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Wikipedia:WikiProject Chemicals/Chembox validation/VerifiedDataSandbox and Silver tetrafluoroborate: Difference between pages

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Saving copy of the {{chembox}} taken from revid 472458592 of page Silver_tetrafluoroborate for the Chem/Drugbox validation project (updated: '').
 
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{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid [{{fullurl:Silver_tetrafluoroborate|oldid=472458592}} 472458592] of page [[Silver_tetrafluoroborate]] with values updated to verified values.}}
{{chembox
{{chembox
| Watchedfields = changed
| Watchedfields = changed
| verifiedrevid = 464391582
| verifiedrevid = 477000465
| Name =
| ImageFile = Silver tetrafluoroborate.png
| ImageFile = Silver tetrafluoroborate.svg
| ImageSize =
| ImageSize =
| ImageFile1 = Silver-tetrafluoroborate-xtal-3D-SF.png
| ImageFile1 = Silver-tetrafluoroborate-xtal-3D-SF.png
| ImageSize1 =
| IUPACName = Silver tetrafluoridoborate(1–)
| ImageSize1 =
| IUPACName = Silver tetrafluoridoborate(1–)
| OtherNames = Borate(1-), tetrafluoro-, silver(1+)
| OtherNames = Borate(1-), tetrafluoro-, silver(1+)<br/> Argentous tetrafluoroborate
| SystematicName =
| Section1 = {{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| Section1 = {{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 140438
| ChemSpiderID = 140438
| InChI = 1/Ag.BF4/c;2-1(3,4)5/q+1;-1
| InChI = 1/Ag.BF4/c;2-1(3,4)5/q+1;-1
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| StdInChIKey = CCAVYRRHZLAMDJ-UHFFFAOYSA-N
| StdInChIKey = CCAVYRRHZLAMDJ-UHFFFAOYSA-N
| CASNo = 14104-20-2
| CASNo = 14104-20-2
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo_Ref = {{cascite|correct|CAS}}
| PubChem = 159722
| PubChem = 159722
| SMILES = [Ag+].F[B-](F)(F)F
| SMILES = [Ag+].F[B-](F)(F)F
| RTECS = ED2875000
| RTECS = ED2875000
| EINECS = 237-956-5
}}
}}
| Section2 = {{Chembox Properties
| Section2 = {{Chembox Properties
| Formula = AgBF<sub>4</sub>
| Formula = AgBF<sub>4</sub>
| MolarMass = 194.673 g/mol
| MolarMass = 194.673 g/mol
| Appearance = Off-white powder
| Appearance = Off-white powder
| Odor = almost odorless
| Density =
| Density = 4.16 g/cm<sup>3</sup>
| MeltingPtC = 71.5
| BoilingPtC =
| MeltingPtC = 71.5
| MeltingPt_notes = (monohydrate)
| Solubility = soluble
| BoilingPtC =
}}
| Solubility = soluble
| Section3 = {{Chembox Hazards
| ExternalMSDS = [https://fscimage.fishersci.com/msds/55776.htm External MSDS]
| EUClass = Corrosive ('''C''')
| NFPA-H = 3
| NFPA-F = 0
| NFPA-R = 0
| NFPA-O =
| FlashPt =
| Autoignition =
| RPhrases =
}}
}}
| Section3 = {{Chembox Hazards
| ExternalSDS = [https://fscimage.fishersci.com/msds/55776.htm External MSDS]
| GHS_ref=<ref>{{cite web |title=Silver tetrafluoroborate |url=https://pubchem.ncbi.nlm.nih.gov/compound/159722#section=Safety-and-Hazards |website=pubchem.ncbi.nlm.nih.gov |access-date=15 December 2021 |language=en}}</ref>
| GHSPictograms = {{GHS05}}
| GHSSignalWord = Danger
| HPhrases = {{H-phrases|314}}
| PPhrases = {{P-phrases|260|264|280|301+330+331|303+361+353|304+340|305+351+338|310|321|363|405|501}}
| NFPA-H = 3
| NFPA-F = 0
| NFPA-R = 0
| NFPA-S =
| FlashPt =
| AutoignitionPt =
}}
| Section4 =
| Section5 =
| Section6 =
}}
}}
'''Silver tetrafluoroborate''' is an [[inorganic compound]] with the chemical formula AgBF<sub>4</sub>. It is a white solid that dissolves in polar organic solvents as well as water. In its solid state, the Ag<sup>+</sup> centers are bound to fluoride.<ref>Evgeny Goreshnik, Zoran Mazej, "X-ray single crystal structure and vibrational spectra of AgBF<sub>4</sub>" Solid State Sciences 2005, Volume 7, pp. 1225–1229. {{doi|10.1016/j.solidstatesciences.2005.06.007}}
</ref>

==Preparation==
Silver tetrafluoroborate is prepared by the reaction between [[boron trifluoride]] and [[silver oxide]] in the presence of [[benzene]].

==Laboratory uses==
In the [[inorganic chemistry|inorganic]] and [[organometallic chemistry]] laboratory, silver tetrafluoroborate, sometimes referred to "silver BF-4", is a useful [[reagent]]. In dichloromethane, silver tetrafluoroborate is a moderately strong oxidant.<ref>{{cite journal|author=N. G. Connelly, W. E. Geiger| title=Chemical Redox Agents for Organometallic Chemistry|journal=[[Chemical Reviews]]|year= 1996| volume= 96|issue=2| pages= 877–910| doi=10.1021/cr940053x| pmid=11848774}}</ref> Similar to [[silver hexafluorophosphate]], it is commonly used to replace [[halide]] anions or ligands with the [[non-coordinating anion|weakly coordinating]] [[tetrafluoroborate]] anions. The abstraction of the halide is driven by the precipitation of the corresponding [[silver halide]].

==References==
<references/>
{{Silver compounds}}
{{Tetrafluoroborates}}

[[Category:Tetrafluoroborates]]
[[Category:Silver compounds]]
[[Category:Oxidizing agents]]


{{inorganic-compound-stub}}