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==Notes for identification==
==Notes for identification==
[[Image:Kyanite.JPG|thumb|left|Deep blue kyanite]]
[[Image:Kyanite.JPG|thumb|left|Deep blue kyanite]]
Kyanite's elongated, columnar crystals are usually a good first indication of the mineral, as well as its color (when the specimen is blue). Associated minerals are useful as well, especially the presence of the [[Polymorphism (materials science)|polymorphs]] of [[staurolite]], which occur frequently with kyanite. However, the most useful characteristic in identifying kyanite is its anisotropism. If one suspects a specimen to be kyanite, verifying that it has two distinctly different [[Mohs hardness scale|hardness]] on perpendicular axes is a key to identification; it has a hardness of 5.5 parallel to {001} and 7 parallel to {100}.<ref name=Handbook/><ref name=Mindat/>
Kyanite's elongated, columnar crystals are usually a good first indication of the mineral, as well as its color (when the specimen is blue). Associated minerals are useful as well, especially the presence of the [[Polymorphism (materials science)|polymorphs]] of [[staurolite]], which occur frequently with kyanite. However, the most useful characteristic in identifying kyanite is its anisotropism. If one suspects a specimen to be kyanite, verifying that it has two distinctly different [[Mohs hardness scale|hardness]] on perpendicular axes is a key to identification; it has a hardness
of 5.5 parallel to {001} and 7 parallel to {100}.<ref name=Handbook/><ref name=Mi
TEANDRA THOMPSON(:


==Occurrence==
==Occurrence==

Revision as of 17:35, 12 February 2014

Kyanite
General
CategoryNesosilicate
Formula
(repeating unit)
Al2SiO5
Strunz classification09.AF.15
Crystal systemTriclinic
Space groupTriclinic pinacoidal H–M Symbol: 1 Space group: P1
Unit cella = 7.1262(12) Å,
b = 7.852(10) Å,
c = 5.5724(10) Å
α = 89.99(2)°, β = 101.11(2)°, γ = 106.03(1)°
Z = 4
Identification
ColorBlue, white, rarely green, gray, yellow, pink, orange, and black, can be zoned
Crystal habitColumnar; fibrous; bladed
TwinningLamellar on {100}
Cleavage[100] perfect [010] imperfect with 79° angle between
FractureSplintery
TenacityBrittle
Mohs scale hardness4.5-5 parallel to one axis
6.5-7 perpendicular to that axis
LusterVitreous to pearly
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity3.53 - 3.65 measured; 3.67 calculated
Optical propertiesBiaxial (-)
Refractive indexnα = 1.712 - 1.718 nβ = 1.720 - 1.725 nγ = 1.727 - 1.734
PleochroismTrichroic, colorless to pale blue to blue
2V angle78°-83°
References[1][2][3]

Kyanite, whose name derives from the Greek word kuanos sometimes referred to as "kyanos", meaning deep blue, is a typically blue silicate mineral, commonly found in aluminium-rich metamorphic pegmatites and/or sedimentary rock. Kyanite in metamorphic rocks generally indicates pressures higher than four kilobars. Although potentially stable at lower pressure and low temperature, the activity of water is usually high enough under such conditions that it is replaced by hydrous aluminosilicates such as muscovite, pyrophyllite, or kaolinite. Kyanite is also known as disthene, rhaeticite and cyanite.

Kyanite is a member of the aluminosilicate series, which also includes the polymorph andalusite and the polymorph sillimanite. Kyanite is strongly anisotropic, in that its hardness varies depending on its crystallographic direction. In kyanite, this anisotropism can be considered an identifying characteristic.

At temperatures above 1100 °C kyanite decomposes into mullite and vitreous silica via the following reaction: 3(Al2O3·SiO2) → 3Al2O3·2SiO2 + SiO2. This transformation results in an expansion.[4]

Uses

Kyanite is used primarily in refractory and ceramic products, including porcelain plumbing fixtures and dishware. It is also used in electronics, electrical insulators and abrasives.

Kyanite has been used as a semiprecious gemstone, which may display cat's eye chatoyancy, though this use is limited by its anisotropism and perfect cleavage. Color varieties include recently discovered orange kyanite from Tanzania.[citation needed] The orange color is due to inclusion of small amounts of manganese (Mn3+) in the structure.[5]

Kyanite is one of the index minerals that are used to estimate the temperature, depth, and pressure at which a rock undergoes metamorphism.

Notes for identification

Deep blue kyanite

Kyanite's elongated, columnar crystals are usually a good first indication of the mineral, as well as its color (when the specimen is blue). Associated minerals are useful as well, especially the presence of the polymorphs of staurolite, which occur frequently with kyanite. However, the most useful characteristic in identifying kyanite is its anisotropism. If one suspects a specimen to be kyanite, verifying that it has two distinctly different hardness on perpendicular axes is a key to identification; it has a hardness

of 5.5 parallel to {001} and 7 parallel to {100}.[1]Cite error: The <ref> tag has too many names (see the help page).

Kyanite occurs in Manhattan schist, formed under extreme pressure as a result of the two landmasses that formed supercontinent Pangaea.[6]

References

Phase diagram of Al2SiO5
(aluminosilicates).[7]
Specific citations
  1. ^ a b Downs, Bob (2001). Handbook of Mineralogy "Kyanite". The RRUFF Project. Retrieved 2013-06-13. {{cite web}}: Check |url= value (help)
  2. ^ "Kyanite". MinDat. Retrieved 2013-06-14.
  3. ^ "Kyanite Mineral Data". Webmineral.com. Retrieved 2013-06-14.
  4. ^ Speyer, Robert (1993). Thermal Analysis of Materials. CRC Press. p. 166. ISBN 0-8247-8963-6.
  5. ^ M. Gaft (August 2011). "Laser-induced time-resolved luminescence of orange kyanite Al2SiO5". Optical Materials. 33 (10). sciencedirect.com: 1476–1480. Bibcode:2011OptMa..33.1476G. doi:10.1016/j.optmat.2011.03.052. {{cite journal}}: Unknown parameter |coauthors= ignored (|author= suggested) (help)
  6. ^ Quinn, Helen (6 June 2013). "How ancient collision shaped New York skyline". BBC Science. BBC.co.uk. Retrieved 2013-06-13. Prof Stewart was keeping an eye out for a mineral known as kyanite, a beautiful blue specimen commonly seen in the Manhattan schist. 'Kyanite is a key mineral to identify, we know it only forms at very deep depths and under extensive pressure,' he said. 'It's like a fingerprint, revealing a wealth of information.' The presence of this mineral reveals that the Manhattan schist was compressed under incredibly high pressure over 300 million years ago. The schist formed as a result of two enormous landmasses coming together to form a supercontinent, known as Pangaea.
  7. ^ Whitney, D.L. (2002). "Coexisting andalusite, kyanite, and sillimanite: Sequential formation of three Al2SiO5 polymorphs during progressive metamorphism near the triple point, Sivrihisar, Turkey". American Mineralogist. 87 (4): 405–416. doi:10.2138/am-2002-0404.
General references