Secondary treatment is an effluent quality standard theoretically obtainable by a sewage treatment plant using both physical phase separation to remove settleable solids and a biochemical process to remove dissolved and suspended organic compounds. Sewage meeting this standard may be described as secondary-treated sewage. From an engineering perspective, secondary treatment is the portion of a sewage treatment sequence removing dissolved and colloidal compounds measured as biochemical oxygen demand (BOD). Secondary treatment is traditionally applied to the liquid portion of sewage after primary treatment has removed settleable solids and floating material. Secondary treatment is typically performed by indigenous, aquatic microorganisms in a managed aerobic habitat. Bacteria and protozoa consume biodegradable soluble organic contaminants (e.g. sugars, fats, and organic short-chain carbon molecules from human waste, food waste, soaps and detergent) while reproducing to form cells of biological solids. Biological oxidation processes are sensitive to temperature and, between 0 °C and 40 °C, the rate of biological reactions increase with temperature. Most surface aerated vessels operate at between 4 °C and 32 °C.
Primary treatment of sewage by quiescent settling allows separation of floating material and heavy solids from liquid waste. The remaining liquid usually contains less than half of the original solids content and approximately two-thirds of the BOD in the form of colloids and dissolved organic compounds. Where nearby water bodies can rapidly dilute this liquid waste, primary treated sewage may be discharged so natural biological decomposition oxidizes remaining waste. The city of San Diego used Pacific Ocean dilution of primary treated effluent into the 21st century. Where natural waterways are too small to rapidly oxidize primary treated sewage, the liquid may be used to irrigate sewage farms until suburban property values encourage secondary treatment methods requiring less acreage. Glacial sand deposits allowed some northeastern United States cities to use intermittent sand filtration until more compact secondary treatment bioreactors became available.
Fixed-film or attached growth secondary treatment systems are similar to a plug flow reactor model circulating water over surfaces colonized by biofilm, while suspended-growth systems resemble a continuous stirred-tank reactor keeping microorganisms suspended while water is being treated. Secondary treatment bioreactors may be followed by a physical phase separation to remove biological solids from the treated water. Suspended growth activated sludge systems can be operated in a smaller space than fixed-film trickling filter systems that treat the same amount of water; but fixed-film systems are better able to cope with drastic changes in the amount of biological material and can provide higher removal rates for organic material and suspended solids than suspended growth systems.:11–13
The United States Environmental Protection Agency defined secondary treatment at 40CFR133.102 on the basis of performance observed at late 20th-century bioreactors treating typical United States municipal sewage. Secondary treated sewage is expected to produce effluent with a monthly average of less than 30 mg/l BOD and less than 30 mg/l suspended solids. Weekly averages may be up to 50 percent higher. A sewage treatment plant providing both primary and secondary treatment is expected to remove at least 85 percent of the BOD and suspended solids from domestic sewage. The United States Code of Federal Regulations describes stabilization ponds as providing treatment equivalent to secondary treatment removing 65 percent of the BOD and suspended solids from incoming sewage and discharging approximately 50 percent higher effluent concentrations than modern bioreactors. The regulations also recognize the difficulty of meeting the specified removal percentages from combined sewers, dilute industrial wastewater, or Infiltration/Inflow.
Filter beds (oxidizing beds)
In older plants and those receiving variable loadings, trickling filter beds are used where the settled sewage liquor is spread onto the surface of a bed made up of coke (carbonized coal), limestone chips or specially fabricated plastic media. Such media must have large surface areas to support the biofilms that form. The liquor is typically distributed through perforated spray arms. The distributed liquor trickles through the bed and is collected in drains at the base. These drains also provide a source of air which percolates up through the bed, keeping it aerobic. Biofilms of bacteria, protozoa and fungi form on the media’s surfaces and eat or otherwise reduce the organic content.:12 The filter removes a small percentage of the suspended organic matter, while the majority of the organic matter supports microorganism reproduction and cell growth from the biological oxidation and nitrification taking place in the filter. With this aerobic oxidation and nitrification, the organic solids are converted into biofilm grazed by insect larvae, snails, and worms which help maintain an optimal thickness. Overloading of beds may increase biofilm thickness leading to anaerobic conditions and possible clogging of the filter media and ponding on the surface.
Rotating biological contactors
Rotating biological contactors (RBCs) are robust mechanical fixed-film secondary treatment systems capable of withstanding surges in organic load. RBCs were first installed in Germany in 1960 and have since been developed and refined into a reliable operating unit. The rotating disks support the growth of bacteria and micro-organisms present in the sewage, which break down and stabilize organic pollutants. To be successful, micro-organisms need both oxygen to live and food to grow. Oxygen is obtained from the atmosphere as the disks rotate. As the micro-organisms grow, they build up on the media until they are sloughed off due to shear forces provided by the rotating discs in the sewage. Effluent from the RBC is then passed through a secondary clarifier where the sloughed biological solids in suspension settle as a sludge.
Activated sludge is a common suspended-growth method of secondary treatment. Activated sludge plants encompass a variety of mechanisms and processes using dissolved oxygen to promote growth of biological floc that substantially removes organic material.:12–13 Biological floc is an ecosystem of living biota subsisting on nutrients from the inflowing primary clarifier effluent. These mostly carbonaceous dissolved solids undergo aeration to be broken down and either biologically oxidized to carbon dioxide or converted to additional biological floc of reproducing micro-organisms. Nitrogenous dissolved solids (amino acids, ammonia, etc.) are similarly converted to biological floc or oxidized by the floc to nitrites, nitrates, and, in some processes, to nitrogen gas through denitrification. While denitrification is encouraged in some treatment processes, denitrification often impairs the settling of the floc causing poor quality effluent in many suspended aeration plants. Overflow from the activated sludge mixing chamber is sent to a secondary clarifier where the suspended biological floc settles out while the treated water moves into tertiary treatment or disinfection. Settled floc is returned to the mixing basin to continue growing in primary effluent. Like most ecosystems, population changes among activated sludge biota can reduce treatment efficiency. Nocardia, a floating brown foam sometimes misidentified as sewage fungus, is the best known of many different fungi and protists that can overpopulate the floc and cause process upsets. Elevated concentrations of toxic wastes including pesticides, industrial metal plating waste, or extreme pH, can kill the biota of an activated sludge reactor ecosystem.
Membrane bioreactors (MBR) are activated sludge systems using a membrane liquid-solid phase separation process. The membrane component uses low pressure microfiltration or ultrafiltration membranes and eliminates the need for a secondary clarifier or filtration. The membranes are typically immersed in the aeration tank; however, some applications utilize a separate membrane tank. One of the key benefits of an MBR system is that it effectively overcomes the limitations associated with poor settling of sludge in conventional activated sludge (CAS) processes. The technology permits bioreactor operation with considerably higher mixed liquor suspended solids (MLSS) concentration than CAS systems, which are limited by sludge settling. The process is typically operated at MLSS in the range of 8,000–12,000 mg/L, while CAS are operated in the range of 2,000–3,000 mg/L. The elevated biomass concentration in the MBR process allows for very effective removal of both soluble and particulate biodegradable materials at higher loading rates. Thus increased sludge retention times, usually exceeding 15 days, ensure complete nitrification even in extremely cold weather.
The cost of building and operating an MBR is often higher than conventional methods of sewage treatment. Membrane filters can be blinded with grease or abraded by suspended grit and lack a clarifier's flexibility to pass peak flows. The technology has become increasingly popular for reliably pretreated waste streams and has gained wider acceptance where infiltration and inflow have been controlled, however, and the life-cycle costs have been steadily decreasing. The small footprint of MBR systems, and the high quality effluent produced, make them particularly useful for water reuse applications.
Surface-aerated basins (lagoons)
Aerated lagoons are a low technology suspended-growth method of secondary treatment using motor-driven aerators floating on the water surface to increase atmospheric oxygen transfer to the lagoon and to mix the lagoon contents. The floating surface aerators are typically rated to deliver the amount of air equivalent to 1.8 to 2.7 kg O2/kW·h. Aerated lagoons provide less effective mixing than conventional activated sludge systems and do not achieve the same performance level. The basins may range in depth from 1.5 to 5.0 metres. Surface-aerated basins achieve 80 to 90 percent removal of BOD with retention times of 1 to 10 days. Many small municipal sewage systems in the United States (1 million gal./day or less) use aerated lagoons.
Primary clarifier effluent was discharged directly to eutrophic natural wetlands for decades before environmental regulations discouraged the practice. Where adequate land is available, stabilization ponds with constructed wetland ecosystems can be built to perform secondary treatment separated from the natural wetlands receiving secondary treated sewage. Constructed wetlands resemble fixed-film systems more than suspended growth systems, because natural mixing is minimal. Constructed wetland design uses plug flow assumptions to compute the residence time required for treatment. Patterns of vegetation growth and solids deposition in wetland ecosystems, however, can create preferential flow pathways which may reduce average residence time. Measurement of wetland treatment efficiency is complicated because most traditional water quality measurements cannot differentiate between sewage pollutants and biological productivity of the wetland. Demonstration of treatment efficiency may require more expensive analyses.
- Aerobic granulation
- Biological Aerated (or Anoxic) Filter (BAF) or Biofilters combine filtration with biological carbon reduction, nitrification or denitrification. BAF usually includes a reactor filled with a filter media. The media is either in suspension or supported by a gravel layer at the foot of the filter. The dual purpose of this media is to support highly active biomass that is attached to it and to filter suspended solids. Carbon reduction and ammonia conversion occurs in aerobic mode and sometime achieved in a single reactor while nitrate conversion occurs in anoxic mode. BAF is operated either in upflow or downflow configuration depending on design specified by manufacturer.
- Integrated Fixed-Film Activated Sludge (IFAS)
- Moving Bed Biofilm Reactors (MBBR) typically requires smaller footprint than suspended-growth systems.
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