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X unit

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Template:Unit of length The x unit (symbol xu) is a unit of length approximately equal to 0.1 pm (10−13 m).[1] It is used to quote the wavelength of X-rays and gamma rays.

Originally defined by the Swedish physicist Manne Siegbahn (1886–1978) in 1925, the x unit could not at that time be measured directly; the definition was instead made in terms of the spacing between planes of the calcite crystals used in the measuring apparatus. One X-unit was set at 13029.04 of the spacing of the (200) planes of calcite at 18 °C.

In modern usage, there are two separate x units, which are defined in terms of the wavelengths of the two most commonly used X-ray lines in X-ray crystallography:[2]

  • the copper X-unit (symbol xu(Cu Kα1)) is defined so that the wavelength of the 1 line of copper is exactly 1537.400 xu(Cu Kα1);
  • the molybdenum X-unit (symbol xu(Mo Kα1)) is defined so that the wavelength of the Kα1 line of molybdenum is exactly 707.831 xu(Mo Kα1).

The 2006 CODATA recommended values for these units are:[3]

1 xu(Cu Kα1) = 1.00207699(28)×10−13 m
1 xu(Mo Kα1) = 1.00209955(53)×10−13 m

See also

References

  1. ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "x unit". doi:10.1351/goldbook.X06719
  2. ^ Template:CODATA1998
  3. ^ Template:CODATA2006