Chicken wire (chemistry): Difference between revisions
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* Non-[[aromatic]] polycyclic [[hydrocarbon]]s, e.g. [[steroids]] like [[cholesterol]]<ref>[http://www.gethealthygetsmart.com/articles/cholesterol_excess_fat.asp Get Healthy...Get Smart<!-- Bot generated title -->]</ref> |
* Non-[[aromatic]] polycyclic [[hydrocarbon]]s, e.g. [[steroids]] like [[cholesterol]]<ref>[http://www.gethealthygetsmart.com/articles/cholesterol_excess_fat.asp Get Healthy...Get Smart<!-- Bot generated title -->]</ref> |
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* Flat hexagonal [[hydrogen bond]]ed |
* Flat hexagonal [[hydrogen bond]]ed [[trimesic acid]] (benzene-1,3,5-tricarboxylic acid)<ref>[http://www.scs.uiuc.edu/zimmerman/papers/63.pdf]</ref> or [[melamine-cyanuric acid complex]]es<ref name="burrows">{{cite journal |
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| author = Andrew D. Burrows |
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| year = 2004 |
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| title = Crystal Engineering Using Multiple Hydrogen Bonds |
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| journal = Structure and Bonding |
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| volume = 108 |
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| issue = |
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| pages = 55–96 |
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| pmid = |
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| ISSN = ISSN 0081-5993 (Print) |
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| ISSN = ISSN 1616-8550 (online) |
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| doi = 10.1007/b14137 |
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| url = http://www.springerlink.com/content/tfb8mwejrw0m7v2r/ |
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}} |
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</ref> |
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* Interwoven molecule chains in the inorganic polymer NaAuS <ref>PMID 11670705</ref> |
* Interwoven molecule chains in the inorganic polymer NaAuS <ref>PMID 11670705</ref> |
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* Complexes of the [[protein]] [[clathrin]]<ref>[http://bio.winona.msus.edu/wilson/cell%20biology/unit3revANSWER.doc]</ref> |
* Complexes of the [[protein]] [[clathrin]]<ref>[http://bio.winona.msus.edu/wilson/cell%20biology/unit3revANSWER.doc]</ref> |
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Revision as of 22:19, 27 September 2008
The term chicken wire in chemistry is used in different contexts. Most of them relate to the similarity of the regular hexagonal (honeycomb-like) patterns found in certain chemical compounds to the mesh structure commonly seen in real chicken wire.
Polycyclic aromatic hydrocarbons
Polycyclic aromatic hydrocarbons or graphenes including fullerenes, carbon nanotubes, and graphite have a hexagonal structure that is often described as chicken wire-like. [1] [2] [3]
Hexagonal molecular structures
A hexagonal structure that is often described as chicken wire-like can also be found in other types of chemical compounds. Examples are:
- Non-aromatic polycyclic hydrocarbons, e.g. steroids like cholesterol[4]
- Flat hexagonal hydrogen bonded trimesic acid (benzene-1,3,5-tricarboxylic acid)[5] or melamine-cyanuric acid complexes[6]
- Interwoven molecule chains in the inorganic polymer NaAuS [7]
- Complexes of the protein clathrin[8]
Bond line notation
The bond line notation is a method to draw structural formulas of organic compounds where lines represent the chemical bonds and the edges represent implicit carbon atoms [9]. This notation is sometimes jestingly called chicken wire notation. [10][11][12]
Placeholder for organic compounds
Chicken wire is sometimes used as a placeholder name for any organic compound, similar to the use of the name John Doe.[citation needed]
Chemical joke
It is an old and notable joke in chemistry to draw a polycyclic hexagonal chemical structure and call this fictional compound chickenwire. By adding one or two simple chemical groups to this skeleton, the compound can then be named following the official chemical naming convention. Examples are:
- 1,2-Dimethyl-chickenwire in a cartoon by Nick D. Kim
Surface plots
In computational chemistry a chicken wire model or chicken wire surface plot is a way to visualize molecular models by drawing the polygon mesh of their surface (defined e.g. as the van der Waals radius or a certain electron density). [13][14][15][16][17]
References
- ^ Soccerballs
- ^ General Chemistry Online: Glossary:
- ^ Space Chemicals: Scientific American
- ^ Get Healthy...Get Smart
- ^ [1]
- ^ Andrew D. Burrows (2004). "Crystal Engineering Using Multiple Hydrogen Bonds". Structure and Bonding. 108: 55–96. doi:10.1007/b14137. ISSN 1616-8550 (online) ISSN 1616-8550 (online).
{{cite journal}}: Check|issn=value (help) - ^ PMID 11670705
- ^ [2]
- ^ Template
- ^ Chem 32 Virtual Manual
- ^ Stereochemistry and Chirality Part I Problems
- ^ Chem 32 Virtual Manual
- ^ [3]
- ^ [4]
- ^ MolScript v2.1: Interface to external objects
- ^ [5]
- ^ [6]