Wikipedia:WikiProject Chemicals/Chembox validation/VerifiedDataSandbox and Silver tetrafluoroborate: Difference between pages
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Saving copy of the {{chembox}} taken from revid 472458592 of page Silver_tetrafluoroborate for the Chem/Drugbox validation project (updated: ''). |
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{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid [{{fullurl:Silver_tetrafluoroborate|oldid=472458592}} 472458592] of page [[Silver_tetrafluoroborate]] with values updated to verified values.}} |
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| Name = |
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| ImageFile = Silver tetrafluoroborate. |
| ImageFile = Silver tetrafluoroborate.svg |
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| ImageSize = |
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| ImageFile1 = Silver-tetrafluoroborate-xtal-3D-SF.png |
| ImageFile1 = Silver-tetrafluoroborate-xtal-3D-SF.png |
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| IUPACName = Silver tetrafluoridoborate(1–) |
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| IUPACName = Silver tetrafluoridoborate(1–) |
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| OtherNames = Borate(1-), tetrafluoro-, silver(1+) |
| OtherNames = Borate(1-), tetrafluoro-, silver(1+)<br/> Argentous tetrafluoroborate |
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| SystematicName = |
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| Section1 = {{Chembox Identifiers |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
| Section1 = {{Chembox Identifiers |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID = 140438 |
| ChemSpiderID = 140438 |
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| InChI = 1/Ag.BF4/c;2-1(3,4)5/q+1;-1 |
| InChI = 1/Ag.BF4/c;2-1(3,4)5/q+1;-1 |
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| StdInChIKey = CCAVYRRHZLAMDJ-UHFFFAOYSA-N |
| StdInChIKey = CCAVYRRHZLAMDJ-UHFFFAOYSA-N |
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| CASNo = 14104-20-2 |
| CASNo = 14104-20-2 |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| PubChem = 159722 |
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| SMILES = [Ag+].F[B-](F)(F)F |
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| RTECS = ED2875000 |
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| EINECS = 237-956-5 |
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| Section2 = {{Chembox Properties |
| Section2 = {{Chembox Properties |
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| Formula = AgBF<sub>4</sub> |
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| MolarMass = 194.673 g/mol |
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| Appearance = Off-white powder |
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| Odor = almost odorless |
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| Density = |
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| Density = 4.16 g/cm<sup>3</sup> |
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| MeltingPtC = 71.5 |
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| MeltingPtC = 71.5 |
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| MeltingPt_notes = (monohydrate) |
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| EUClass = Corrosive ('''C''') |
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| GHS_ref=<ref>{{cite web |title=Silver tetrafluoroborate |url=https://pubchem.ncbi.nlm.nih.gov/compound/159722#section=Safety-and-Hazards |website=pubchem.ncbi.nlm.nih.gov |access-date=15 December 2021 |language=en}}</ref> |
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| GHSPictograms = {{GHS05}} |
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| GHSSignalWord = Danger |
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| HPhrases = {{H-phrases|314}} |
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| PPhrases = {{P-phrases|260|264|280|301+330+331|303+361+353|304+340|305+351+338|310|321|363|405|501}} |
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'''Silver tetrafluoroborate''' is an [[inorganic compound]] with the chemical formula AgBF<sub>4</sub>. It is a white solid that dissolves in polar organic solvents as well as water. In its solid state, the Ag<sup>+</sup> centers are bound to fluoride.<ref>Evgeny Goreshnik, Zoran Mazej, "X-ray single crystal structure and vibrational spectra of AgBF<sub>4</sub>" Solid State Sciences 2005, Volume 7, pp. 1225–1229. {{doi|10.1016/j.solidstatesciences.2005.06.007}} |
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</ref> |
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==Preparation== |
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Silver tetrafluoroborate is prepared by the reaction between [[boron trifluoride]] and [[silver oxide]] in the presence of [[benzene]]. |
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==Laboratory uses== |
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In the [[inorganic chemistry|inorganic]] and [[organometallic chemistry]] laboratory, silver tetrafluoroborate, sometimes referred to "silver BF-4", is a useful [[reagent]]. In dichloromethane, silver tetrafluoroborate is a moderately strong oxidant.<ref>{{cite journal|author=N. G. Connelly, W. E. Geiger| title=Chemical Redox Agents for Organometallic Chemistry|journal=[[Chemical Reviews]]|year= 1996| volume= 96|issue=2| pages= 877–910| doi=10.1021/cr940053x| pmid=11848774}}</ref> Similar to [[silver hexafluorophosphate]], it is commonly used to replace [[halide]] anions or ligands with the [[non-coordinating anion|weakly coordinating]] [[tetrafluoroborate]] anions. The abstraction of the halide is driven by the precipitation of the corresponding [[silver halide]]. |
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==References== |
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<references/> |
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{{Silver compounds}} |
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{{Tetrafluoroborates}} |
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[[Category:Tetrafluoroborates]] |
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[[Category:Silver compounds]] |
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[[Category:Oxidizing agents]] |
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{{inorganic-compound-stub}} |