Dithionous acid has not been detected either as a pure compound or in solution. Dithionite ions undergo both acid and alkaline hydrolysis to thiosulfate and bisulfite, and sulfite and sulfide, respectively
- 2 S2O2−
4 + H2O → S2O2−
3 + 2 HSO−
- 3 Na2S2O4 + 6 NaOH → 5 Na2SO3 + Na2S + 3 H2O
Dithionite is often used in conjunction with complexing agent (e.g., citric acid) to reduce iron(III) oxy-hydroxide into soluble iron(II) compounds and to remove amorphous iron(III)-bearing mineral phases in soil analyses (selective extraction).
The decomposition of dithionite produces reduced species of sulfur that can be very aggressive for the corrosion of steel and stainless steel. Thiosulfate (S2O2−
3) is well known to induce pitting corrosion while dissolved free sulfide (Na2S) is responsible for stress corrosion cracking (SCC).
- Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 0080379419.
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