Copper(II) trifluoroacetate
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| Names | |
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| IUPAC name
copper;2,2,2-trifluoroacetate
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| (CF3COO)2Cu | |
| Molar mass | 289.578 |
| Appearance | blue wet crystals (anhydrous)[1] light blue crystals (tetrahydrate)[2][3] blue crystals (diacetonitrile） |
| soluble[4] | |
| Hazards | |
| GHS labelling:[5] | |
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| Warning | |
| H315, H319, H335 | |
| P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Copper(II) trifluoroacetate is the trifluoroacetate of divalent copper with the chemical formula Cu(CF3COO)2. It exists as the anhydride, hydrate and adducts of other solvents. The hydrate begins to lose two waters of crystallisation at 108 °C, and loses all crystal water at 173 °C to form the anhydrous form. This begins to decompose at 220 °C.[6]
Preparation
Copper trifluoroacetate can be obtained by reacting trifluoroacetic acid with copper oxide, copper hydroxide or basic copper carbonate. Acetone can replace the water molecules in copper trifluoroacetate hydrate, and under reduced pressure conditions, the acetone can be removed to obtain anhydrous material.[1]
Coordination complexes
The copper atoms of copper trifluoroacetate can be coupled with ammonia molecules or water molecules, and can also form adducts with some organic molecules, such as [Cu(H2O)3(OOC-CF3)2]·2C4H8O2.[7]
References
- ^ a b Cotton FA , Dikarev EV , Petrukhina MA. Syntheses and crystal structures of "unligated" copper(I) and copper(II) trifluoroacetates. Inorganic Chemistry, 2000. 39(26):6072-6079. DOI: 10.1021/ic000663h
- ^ Karpova, Elena V.; Boltalin, Alexander I.; Zakharov, Maxim A.; Sorokina, Nataliya I.; Korenev, Yuri M.; Troyanov, Sergei I. (Apr 1998). <741::aid-zaac741>3.0.co;2-4 "Synthesis and Crystal Structure of Copper(II) Trifluoroacetates, Cu2(CF3COO)4 · 2 CH3CN and Cu(CF3COO)2(H2O)4". Zeitschrift für anorganische und allgemeine Chemie. 624 (4): 741–744. doi:10.1002/(sici)1521-3749(199804)624:4<741::aid-zaac741>3.0.co;2-4. ISSN 0044-2313.
- ^ Elena V. Karpova, Alexander I. Boltalin, Maxim A. Zakharov, et al. Synthesis and Crystal Structure of Copper(II) Trifluoroacetates, Cu2(CF3COO)4 · 2 CH3CN and Cu(CF3COO)2(H2O)4. ZAAC, 1998. 624(4): 741-744
- ^ MJ Baillie, DH Brown, KC Moss. Anhydrous metal trifluoroacetates. Journal of the Chemical Society A Inorganic Physical Theoretical, 1968: 3110-3114. DOI: 10.1039/j19680003110
- ^ "Copper (II) Trifluoroacetate". pubchem.ncbi.nlm.nih.gov.
- ^ 宋代磊. 三氟乙酸铜的制备及其在多元缩合反应中的应用[D]. 辽宁石油化工大学, 2009
- ^ VICTOR CALVO, PIEDAD CORTÉS, YANKO MORENO, et al. INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES Archived 2017-03-16 at the Wayback Machine. Bol. Soc. Chil. Quím, 2000. 45 (2). doi: 10.4067/S0366-16442000000200013
External reading
- Moreland, James A.; Doedens, Robert J. (Feb 1975). "Synthesis, crystal structure, and magnetic properties of a dimeric quinoline adduct of copper(II) trifluoroacetate". Journal of the American Chemical Society. 97 (3): 508–513. doi:10.1021/ja00836a007. ISSN 0002-7863.
- Ollevier, Thierry (2001-04-15), "Copper(II) Trifluoroacetate", Encyclopedia of Reagents for Organic Synthesis, Chichester, UK: John Wiley & Sons, Ltd, p. 1, doi:10.1002/047084289x.rn01852, ISBN 978-0-470-84289-8, retrieved 2024-05-16
- Szczęsny, Robert; Szłyk, Edward; Wiśniewski, Marek A.; Hoang, Tuan K. A.; Gregory, Duncan H. (2016). "Facile preparation of copper nitride powders and nanostructured films". J. Mater. Chem. C. 4 (22): 5031–5037. doi:10.1039/C6TC00493H. ISSN 2050-7526.