Bulk modulus

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Illustration of uniform compression

The bulk modulus (K or B) of a substance measures the substance's resistance to uniform compression. It is defined as the ratio of the infinitesimal pressure increase to the resulting relative decrease of the volume. Its SI unit is the pascal, and its dimensional form is M1L-1T−2.[1]

Definition[edit]

The bulk modulus K>0 can be formally defined by the equation

K=-V\frac{\mathrm d P}{\mathrm d V}

where P is pressure, V is volume, and dP/dV denotes the derivative of pressure with respect to volume. Equivalently

K=\rho \frac{\mathrm d P}{\mathrm d \rho}

where ρ is density and dP/dρ denotes the derivative of pressure with respect to density. The inverse of the bulk modulus gives a substance's compressibility.

Other moduli describe the material's response (strain) to other kinds of stress: the shear modulus describes the response to shear, and Young's modulus describes the response to linear stress. For a fluid, only the bulk modulus is meaningful. For an anisotropic solid such as wood or paper, these three moduli do not contain enough information to describe its behaviour, and one must use the full generalized Hooke's law.

Thermodynamic relation[edit]

Strictly speaking, the bulk modulus is a thermodynamic quantity, and in order to specify a bulk modulus it is necessary to specify how the temperature varies during compression: constant-temperature (isothermal K_T), constant-entropy (adiabatic K_S), and other variations are possible. Such distinctions are especially relevant for gases.

For an ideal gas, the adiabatic bulk modulus K_S is given by


K_S=\gamma\, P

and the isothermal bulk modulus K_T is given by


K_T=P\,

where

γ is the adiabatic index, sometimes called κ.
P is the pressure.

When the gas is not ideal, these equations give only an approximation of the bulk modulus. In a fluid, the bulk modulus K and the density ρ determine the speed of sound c (pressure waves), according to the Newton-Laplace formula

c=\sqrt{\frac{K}{\rho}}.

In solids, K_S and K_T have very similar values. Solids can also sustain transverse waves: for these materials one additional elastic modulus, for example the shear modulus, is needed to determine wave speeds.

Measurement[edit]

It is possible to measure the bulk modulus using powder diffraction under applied pressure. It is a property of a fluid which shows its ability to change its volume under its pressure.

Selected values[edit]

Approximate bulk modulus (K) for common materials
Material Bulk modulus in GPa Bulk modulus in ksi
Glass (see also diagram below table) 35 to 55 5.8×103
Steel 160 23×103
Diamond (at 4K) [2] 443 64×103
Influences of selected glass component additions on the bulk modulus of a specific base glass.[3]

A material with a bulk modulus of 35 GPa loses one percent of its volume when subjected to an external pressure of 0.35 GPa (~3500 Bar).

Approximate bulk modulus (K) for other substances
Water 2.2×109 Pa (value increases at higher pressures)
Methanol 8.23×108 Pa (at 20°C and 1 Atm)
Air 1.42×105 Pa (adiabatic bulk modulus)
Air 1.01×105 Pa (constant temperature bulk modulus)
Solid helium 5×107 Pa (approximate)

References[edit]

  1. ^ "Bulk Elastic Properties". hyperphysics. Georgia State University. 
  2. ^ Page 52 of "Introduction to Solid State Physics, 8th edition" by Charles Kittel, 2005, ISBN 0-471-41526
  3. ^ Fluegel, Alexander. "Bulk modulus calculation of glasses". glassproperties.com. 
Conversion formulas
Homogeneous isotropic linear elastic materials have their elastic properties uniquely determined by any two moduli among these, thus given any two, any other of the elastic moduli can be calculated according to these formulas.
(K,\,E) (K,\,\lambda) (K,\,G) (K,\, \nu) (E,\,G) (E,\,\nu) (\lambda,\,G) (\lambda,\,\nu) (G,\,\nu) (G,\,M)
K=\, K K K K \tfrac{EG}{3(3G-E)} \tfrac{E}{3(1-2\nu)} \lambda+ \tfrac{2G}{3} \tfrac{\lambda(1+\nu)}{3\nu} \tfrac{2G(1+\nu)}{3(1-2\nu)} M - \tfrac{4G}{3}
E=\, E \tfrac{9K(K-\lambda)}{3K-\lambda} \tfrac{9KG}{3K+G} 3K(1-2\nu)\, E E \tfrac{G(3\lambda + 2G)}{\lambda + G} \tfrac{\lambda(1+\nu)(1-2\nu)}{\nu} 2G(1+\nu)\, \tfrac{G(3M-4G)}{M-G}
\lambda=\, \tfrac{3K(3K-E)}{9K-E} \lambda K-\tfrac{2G}{3} \tfrac{3K\nu}{1+\nu} \tfrac{G(E-2G)}{3G-E} \tfrac{E\nu}{(1+\nu)(1-2\nu)} \lambda \lambda \tfrac{2 G \nu}{1-2\nu} M - 2G\,
G=\, \tfrac{3KE}{9K-E} \tfrac{3(K-\lambda)}{2} G \tfrac{3K(1-2\nu)}{2(1+\nu)} G \tfrac{E}{2(1+\nu)} G \tfrac{\lambda(1-2\nu)}{2\nu} G G
\nu=\, \tfrac{3K-E}{6K} \tfrac{\lambda}{3K-\lambda} \tfrac{3K-2G}{2(3K+G)} \nu \tfrac{E}{2G}-1 \nu \tfrac{\lambda}{2(\lambda + G)} \nu \nu \tfrac{M - 2G}{2M - 2G}
M=\, \tfrac{3K(3K+E)}{9K-E} 3K-2\lambda\, K+\tfrac{4G}{3} \tfrac{3K(1-\nu)}{1+\nu} \tfrac{G(4G-E)}{3G-E} \tfrac{E(1-\nu)}{(1+\nu)(1-2\nu)} \lambda+2G\, \tfrac{\lambda(1-\nu)}{\nu} \tfrac{2G(1-\nu)}{1-2\nu} M