Jump to content

Table of spherical harmonics: Difference between revisions

From Wikipedia, the free encyclopedia
Content deleted Content added
m removed the remaining redundant 1 prefactors following edit of 157.193.175.162
Line 265: Line 265:
:<math>Y_{8}^{-7}(\theta,\varphi)={3\over 64}\sqrt{12155\over 2\pi}\cdot e^{-7i\varphi}\cdot\sin^{7}\theta\cdot\cos\theta</math>
:<math>Y_{8}^{-7}(\theta,\varphi)={3\over 64}\sqrt{12155\over 2\pi}\cdot e^{-7i\varphi}\cdot\sin^{7}\theta\cdot\cos\theta</math>
:<math>Y_{8}^{-6}(\theta,\varphi)={1\over 128}\sqrt{7293\over \pi}\cdot e^{-6i\varphi}\cdot\sin^{6}\theta\cdot(15\cos^{2}\theta-1)</math>
:<math>Y_{8}^{-6}(\theta,\varphi)={1\over 128}\sqrt{7293\over \pi}\cdot e^{-6i\varphi}\cdot\sin^{6}\theta\cdot(15\cos^{2}\theta-1)</math>
:<math>Y_{8}^{-5}(\theta,\varphi)={3\over 64}\sqrt{17017\over 2\pi}\cdot e^{-5i\varphi}\cdot\sin^{5}\theta\cdot(5\cos^{3}\theta-1\cos\theta)</math>
:<math>Y_{8}^{-5}(\theta,\varphi)={3\over 64}\sqrt{17017\over 2\pi}\cdot e^{-5i\varphi}\cdot\sin^{5}\theta\cdot(5\cos^{3}\theta-\cos\theta)</math>
:<math>Y_{8}^{-4}(\theta,\varphi)={3\over 128}\sqrt{1309\over 2\pi}\cdot e^{-4i\varphi}\cdot\sin^{4}\theta\cdot(65\cos^{4}\theta-26\cos^{2}\theta+1)</math>
:<math>Y_{8}^{-4}(\theta,\varphi)={3\over 128}\sqrt{1309\over 2\pi}\cdot e^{-4i\varphi}\cdot\sin^{4}\theta\cdot(65\cos^{4}\theta-26\cos^{2}\theta+1)</math>
:<math>Y_{8}^{-3}(\theta,\varphi)={1\over 64}\sqrt{19635\over 2\pi}\cdot e^{-3i\varphi}\cdot\sin^{3}\theta\cdot(39\cos^{5}\theta-26\cos^{3}\theta+3\cos\theta)</math>
:<math>Y_{8}^{-3}(\theta,\varphi)={1\over 64}\sqrt{19635\over 2\pi}\cdot e^{-3i\varphi}\cdot\sin^{3}\theta\cdot(39\cos^{5}\theta-26\cos^{3}\theta+3\cos\theta)</math>
Line 275: Line 275:
:<math>Y_{8}^{3}(\theta,\varphi)={-1\over 64}\sqrt{19635\over 2\pi}\cdot e^{3i\varphi}\cdot\sin^{3}\theta\cdot(39\cos^{5}\theta-26\cos^{3}\theta+3\cos\theta)</math>
:<math>Y_{8}^{3}(\theta,\varphi)={-1\over 64}\sqrt{19635\over 2\pi}\cdot e^{3i\varphi}\cdot\sin^{3}\theta\cdot(39\cos^{5}\theta-26\cos^{3}\theta+3\cos\theta)</math>
:<math>Y_{8}^{4}(\theta,\varphi)={3\over 128}\sqrt{1309\over 2\pi}\cdot e^{4i\varphi}\cdot\sin^{4}\theta\cdot(65\cos^{4}\theta-26\cos^{2}\theta+1)</math>
:<math>Y_{8}^{4}(\theta,\varphi)={3\over 128}\sqrt{1309\over 2\pi}\cdot e^{4i\varphi}\cdot\sin^{4}\theta\cdot(65\cos^{4}\theta-26\cos^{2}\theta+1)</math>
:<math>Y_{8}^{5}(\theta,\varphi)={-3\over 64}\sqrt{17017\over 2\pi}\cdot e^{5i\varphi}\cdot\sin^{5}\theta\cdot(5\cos^{3}\theta-1\cos\theta)</math>
:<math>Y_{8}^{5}(\theta,\varphi)={-3\over 64}\sqrt{17017\over 2\pi}\cdot e^{5i\varphi}\cdot\sin^{5}\theta\cdot(5\cos^{3}\theta-\cos\theta)</math>
:<math>Y_{8}^{6}(\theta,\varphi)={1\over 128}\sqrt{7293\over \pi}\cdot e^{6i\varphi}\cdot\sin^{6}\theta\cdot(15\cos^{2}\theta-1)</math>
:<math>Y_{8}^{6}(\theta,\varphi)={1\over 128}\sqrt{7293\over \pi}\cdot e^{6i\varphi}\cdot\sin^{6}\theta\cdot(15\cos^{2}\theta-1)</math>
:<math>Y_{8}^{7}(\theta,\varphi)={-3\over 64}\sqrt{12155\over 2\pi}\cdot e^{7i\varphi}\cdot\sin^{7}\theta\cdot\cos\theta</math>
:<math>Y_{8}^{7}(\theta,\varphi)={-3\over 64}\sqrt{12155\over 2\pi}\cdot e^{7i\varphi}\cdot\sin^{7}\theta\cdot\cos\theta</math>
Line 286: Line 286:
:<math>Y_{9}^{-6}(\theta,\varphi)={1\over 128}\sqrt{40755\over \pi}\cdot e^{-6i\varphi}\cdot\sin^{6}\theta\cdot(17\cos^{3}\theta-3\cos\theta)</math>
:<math>Y_{9}^{-6}(\theta,\varphi)={1\over 128}\sqrt{40755\over \pi}\cdot e^{-6i\varphi}\cdot\sin^{6}\theta\cdot(17\cos^{3}\theta-3\cos\theta)</math>
:<math>Y_{9}^{-5}(\theta,\varphi)={3\over 256}\sqrt{2717\over \pi}\cdot e^{-5i\varphi}\cdot\sin^{5}\theta\cdot(85\cos^{4}\theta-30\cos^{2}\theta+1)</math>
:<math>Y_{9}^{-5}(\theta,\varphi)={3\over 256}\sqrt{2717\over \pi}\cdot e^{-5i\varphi}\cdot\sin^{5}\theta\cdot(85\cos^{4}\theta-30\cos^{2}\theta+1)</math>
:<math>Y_{9}^{-4}(\theta,\varphi)={3\over 128}\sqrt{95095\over 2\pi}\cdot e^{-4i\varphi}\cdot\sin^{4}\theta\cdot(17\cos^{5}\theta-10\cos^{3}\theta+1\cos\theta)</math>
:<math>Y_{9}^{-4}(\theta,\varphi)={3\over 128}\sqrt{95095\over 2\pi}\cdot e^{-4i\varphi}\cdot\sin^{4}\theta\cdot(17\cos^{5}\theta-10\cos^{3}\theta+\cos\theta)</math>
:<math>Y_{9}^{-3}(\theta,\varphi)={1\over 256}\sqrt{21945\over \pi}\cdot e^{-3i\varphi}\cdot\sin^{3}\theta\cdot(221\cos^{6}\theta-195\cos^{4}\theta+39\cos^{2}\theta-1)</math>
:<math>Y_{9}^{-3}(\theta,\varphi)={1\over 256}\sqrt{21945\over \pi}\cdot e^{-3i\varphi}\cdot\sin^{3}\theta\cdot(221\cos^{6}\theta-195\cos^{4}\theta+39\cos^{2}\theta-1)</math>
:<math>Y_{9}^{-2}(\theta,\varphi)={3\over 128}\sqrt{1045\over \pi}\cdot e^{-2i\varphi}\cdot\sin^{2}\theta\cdot(221\cos^{7}\theta-273\cos^{5}\theta+91\cos^{3}\theta-7\cos\theta)</math>
:<math>Y_{9}^{-2}(\theta,\varphi)={3\over 128}\sqrt{1045\over \pi}\cdot e^{-2i\varphi}\cdot\sin^{2}\theta\cdot(221\cos^{7}\theta-273\cos^{5}\theta+91\cos^{3}\theta-7\cos\theta)</math>
Line 294: Line 294:
:<math>Y_{9}^{2}(\theta,\varphi)={3\over 128}\sqrt{1045\over \pi}\cdot e^{2i\varphi}\cdot\sin^{2}\theta\cdot(221\cos^{7}\theta-273\cos^{5}\theta+91\cos^{3}\theta-7\cos\theta)</math>
:<math>Y_{9}^{2}(\theta,\varphi)={3\over 128}\sqrt{1045\over \pi}\cdot e^{2i\varphi}\cdot\sin^{2}\theta\cdot(221\cos^{7}\theta-273\cos^{5}\theta+91\cos^{3}\theta-7\cos\theta)</math>
:<math>Y_{9}^{3}(\theta,\varphi)={-1\over 256}\sqrt{21945\over \pi}\cdot e^{3i\varphi}\cdot\sin^{3}\theta\cdot(221\cos^{6}\theta-195\cos^{4}\theta+39\cos^{2}\theta-1)</math>
:<math>Y_{9}^{3}(\theta,\varphi)={-1\over 256}\sqrt{21945\over \pi}\cdot e^{3i\varphi}\cdot\sin^{3}\theta\cdot(221\cos^{6}\theta-195\cos^{4}\theta+39\cos^{2}\theta-1)</math>
:<math>Y_{9}^{4}(\theta,\varphi)={3\over 128}\sqrt{95095\over 2\pi}\cdot e^{4i\varphi}\cdot\sin^{4}\theta\cdot(17\cos^{5}\theta-10\cos^{3}\theta+1\cos\theta)</math>
:<math>Y_{9}^{4}(\theta,\varphi)={3\over 128}\sqrt{95095\over 2\pi}\cdot e^{4i\varphi}\cdot\sin^{4}\theta\cdot(17\cos^{5}\theta-10\cos^{3}\theta+\cos\theta)</math>
:<math>Y_{9}^{5}(\theta,\varphi)={-3\over 256}\sqrt{2717\over \pi}\cdot e^{5i\varphi}\cdot\sin^{5}\theta\cdot(85\cos^{4}\theta-30\cos^{2}\theta+1)</math>
:<math>Y_{9}^{5}(\theta,\varphi)={-3\over 256}\sqrt{2717\over \pi}\cdot e^{5i\varphi}\cdot\sin^{5}\theta\cdot(85\cos^{4}\theta-30\cos^{2}\theta+1)</math>
:<math>Y_{9}^{6}(\theta,\varphi)={1\over 128}\sqrt{40755\over \pi}\cdot e^{6i\varphi}\cdot\sin^{6}\theta\cdot(17\cos^{3}\theta-3\cos\theta)</math>
:<math>Y_{9}^{6}(\theta,\varphi)={1\over 128}\sqrt{40755\over \pi}\cdot e^{6i\varphi}\cdot\sin^{6}\theta\cdot(17\cos^{3}\theta-3\cos\theta)</math>

Revision as of 14:58, 16 January 2014

This is a table of orthonormalized spherical harmonics that employ the Condon-Shortley phase up to degree l = 10. Some of these formulas give the "Cartesian" version. This assumes x, y, z, and r are related to and through the usual spherical-to-Cartesian coordinate transformation:

Spherical harmonics with l = 0[1]

Real spherical harmonics with l = 0[2][3]

Spherical harmonics with l = 1[1]

Real spherical harmonics with l = 1[2][3]

Spherical harmonics with l = 2[1]

Real spherical harmonics with l = 2[2][3]

Spherical harmonics with l = 3[1]

Real spherical harmonics with l = 3[2]

Spherical harmonics with l = 4[1]

Real spherical harmonics with l = 4

Spherical harmonics with l = 5[1]

Spherical harmonics with l = 6

Spherical harmonics with l = 7

Spherical harmonics with l = 8

Spherical harmonics with l = 9

Spherical harmonics with l = 10

See also

External links

References

Cited references
  1. ^ a b c d e f D. A. Varshalovich, A. N. Moskalev, V. K. Khersonskii (1988). Quantum theory of angular momentum : irreducible tensors, spherical harmonics, vector coupling coefficients, 3nj symbols (1. repr. ed.). Singapore: World Scientific Pub. p. 155-156. ISBN 9971-50-107-4.{{cite book}}: CS1 maint: multiple names: authors list (link)
  2. ^ a b c d C.D.H. Chisholm (1976). Group theoretical techniques in quantum chemistry. New York: Academic Press. ISBN 0-12-172950-8.
  3. ^ a b c Blanco, Miguel A. (1 December 1997). "Evaluation of the rotation matrices in the basis of real spherical harmonics". Journal of Molecular Structure: THEOCHEM. 419 (1–3): 19–27. doi:10.1016/S0166-1280(97)00185-1. {{cite journal}}: Unknown parameter |coauthors= ignored (|author= suggested) (help)
General references