J. Middleton; D. M. Gale | title = Bis(Trifluoromethyl)diazomethane | collvol = 6 | collvolpages = 161 | prep = cv6p0161 | year = 1988}}</ref>
|(CF<sub>3</sub>)<sub>2</sub>CN<sub>2</sub>
|12.5±0.5
|
|
|684-23-1
|-
|[[Silylphosphine]]<ref>{{cite book |last1=Ebsworth |first1=E. A. V. |title=Volatile Silicon Compounds |date=1963 |publisher=Pergamon Press |page=118}}</ref>
|SiH<sub>3</sub>PH<sub>2</sub>
|12.7
|
|68
|14616-47-8
|-
|[[Cyanogen chloride]]
|ClCN
|13
|−6.55
|61.5
|506-77-4
|-
|[[trans-1-Bromo-1,2-difluoroethylene]]<ref name=demiel/>
|CBrF=CFH
|13
|
|143
|358-99-6
|-
|[[Trifluoromethyl phosphine]]<ref name=yaws/>
|CF<sub>3</sub>PH<sub>2</sub>
|13.1
|
|102
|420-52-0
|-
|[[2,2,2-Trifluorodiazoethane]]<ref>{{cite journal |last1=Gilman |first1=Henry |last2=Jones |first2=R. G. |title=2,2,2-Trifluoroethylamine and 2,2,2-Trifluorodiazoethane |journal=Journal of the American Chemical Society |date=August 1943 |volume=65 |issue=8 |pages=1458–1460 |doi=10.1021/ja01248a005}}</ref>
|CF<sub>3</sub>CHNN
|13.2
|
|91
|371-67-5
|-
|[[2-Chloro-1,1,1,2-tetrafluoropropane]] HCFC-244bb<ref>{{cite journal |last1=Yang |first1=Zhi-qiang |last2=Kou |first2=Lian-gang |last3=Mao |first3=Wei |last4=Lu |first4=Jing |last5=Zhang |first5=Wei |last6=Lu |first6=Jian |title=Experimental Study of Saturated Pressure Measurements for 2,3,3,3-Tetrafluoropropene (HFO-1234yf) and 2-Chloro-1,1,1,2-Tetrafluoropropane (HCFC-244bb) |journal=Journal of Chemical & Engineering Data |date=20 December 2013 |volume=59 |issue=1 |pages=157–160 |doi=10.1021/je400970y}}</ref>
|CF<sub>3</sub>CClFCH<sub>3</sub>
|13.23
|
|150.5
|421-73-8
|-
|[[Pentafluoroethyl sulfur pentafluoride]]<ref>{{cite journal |last1=Hoffmann |first1=Friedrich W. |last2=Simmons |first2=Thomas C. |last3=Beck |first3=R. B. |last4=Holler |first4=H. V. |last5=Katz |first5=T. |last6=Koshar |first6=R. J. |last7=Larsen |first7=E. R. |last8=Mulvaney |first8=J. E. |last9=Rogers |first9=F. E. |last10=Singleton |first10=B. |last11=Sparks |first11=R. S. |title=Fluorocarbon Derivatives. I. Derivatives of Sulfur Hexafluoride |journal=Journal of the American Chemical Society |date=July 1957 |volume=79 |issue=13 |pages=3424–3429 |doi=10.1021/ja01570a029}}</ref>
|C<sub>2</sub>F<sub>5</sub>SF<sub>5</sub>
|13.5
|
|246
|
|-
|[[Phosphorus(III) dichloride fluoride]]
|PCl<sub>2</sub>F
|13.85
|−144
|121
|15597-63-4
|-
|[[2-Chloro-1,1,1,3,3,3-hexafluoropropane]]<ref name=miller/>
|CF<sub>3</sub>CHClCF<sub>3</sub>
|14
|−120.8
|186.5
|51346-64-6
|-
|[[Difluoro(difluorochloromethyl)amine]]
|CClF<sub>2</sub>NF<sub>2</sub>
|14.14
|
|137.5
|13880-71-2
|-
|[[Nitrosyl bromide]]
|ONBr
|14.5
|
|110
|13444-87-6
|-
|[[Hexafluoroisobutylene]]<ref name=yaws/>
|(CF<sub>3</sub>)<sub>2</sub>C=CH<sub>2</sub>
|14.5
|
|164
|382-10-5
|-
|[[N,N-Difluoroethylamine]]<ref name=frazer/>
|CH<sub>3</sub>CH<sub>2</sub>NF<sub>2</sub>
|14.9
|−150.3
|81
|758-18-9
|-
|2-(Pentafluorothio)-3,3-difluorooxaziridine<ref>{{cite journal |last1=Sekiya |first1=Akira |last2=DesMarteau |first2=Darryl D. |title=Synthesis and properties of 2-(pentafluorothio)-3,3-difluorooxaziridine |journal=Inorganic Chemistry |date=May 1980 |volume=19 |issue=5 |pages=1330–1333 |doi=10.1021/ic50207a045}}</ref>
|SF<sub>5</sub>(-NCF<sub>2</sub>O-)
|14.0
|
|207
|73002-62-7
|-
|[[Disulfur difluoride]]
|FSSF
|15
|−133
|102
|13709-35-8
|-
|[[1,1,1,3,3-Pentafluoropropane]]<ref name=yaws/>
|CF<sub>3</sub>CH<sub>2</sub>CHF<sub>2</sub>
|15.14
|−102.10
|134
|460-73-1
|-
|[[1,1,1,2,2,3,3,4,4-Nonafluorobutane]]<ref name=yaws/>
|CF<sub>3</sub>CF<sub>2</sub>CF<sub>2</sub>CF<sub>2</sub>H
|12
|
|220
|375-17-7
|-
|[[Trifluoromethyl phosphorodifluoroperoxoate]]<ref name="dic18">{{cite book |last1=Macintyre |first1=Jane E. |title=Dictionary of Inorganic Compounds, Supplement 2 |date=1994 |publisher=CRC Press |isbn=9780412491009 |url=https://books.google.com/books?id=yV-Kj-ubc0IC&pg=PA18 |language=en}}</ref>
|CF<sub>3</sub>OOP(O)F<sub>2</sub>
|15.5
|−88.6
|167
|39125-42-3
|-
|[[(Trifluoroacetyl)sulfur pentafluoride]]<ref name="marco">{{cite journal |last1=De Marco |first1=Ronald A. |last2=Fox |first2=W. B. |title=(Trifluoroacetyl)sulfur pentafluoride |journal=The Journal of Organic Chemistry |date=September 1982 |volume=47 |issue=19 |pages=3772–3773 |doi=10.1021/jo00140a039}}</ref>
|CF<sub>3</sub>C(O)SF<sub>5</sub>
|15.6
|−112
|224
|82390-51-0
|-
|[[Vinyl bromide]]
|CH<sub>2</sub>=CHBr
|15.8
|−137.8
|107
|593-60-2
|-
|[[Bis(fluorocarbonyl) peroxide]]<ref>{{cite journal |last1=Arvia |first1=A. J. |last2=Aymonino |first2=P. J. |last3=Waldow |first3=C. H. |last4=Schumacher |first4=H. J. |title=Bis-monofluorcarbonyl-peroxyd |journal=Angewandte Chemie |date=7 March 1960 |volume=72 |issue=5 |pages=169 |doi=10.1002/ange.19600720505}}</ref><ref name=handbook/>
|CF(O)OOCFO
|15.9
|−42.5
|126
|692-74-0
|-
|[[1-Chloro-1,1,2-trifluoroethane]]
|CClF<sub>2</sub>CH<sub>2</sub>F
|16
|
|118.5
|421-04-5
|-
|[[cis-1-Bromo-1,2-difluoroethylene]]<ref name=demiel/>
|CBrF=CHF
|16
|
|143
|
|-
|[[1-Fluoro-2-methylpropane]]<ref name="toro"/>
|CH<sub>2</sub>FCHCH<sub>3</sub>CH<sub>3</sub>
|16
|
|76
|359-00-2
|-
|[[Difluoromethyl 1,1,2-trifluoroethyl ether]]
|CHF<sub>2</sub>OCF<sub>2</sub>CH<sub>2</sub>F
|16.14
|
|150
|69948-24-9
|-
|[[1-Chloro-1-fluoroethane]]<ref name=yaws/>
|CHClFCH<sub>3</sub>
|16.15
|
|82.5
|1615-75-4
|-
|[[Fluorotrimethylsilane]]
|(CH<sub>3</sub>)<sub>3</sub>SiF
|16.4
|−74.3
|92
|420-56-4
|-
|[[Bis(trifluoromethyl)nitramine]]<ref name="ang"/>
|(CF<sub>3</sub>)<sub>2</sub>NNO<sub>2</sub>
|16.4
|
|198
|
|-
|[[Hexafluoroacetone imine]]<ref>{{cite book |last1=Knunyants |first1=I. L. |last2=Yakobson |first2=G. G. |title=Syntheses of Fluoroorganic Compounds |date=2012 |publisher=Springer Science & Business Media |isbn=9783642702075 |url=https://books.google.com/books?id=m6zxCAAAQBAJ&pg=PA46 |language=en}}</ref>
|CF<sub>3</sub>C(=NH)CF<sub>3</sub>
|16.5±
|−47
|165
|1645-75-6
|-
|[[Dichloro(trifluoromethyl)amine]]<ref name=yaws/>
|CF<sub>3</sub>NCl<sub>2</sub>
|16.6
|
|154
|13880-73-4
|-
|[[Ethylamine]]
|CH<sub>3</sub>CH<sub>2</sub>NH<sub>2</sub>
|16.6
|−81
|45
|75-04-7
|-
|[[1,1,1-Trifluorobutane]]<ref>{{cite web |title=trifluorbutane {{!}} C4H7F3 {{!}} ChemSpider |url=http://www.chemspider.com/Chemical-Structure.10675046.html |website=www.chemspider.com}}</ref>
|CF<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>3</sub>
|16.74
|−114.79
|112
|460-34-4
|-
|[[Bismuth hydride]]
|BiH<sub>3</sub>
|17
|−67
|212
|18288-22-7
|-
|[[2,2,3,3-Tetrafluorobutane]]<ref name=bu418>{{cite book |last1=Burns |first1=T. H. S. |last2=Bracken |first2=A. |title=Modern Inhalation Anesthetics |date=1972 |publisher=Springer Berlin Heidelberg |isbn=9783642650574 |pages=418–439 |language=en |chapter=Exploratory and Newer Compounds|doi=10.1007/978-3-642-65055-0_19 }}</ref>
|CH<sub>3</sub>CF<sub>2</sub>CF<sub>2</sub>CH<sub>3</sub>
|17
|
|130
|
|-
|[[Tungsten(VI) fluoride]]
|WF<sub>6</sub>
|17.1
|1.9
|294
|7783-82-6
|-
|[[1-Chloro-1,2,2-trifluoroethane]]
|CHClFCHF<sub>2</sub>
|17.3
|
|99.5
|431-07-2
|-
|[[Bis (trifluoromethyl) carbamyl fluoride]]
|(CF<sub>3</sub>)<sub>2</sub>NC(O)F
|17.5±2.5
|
|199
|
|-
|[[Ethyl nitrite]]
|C<sub>2</sub>H<sub>5</sub>NO<sub>2</sub>
|17.5
|
|75
|109-95-5
|-
|[[Tetraborane(10)]]
|B<sub>4</sub>H<sub>10</sub>
|18
|−120
|54
|18283-93-7
|-
|[[trifluoro-(sulfinylamino)methane]]<ref>{{cite journal |last1=Lustig |first1=Max |title=Some Perfluoroalkyliminosulfur Derivatives |journal=Inorganic Chemistry |date=August 1966 |volume=5 |issue=8 |pages=1317–1319 |doi=10.1021/ic50042a004}}</ref>
|CF<sub>3</sub>N=S=O
|18
|
|131
|10564-49-5
|-
|F-2,3-dihydro-1,4-dioxin<ref>{{cite journal |last1=Krespan |first1=Carl G. |last2=Dixon |first2=David A. |title=Perhalodioxins and perhalodihydrodioxins |journal=The Journal of Organic Chemistry |date=June 1991 |volume=56 |issue=12 |pages=3915–3923 |doi=10.1021/jo00012a026}}</ref>
| -CF<sub>2</sub>CF<sub>2</sub>OCF=CFO-
|18.5
|
|158
|
|-
|[[Bromofluoromethane]]
|CH<sub>2</sub>BrF
|19 (CRC=23)
|
|113
|373-52-4
|-
|[[Bis(trifluoromethyl)arsine]]<ref name="Hall Ltd 1986. p. 19"/>
|(CF<sub>3</sub>)<sub>2</sub>AsH
|19
|
|214
|
|-
|[[1,1-Dichloro-2,2-difluoroethene]]
|CCl<sub>2</sub>=CF<sub>2</sub>
|19
|−116
|135
|79-35-6
|-
|[[Perfluorovinylsulphur pentafluoride]]<ref>{{cite journal |last1=Case |first1=J. R. |last2=Ray |first2=N. H. |last3=Roberts |first3=H. L. |title=394. Sulphur chloride pentafluoride: reaction with fluoro-olefins |journal=Journal of the Chemical Society (Resumed) |date=1961 |pages=2070 |doi=10.1039/JR9610002070}}</ref>
|CF<sub>2</sub>=CFSF<sub>5</sub>
|19
|
|208
|1186-51-2
|-
|[[Fluoroformic acid anhydride]]<ref>{{cite journal |last1=Pernice |first1=Holger |last2=Willner |first2=Helge |last3=Bierbrauer |first3=Karina |last4=Burgos Paci |first4=Maximiliano |last5=Argüello |first5=Gustavo A. |title=Fluoroformic Acid Anhydride, FC(O)OC(O)F |journal=Angewandte Chemie International Edition |date=18 October 2002 |volume=41 |issue=20 |pages=3832–3834 |doi=10.1002/1521-3773(20021018)41:20<3832::AID-ANIE3832>3.0.CO;2-M |pmid=12386862 }}</ref>
|FC(O)OC(O)F
|19.2
|−46.2
|110
|177036-04-3
|-
|[[Trifluorovinyl isocyanate]]<ref>{{cite journal |last1=Middleton |first1=William J. |title=Perfluorovinyl isocyanates |journal=The Journal of Organic Chemistry |date=November 1973 |volume=38 |issue=22 |pages=3924–3928 |doi=10.1021/jo00962a022}}</ref>
|CF<sub>2</sub>=CFNCO
|19.5
|
|123
|41594-57-4
|-
|[[Hydrogen fluoride]]
|HF
|20
|−83.36
|20
|7664-39-3
|-
|[[Bromine monofluoride]]
|BrF
|20 dec
|−33
|99
|13863-59-7
|-
|[[Perbromyl fluoride]]
|BrO<sub>3</sub>F
|20 dec
|−110
|147
|25251-03-0
|-
|[[1-Chloro-1,1,2,2-tetrafluoropropane]]<ref>{{cite web |title=1-Chloro-1,1,2,2-tetrafluoropropane {{!}} C3H3ClF4 {{!}} ChemSpider |url=http://www.chemspider.com/Chemical-Structure.61220.html |website=www.chemspider.com}}</ref>
|CF<sub>2</sub>ClCF<sub>2</sub>CH<sub>3</sub>
|20
|
|150.5
|421-75-0
|-
|[[Perfluorooxaspiro(2.3)hexane|Perfluorooxaspiro[2.3]hexane]]<ref name=depa/>
|C<sub>5</sub>F<sub>8</sub>O
|18-21
|
|228
|
|-
|[[pentafluoroethylsulfinyl fluoride]]<ref name="rat"/>
|C<sub>2</sub>F<sub>5</sub>S(O)F
|20
|
|186
|20621-31-2
|-
|[[3-Methyl-1-butene]]
|CH<sub>2</sub>=CHCH(CH<sub>3</sub>)<sub>2</sub>
|20.1
|−168.41
|70
|563-45-1
|-
|[[Acetaldehyde]]
|CH<sub>3</sub>CHO
|20.2
|−123.37
|44
|75-07-0
|-
|[[Chlorotetrafluoro(trifluoromethyl)sulfur]]
|CF<sub>3</sub>SClF<sub>4</sub>
|20.2
|
|212.5
|42179-04-4
|-
|[[trans-Bis(trifluoromethyl)sulfur tetrafluoride]]<ref>{{cite journal |last1=Clifford |first1=A. F. |last2=El-Shamy |first2=H. K. |last3=Emeléus |first3=H. J. |last4=Haszeldine |first4=R. N. |title=483. Organometallic and organometalloidal fluorine compounds. Part VIII. The electrochemical fluorination of dimethyl sulphide and carbon disulphide |journal=J. Chem. Soc. |date=1953 |volume=0 |pages=2372–2375 |doi=10.1039/JR9530002372}}</ref>
|CF<sub>3</sub>SF<sub>4</sub>CF<sub>3</sub>
|20.5
|
|246
|42179-02-2
|-
|[[Decafluorocyclopentane]]<ref name=yaws/>
|C<sub>5</sub>F<sub>10</sub>
|20.5
|
|250
|376-77-2
|-
|[[1,1-Dimethylcyclopropane]]
|(CH<sub>3</sub>)<sub>2</sub>CCH<sub>2</sub>CH<sub>2</sub>
|21
|−109.0
|70
|1630-94-0
|-
|[[Acetyl fluoride]]
|CH<sub>3</sub>C(O)F
|21
|−84
|62
|557-99-3
|-
|[[Perfluoro-N-methyloxazolidine]]
|CF<sub>3</sub>-NCF<sub>2</sub>OCF<sub>2</sub>CF<sub>2</sub>-
|21
|
|237
|
|-
|[[Bis(trifluoromethyl)cyanoamine]]<ref name="ang"/>
|(CF<sub>3</sub>)<sub>2</sub>NCN
|21
|
|178
|
|-
|[[Bis(trifluoromethyl)sulfur difluoride]]<ref name="dic25">{{cite book |last1=Macintyre |first1=Jane E. |title=Dictionary of Inorganic Compounds, Supplement 2 |date=1994 |publisher=CRC Press |isbn=9780412491009 |page=25 |url=https://books.google.com/books?id=yV-Kj-ubc0IC&pg=PA25 |language=en}}</ref>
|(CF<sub>3</sub>)<sub>2</sub>SF<sub>2</sub>
|21
|
|198
|30341-38-9
|-
|[[Perfluoroethyldimethylamine]]<ref name=pfta/>
|C<sub>2</sub>F<sub>5</sub>(CF<sub>3</sub>)<sub>2</sub>N
|21±1
|
|271
|815-28-1
|-
|[[cis-1,2-Dichloro-1,2-difluoroethene]]
|CClF=CClF
|21.1
|−119.6
|133
|598-88-9
|-
|Trifluoromethyl trifluoromethanesulfonate<ref>{{cite journal |last1=Kobayashi |first1=Yoshiro |last2=Yoshida |first2=Tsutomu |last3=Kumadaki |first3=Itsumaro |title=Trifluoromethyl trifluoromethanesulfonate (CF3SO2OCF3) |journal=Tetrahedron Letters |date=January 1979 |volume=20 |issue=40 |pages=3865–3866 |doi=10.1016/S0040-4039(01)95545-5}}</ref>
|CF<sub>3</sub>SO<sub>2</sub>OCF<sub>3</sub>
|21.2
|−108.2
|218
|3582-05-6
|-
|[[Nitrogen tetroxide]]
|N<sub>2</sub>O<sub>4</sub>
|21.15
|−9.3
|92
|10544-72-6
|-
|[[Difluoroiodomethane]]
|CHF<sub>2</sub>I
|21.5
|−122
|178
|1493-03-4
|-
|[[Trifluoromethylcyclopropane]]<ref name=mis>{{cite journal |last1=Misani |first1=Fernanda |last2=Speers |first2=Louise |last3=Lyon |first3=A. M. |title=Synthetic Studies in the Field of Fluorinated Cyclopropanes |journal=Journal of the American Chemical Society |date=June 1956 |volume=78 |issue=12 |pages=2801–2804 |doi=10.1021/ja01593a041}}</ref>
|C<sub>5</sub>H<sub>6</sub>F<sub>3</sub>CH<sub>3</sub>
|21.6
|
|110
|381-74-8
|-
|[[1,1,1-Trifluoroacetone]]
|CF<sub>3</sub>C(O)CH<sub>3</sub>
|21.9
|−78
|112
|421-50-1
|-
|[[trans-1,2-Dichloro-1,2-difluoroethene]]
|CClF=CClF
|22
|−93.3
|133
|27156-03-2
|-
|[[Heptafluoroisopropyl hypochlorite]]<ref name=gould>{{cite journal |last1=Gould |first1=Douglas E. |last2=Anderson |first2=Lowell Ray |last3=Young |first3=David Edward |last4=Fox |first4=William B. |title=Perhaloalkyl hypochlorites and pentafluorosulfur hypochlorite. I. Preparation and properties |journal=Journal of the American Chemical Society |date=March 1969 |volume=91 |issue=6 |pages=1310–1313 |doi=10.1021/ja01034a008}}</ref>
|(CF<sub>3</sub>)<sub>2</sub>CFOCl
|22
|
|220.5
|22675-68-9
|-
|[[Perfluoroazoethane]]<ref name=chambers>{{cite journal |last1=Chambers |first1=W. J. |last2=Tullock |first2=C. W. |last3=Coffman |first3=D. D. |title= The Synthesis and Chemistry of Fluoroazoalkanes|journal=Journal of the American Chemical Society |date=June 1962 |volume=84 |issue=12 |pages=2337–2343 |doi=10.1021/ja00871a014}}</ref>
|C<sub>2</sub>F<sub>5</sub>NNC<sub>2</sub>F<sub>5</sub>
|22
|
|266
|
|-
|[[1,2,2-Trifluoropropane]]<ref>{{cite web |title=1,2,2-Trifluoropropane {{!}} C3H5F3 {{!}} ChemSpider |url=http://www.chemspider.com/Chemical-Structure.10675014.html |website=www.chemspider.com}}</ref>
|CH<sub>2</sub>FCF<sub>2</sub>CH<sub>3</sub>
|22
|
|98
|811-94-9
|-
|[[Bis(trifluoromethyl)bromamine]]<ref name="ang"/>
|(CF<sub>3</sub>)<sub>2</sub>NBr
|22
|
|232
|
|-
|[[Bis(trifluoromethyl)sulfde]]<ref>{{cite book |last1=Wold |first1=Aaron |last2=Ruff |first2=John K. |title=Inorganic Syntheses Volume 14 |date=2009 |publisher=John Wiley & Sons |isbn=9780470132807 |page=45 |url=https://books.google.com/books?id=m751CWmh0zEC&pg=PA45 |language=en}}</ref>
|(CF<sub>3</sub>)<sub>2</sub>S
|22.2
|
|170
|371-78-8
|-
|[[1,1,1,3,3-Pentafluorobutane]]
|CF<sub>3</sub>CH<sub>3</sub>CF<sub>2</sub>CH<sub>3</sub>
|22.6
|−34.1
|149
|406-58-6
|-
|[[octafluoro-1,4-dioxane]]<ref>{{cite web |title=2,2,3,3,5,5,6,6-Octafluoro-1,4-dioxane {{!}} C4F8O2 {{!}} ChemSpider |url=http://www.chemspider.com/Chemical-Structure.10329211.html |website=www.chemspider.com}}</ref>
|(-CF<sub>2</sub>CF<sub>2</sub>OCF<sub>2</sub>CF<sub>2</sub>O-)
|22.75±0.25
|
|232
|32981-22-9
|-
|[[Cyanic acid]]
|HNCO
|23
|−86
|43
|420-05-3
|-
|[[2-Chloropropene]]
|CH<sub>3</sub>CCl=CH<sub>2</sub>
|23
|−137.4
|76.5
|557-98-2
|-
|[[1,2,2,2-Tetrafluoroethyl difluoromethyl ether]]
|CF<sub>3</sub>CHFOCHF<sub>2</sub>
|23
|
|168
|57041-67-5
|-
|[[1,1,1,2,3-Pentafluoropropane]]<ref>{{cite web |title=1,1,1,2,3-Pentafluoropropane {{!}} C3H3F5 {{!}} ChemSpider |url=http://www.chemspider.com/Chemical-Structure.144295.html |website=www.chemspider.com}}</ref>
|CF<sub>3</sub>CHFCH<sub>2</sub>F
|23
|
|134
|431-31-2
|-
|[[2,2,3,3,4,4,5-Heptafluoro oxolane]]<ref name=burdon>{{cite journal |last1=Burdon |first1=J. |last2=Chivers |first2=G. E. |last3=Mooney |first3=E. F. |last4=Tatlow |first4=J. C. |title=Partial fluorination of tetrahydrofuran with cobalt trifluoride |journal=Journal of the Chemical Society C: Organic |date=1969 |volume=0 |issue=13 |pages=1739 |doi=10.1039/j39690001739 |language=en |issn=0022-4952}}</ref>
| -CF<sub>2</sub>CF<sub>2</sub>CF<sub>2</sub>CHFO-
|23
|
|179
|
|-
|[[Pentafluoroethyl iminosulfur difluoride]]<ref name=smith/>
|CF<sub>3</sub>CF<sub>2</sub>N=SF<sub>2</sub>
|23±1
|
|203
|
|-
|[[Methoxyacetylene]]<ref>{{cite book |last1=Jones |first1=E. R. H. |last2=Eglinton |first2=Geoffrey |last3=Whiting |first3=M. C. |last4=Shaw |first4=B. L. |title=Ethoxyacetylene |journal=Organic Syntheses |date=1954 |volume=34 |pages=48 |doi=10.1002/0471264180.os034.15|isbn=978-0471264224 }}</ref>
|CH<sub>3</sub>OC≡CH
|23±0.5
|
|56
|6443-91-0
|-
|[[Carbonyl fluoride iodide]]
|COFI
|23.4
|
|174
|1495-48-3
|-
|[[1,2,2,2-Tetrafluoroethyl difluoromethyl ether]]<ref name=yaws/>
|CF<sub>3</sub>CHFOCHF<sub>2</sub>
|23.4
|
|168
|57041-67-5
|-
|[[Propylsilane]]<ref name=grif>{{cite journal |last1=Griffiths |first1=S.T. |last2=Wilson |first2=R.R. |title=The spontaneous ignition of alkyl silanes |journal=Combustion and Flame |date=September 1958 |volume=2 |issue=3 |pages=244–252 |doi=10.1016/0010-2180(58)90045-2}}</ref>
|CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>SiH<sub>3</sub>
|23.5±
|
|78
|13154-66-0
|-
|[[Trichlorofluoromethane]]
|CCl<sub>3</sub>F
|23.77
|−110.48
|137.5
|75-69-4
|-
|[[Formic anhydride]]
|C<sub>2</sub>O<sub>3</sub>H<sub>2</sub>
|24/20 mmHg
|
|74
|1558-67-4
|-
|[[1-Chloro-1,3,3,3-tetrafluoropropene]]<ref name=miller/>
|CF<sub>3</sub>CH=CFCl
|24
|
|148.5
|460-71-9
|-
|[[1,1,2,2-Tetrafluoro-1-nitro-2-nitrosoethane]]<ref>{{cite journal |last1=Birchall |first1=J. M. |last2=Bloom |first2=A. J. |last3=Haszeldine |first3=R. N. |last4=Willis |first4=C. J. |title=584. Perfluoroalkyl derivatives of nitrogen. Part X. The reaction of nitric oxide with tetrafluoroethylene, and formation of a nitrosopolymer |journal=Journal of the Chemical Society (Resumed) |date=1962 |pages=3021 |doi=10.1039/JR9620003021}}</ref>
|NO<sub>2</sub>CF<sub>2</sub>CF<sub>2</sub>NO
|24.2
|
|176
|679-08-3
|-
|[[Dibromodifluoromethane]]<ref name=yaws/>
|CBr<sub>2</sub>F<sub>2</sub>
|24.45
|−141.5
|210
|75-61-6
|-
|[[Heptafluoro-n-propyl isocyanate|Heptafluoro-''N''-propyl ''iso''cyanate]]<ref name="barr"/>
|C<sub>3</sub>F<sub>7</sub>NCO
|24.5
|
|211
|87050-96-2
|-
|[[Hexafluorobut-2-yne]]<ref name=bu418/>
|CF<sub>3</sub>C≡CCF<sub>3</sub>
|24.6
|−117.4
|162
|692-50-2
|-
|[[1,1,1,4,4,4-Hexafluorobutane]]<ref>{{Cite journal|last1=Baker|first1=Max T|last2=Ruzicka|first2=Jan A|last3=Tinker|first3=John H|date=April 1999|title=One step synthesis of 1,1,1,4,4,4-hexafluorobutane from succinonitrile|journal=Journal of Fluorine Chemistry|language=en|volume=94|issue=2|pages=123–126|doi=10.1016/S0022-1139(98)00311-X}}</ref>
|CF<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CF<sub>3</sub>
|24.6
|
|
|407-59-0
|-
|[[Chloroheptafluorocyclobutane]]
|C<sub>4</sub>ClF<sub>7</sub>
|25
|−39.1
|216.5
|377-41-3
|-
|[[Dimethylphosphine]]
|(CH<sub>3</sub>)<sub>2</sub>PH
|25
|
|62
|676-59-5
|-
|[[Ethyl phosphine]]<ref>{{cite journal |last1=Wagner |first1=Ross I. |last2=Freeman |first2=LeVern D. |last3=Goldwhite |first3=H. |last4=Rowsell |first4=D. G. |title=Phosphiran |journal=Journal of the American Chemical Society |date=March 1967 |volume=89 |issue=5 |pages=1102–1104 |doi=10.1021/ja00981a013}}</ref>
|CH<sub>3</sub>CH<sub>2</sub>PH<sub>2</sub>
|25
|
|62
|593-68-0
|-
|[[Octafluorocyclopentene]]<ref name=bu416/>
|C<sub>5</sub>F<sub>8</sub>
|25
|
|212
|559-40-0
|-
|[[2-Fluorobutane]]<ref>{{cite web |title=2-Fluorobutane {{!}} C4H9F {{!}} ChemSpider |url=http://www.chemspider.com/Chemical-Structure.2282432.html |website=www.chemspider.com}}</ref>
|CH<sub>3</sub>CHFCH<sub>2</sub>CH<sub>3</sub>
|25
|−121
|76
|359-01-3
|-
|}


==Known as gas==
==Known as gas==

Revision as of 15:09, 31 January 2021

Boiling liquid oxygen

This is a list of gases at standard conditions, which means substances that boil or sublime at or below 25 °C (77 °F) and 1 atm pressure and are reasonably stable.

DONT USE WIKI

Known as gas

The following list has substances known to be gases, but with an unknown boiling point.

Possible

This list includes substances that may be gases. However reliable references are not available.

Near misses

This list includes substances that boil just above standard condition temperatures. Numbers are boiling temperatures in °C.

Unstable substances

  • Gallium(III) hydride liquid decomposes at 0 °C.
  • Nitroxyl is unstable and short lived.
  • Sulfur pentafluoride isocyanide isomerises to sulfur pentafluoride cyanide.[22]

References

  • Haynes, W. M., ed. (2016). CRC Handbook of Chemistry and Physics (96th ed.). Boca Raton, Florida: CRC Press/Taylor & Francis. pp. 3–4–4–101. ISBN 978-1482260960.
  1. ^ Thompson, Phillip Gerhard. (August 1967). "Bis(perfluoroalkyl) trioxides". Journal of the American Chemical Society. 89 (17): 4316–4319. doi:10.1021/ja00993a012.
  2. ^ Cite error: The named reference US Patent 3226418 was invoked but never defined (see the help page).
  3. ^ Varetti, E. L.; Aymonino, P. J. (1967). "New photochemical routes to perfluoromethyl carbonate". Chemical Communications (London) (14): 680. doi:10.1039/C19670000680.
  4. ^ Russo, Antonio; DesMarteau, Darryl D. (June 1993). "Difluorodioxirane". Angewandte Chemie International Edition in English. 32 (6): 905–907. doi:10.1002/anie.199309051.
  5. ^ De Marco, Ronald A.; Shreeve, Jean'ne M. (May 2002). "Reactions of the fluorimide-potassium fluoride adduct HNF2.KF, with sulfinyl and perfluoroalkylsulfinyl fluorides. Preparation of perfluoroalkyl perfluoroalkylthiosulfonates". Inorganic Chemistry. 12 (8): 1896–1899. doi:10.1021/ic50126a040.
  6. ^ Cite error: The named reference rat was invoked but never defined (see the help page).
  7. ^ Horsewood, Peter; Kirby, Gordon W. (1980). "Preparation and dienophilic reactions of nitrosyl cyanide". Journal of the Chemical Society, Perkin Transactions 1: 1587. doi:10.1039/P19800001587.
  8. ^ "1,1,2,3,4,4-Hexafluoro-1,3-butadiene | C4F6 | ChemSpider". www.chemspider.com.
  9. ^ https://www.efgases.com/wp-content/uploads/EFC_Brochure_v3.pdf. {{cite web}}: Missing or empty |title= (help)
  10. ^ Martin, E. L.; Sharkey, W. H. (October 1959). "1,1,4,4-Tetrafluoro-1,2,3-butatriene". Journal of the American Chemical Society. 81 (19): 5256–5258. doi:10.1021/ja01528a056.
  11. ^ Ehm, Christian; Lentz, Dieter (21 January 2011). "Cyclic dimers of tetrafluorobutatriene". Theoretical Chemistry Accounts. 129 (3–5): 507–515. doi:10.1007/s00214-011-0890-3. S2CID 98473500.
  12. ^ "perfluoropent-1-ene | C5F10 | ChemSpider". www.chemspider.com.
  13. ^ a b c d e f g h i j k Cite error: The named reference yaws was invoked but never defined (see the help page).
  14. ^ Ulic, S. E.; von Ahsen, S.; Willner, H. (August 2004). "Photoisomerization of Matrix-Isolated Bis(trifluoromethyl) Sulfoxide: Formation of the Sulfenic Ester CF3SOCF3". Inorganic Chemistry. 43 (17): 5268–5274. doi:10.1021/ic049800r. PMID 15310204.
  15. ^ Cite error: The named reference miller was invoked but never defined (see the help page).
  16. ^ Cite error: The named reference gould was invoked but never defined (see the help page).
  17. ^ Cite error: The named reference burdon was invoked but never defined (see the help page).
  18. ^ "1,1,2,2,3-Pentafluoropropane 411078". Sigma-Aldrich.
  19. ^ a b Burns, T. H. S.; Bracken, A. (1972). "Exploratory and Newer Compounds". Modern Inhalation Anesthetics. Springer Berlin Heidelberg. pp. 416–417. doi:10.1007/978-3-642-65055-0_19. ISBN 9783642650574.
  20. ^ Banks, R. E.; Harrison, A. C.; Haszeldine, R. N. (1966). "Polyfluorocyclopentadienes. Part II. The thermal dimer of perfluorocyclopentadiene: perfluoro(tricyclo[5,2,1,02,6]deca-3,8-diene)". Journal of the Chemical Society C: Organic: 2102. doi:10.1039/J39660002102.
  21. ^ "Trifluoromethanesulfonyl chloride 164798". Sigma-Aldrich.
  22. ^ Thrasher, Joseph S.; Madappat, Krishnan V. (September 1989). "Sulfur-Pentafluoride Isocyanide, SF5NC". Angewandte Chemie International Edition in English. 28 (9): 1256–1258. doi:10.1002/anie.198912561.
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