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The term '''persulfate''' (sometimes known as peroxysulfate) refers to ions or compounds containing the anions {{chem|SO|5|2−}} or {{chem|S|2|O|8|2−}}.<ref name = Ullmann>{{Ullmann | title = Peroxo Compounds, Inorganic | author = Harald Jakob, Stefan Leininger, Thomas Lehmann, Sylvia Jacobi, Sven Gutewort | doi = 10.1002/14356007.a19_177.pub2}}</ref> The anion {{chem|SO|5|2−}} contains one peroxide group per sulfur center, whereas in {{chem|S|2|O|8|2−}}, the peroxide group bridges the sulfur atoms. In both cases, sulfur adopts the normal tetrahedral geometry typical for the S(VI) oxidation state. These salts are strong oxidizers.<ref>{{cite web|url=http://geocleanse.com/persulfate.asp |title=Geo-Cleanse International |publisher=Geocleanse.com |date= |accessdate=2012-06-13}}</ref><ref>{{cite web|url=https://www.sciencedirect.com/science/article/pii/S1385894717312718 |author = Wacławek, S., Lutze, H. V., Grübel, K., Padil, V.V.T., Černík, M., Dionysiou, D.D. (2017) |title=Chemistry of persulfates in water and wastewater treatment: A review. |doi = 10.1016/j.cej.2017.07.132}}</ref> |
The term '''persulfate''' (sometimes known as peroxysulfate or peroxodisulfate)<ref>{{Cite journal|last=Shafiee|first=Saiful Arifin|last2=Aarons|first2=Jolyon|last3=Hamzah|first3=Hairul Hisham|date=|year=2018|title=Electroreduction of Peroxodisulfate: A Review of a Complicated Reaction|url=http://m.jes.ecsdl.org/content/165/13/H785.abstract?sid=3ddef67b-7f3b-49fa-93a7-c6eee812bfe4|journal=Journal of The Electrochemical Society|publisher=ECS|volume=165|issue=13|pages=H785-H798|doi=10.1149/2.1161811jes|via=}}</ref> refers to ions or compounds containing the anions {{chem|SO|5|2−}} or {{chem|S|2|O|8|2−}}.<ref name = Ullmann>{{Ullmann | title = Peroxo Compounds, Inorganic | author = Harald Jakob, Stefan Leininger, Thomas Lehmann, Sylvia Jacobi, Sven Gutewort | doi = 10.1002/14356007.a19_177.pub2}}</ref> The anion {{chem|SO|5|2−}} contains one peroxide group per sulfur center, whereas in {{chem|S|2|O|8|2−}}, the peroxide group bridges the sulfur atoms. In both cases, sulfur adopts the normal tetrahedral geometry typical for the S(VI) oxidation state. These salts are strong oxidizers.<ref>{{cite web|url=http://geocleanse.com/persulfate.asp |title=Geo-Cleanse International |publisher=Geocleanse.com |date= |accessdate=2012-06-13}}</ref><ref>{{cite web|url=https://www.sciencedirect.com/science/article/pii/S1385894717312718 |author = Wacławek, S., Lutze, H. V., Grübel, K., Padil, V.V.T., Černík, M., Dionysiou, D.D. (2017) |title=Chemistry of persulfates in water and wastewater treatment: A review. |doi = 10.1016/j.cej.2017.07.132}}</ref> |
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==Ions== |
==Ions== |
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Revision as of 14:06, 15 September 2018
The term persulfate (sometimes known as peroxysulfate or peroxodisulfate)[1] refers to ions or compounds containing the anions SO2−
5 or S
2O2−
8.[2] The anion SO2−
5 contains one peroxide group per sulfur center, whereas in S
2O2−
8, the peroxide group bridges the sulfur atoms. In both cases, sulfur adopts the normal tetrahedral geometry typical for the S(VI) oxidation state. These salts are strong oxidizers.[3][4]
Ions
- Peroxomonosulfate ion, SO2−
5 - Peroxydisulfate S
2O2−
8
Acids
- Peroxymonosulfuric acid (Caro's acid), H2SO5
- Peroxydisulfuric acid, H2S2O8
Example salts
- Sodium peroxomonosulfate, Na2SO5
- Potassium peroxymonosulfate, KHSO5
- Sodium persulfate (sodium peroxydisulfate), Na2S2O8
- Ammonium persulfate (ammonium peroxydisulfate), (NH4)2S2O8
- Potassium persulfate (potassium peroxydisulfate), K2S2O8
References
- ^ Shafiee, Saiful Arifin; Aarons, Jolyon; Hamzah, Hairul Hisham (2018). "Electroreduction of Peroxodisulfate: A Review of a Complicated Reaction". Journal of The Electrochemical Society. 165 (13). ECS: H785–H798. doi:10.1149/2.1161811jes.
- ^ Harald Jakob, Stefan Leininger, Thomas Lehmann, Sylvia Jacobi, Sven Gutewort. "Peroxo Compounds, Inorganic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a19_177.pub2. ISBN 978-3527306732.
{{cite encyclopedia}}: CS1 maint: multiple names: authors list (link) - ^ "Geo-Cleanse International". Geocleanse.com. Retrieved 2012-06-13.
- ^ Wacławek, S., Lutze, H. V., Grübel, K., Padil, V.V.T., Černík, M., Dionysiou, D.D. (2017). "Chemistry of persulfates in water and wastewater treatment: A review". doi:10.1016/j.cej.2017.07.132.
{{cite web}}: CS1 maint: multiple names: authors list (link) CS1 maint: numeric names: authors list (link)