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Zinc nitrate

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Zinc nitrate
Zinc nitrate
Names
IUPAC name
Zinc nitrate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.038 Edit this at Wikidata
EC Number
  • 231-943-8
RTECS number
  • ZH4772000
UN number 1514
  • InChI=1S/2NO3.Zn/c2*2-1(3)4;/q2*-1;+2 checkY
    Key: ONDPHDOFVYQSGI-UHFFFAOYSA-N checkY
  • InChI=1/2NO3.Zn/c2*2-1(3)4;/q2*-1;+2
    Key: ONDPHDOFVYQSGI-UHFFFAOYAQ
  • [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Zn+2]
Properties
Zn(NO3)2
Molar mass 189.36 g/mol (anhydrous)
297.49 g/mol (hexahydrate)
Appearance colorless, deliquescent crystals
Density 2.065 g/cm3 (hexahydrate)
Melting point 110 °C (anhydrous)
45.5 °C (trihydrate)
36.4 °C (hexahydrate)
Boiling point ~125 °C, decomp (hexahydrate)
327 g/100 mL, 40 °C (trihydrate)
184.3 g/100 ml, 20 °C (hexahydrate)
Solubility very soluble in alcohol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Oxidant, may explode on heating
Flash point Non-flammable
Related compounds
Other anions
Zinc sulfate
Zinc chloride
Other cations
Cadmium nitrate
Mercury(II) nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Zinc nitrate is a highly deliquescent substance which is usually prepared by dissolving zinc in nitric acid. It can be used as a mordant in dyeing. An example reaction gives a precipitate of zinc carbonate: Zn(NO3)2 + Na2CO3 → ZnCO3 + 2 NaNO3.

Conditions/substances to avoid are: reducing agents, organic materials, metal powders, heat and flame, cyanides, sodium hypophosphite, tin(IV) chloride, phosphorus, thiocyanates, carbon, and sulfur.

Zinc nitrate is soluble in both water and alcohol.

Zinc forms zinc nitrate in reaction with nitric acid, but depending on the concentration of the acid it reacts differently:

3Zn + 8HNO3 conc. → 3Zn(NO3)2 + 2NO + 4H2O

Zn + HNO3 dil. → Zn(NO3)2 + NH4NO3 + H2O

References