Valienamine: Difference between revisions

Valienamine
Names
	IUPAC name (1S,2S,3R,6S)-6-amino-4-(hydroxymethyl)cyclohex-4-ene-1,2,3-triol
Identifiers
CAS Number	38231-86-6 ;
3D model (JSmol)	Interactive image;
ChEMBL	ChEMBL1230806 ;
ChemSpider	168149 ;
PubChem CID	193758;
CompTox Dashboard (EPA)	DTXSID80191622 ;
	InChI InChI=1S/C7H13NO4/c8-4-1-3(2-9)5(10)7(12)6(4)11/h1,4-7,9-12H,2,8H2/t4-,5+,6-,7-/m0/s1 Key: XPHOBMULWMGEBA-VZFHVOOUSA-N ; InChI=1/C7H13NO4/c8-4-1-3(2-9)5(10)7(12)6(4)11/h1,4-7,9-12H,2,8H2/t4-,5+,6-,7-/m0/s1 Key: XPHOBMULWMGEBA-VZFHVOOUBJ;
	SMILES O[C@@H]1\C(=C/[C@H](N)[C@H](O)[C@H]1O)CO;
Properties
Chemical formula	C7H13NO4
Molar mass	175.18 g/mol
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

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Revision as of 12:36, 23 January 2012

Valienamine is a C-7 aminocyclitol found as a substructure of pseudooligosaccharides such as acarbose or validamycins. It can be found in Actinoplanes species^[1].

It is an intermediate formed by microbial degradation of validamycins^[2].

References

^ Zhang CS, Stratmann A, Block O; et al. (2002). "Biosynthesis of the C(7)-cyclitol moiety of acarbose in Actinoplanes species SE50/110. 7-O-phosphorylation of the initial cyclitol precursor leads to proposal of a new biosynthetic pathway". J. Biol. Chem. 277 (25): 22853–62. doi:10.1074/jbc.M202375200. PMID 11937512. {{cite journal}}: Explicit use of et al. in: |author= (help); Unknown parameter |month= ignored (help)CS1 maint: multiple names: authors list (link) CS1 maint: unflagged free DOI (link)
^ CID 193758 from PubChem

External links

Valienamine on chemblink.com

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[1] Zhang CS, Stratmann A, Block O; et al. (2002). "Biosynthesis of the C(7)-cyclitol moiety of acarbose in Actinoplanes species SE50/110. 7-O-phosphorylation of the initial cyclitol precursor leads to proposal of a new biosynthetic pathway". J. Biol. Chem. 277 (25): 22853–62. doi:10.1074/jbc.M202375200. PMID 11937512. {{cite journal}}: Explicit use of et al. in: |author= (help); Unknown parameter |month= ignored (help)CS1 maint: multiple names: authors list (link) CS1 maint: unflagged free DOI (link)

[2] CID 193758 from PubChem

[1]

[2]

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 |   PubChem = 193758
 | ChEMBL_Ref = {{ebicite|correct|EBI}}
-| ChEMBL = 174417
+| ChEMBL = 1230806
 |   RTECS =
 |   CASNo_Ref = {{cascite|correct|??}}